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3400 Wildlife Preservation - Herbicide Use in Rolling Hills• d. Pesticide ordinance follow-up on Northern California Cities of Sebastopol and Fairfax. Councilmember Pernell stated that he had requested that staff research the use of pesticides in other jurisdictions. In response to Councilmember Pemell, City Manager Nealis explained that Sebastopol never adopted an ordinance and that the Fairfax ordinance had not resulted in any citations. He also said that Fairfax had been threatened by pesticide industries for possible litigation under the provision that state law regarding pesticides that preempts local jurisdiction. In response to Councilmember Pernell, City Attorney Jenkins explained the use of pesticides on. public property. He. reported that the City of Hermosa Beach initiated an experimental. program of not using pesticide. He said that attempting to control the use of pesticides on private property may cause a legal challenge from the pesticide industry and that there are both federal and state laws governing pesticides use and application. Councilmember Pernell stated that he feels that the City should be sensitive to this issue and that he feels that a pesticide use notification process may be helpful. He also stated that he feels that pesticides should be used in a way that respects the neighborhood. After discussion, the City Attorney was directed research this subject and provide information at an upcoming City Council meeting. PLANNING COMMTCCrnKT rr1n,rc i 1 Introduction to a paper presented to the Wildlife Committee at the Council Chambers in the City of Rolling Hills, Ca. TITLE: Herbicide Use in Rolling Hills WRITTEN BY: Fllavio iign9a�no, Ph.D. DATE: rXY 22, 19 Emulating nature in landscaping begins with respect for an optimally balanced environment. As residents of Rolling Hills, we want to sustain the native habitat of the wildlife in our area. More specifically, this is to understand how plant species inter -relate with one another to grow into vegetation that provide food and shelter for wildlife. The paper introduces five inter -related topics which are: What is a Weed: Methods to Control Weeds At Issue: Weed killers, their Pros and Cons Plant Ecology and the Ecological Role of Weeds Expanding the Concept of Ecology Closing thoughts about safer use of herbicides and References conclude the paper. Prudent use of herbicides is the focus of the paper. Histori- cally, synthesized chemicals that kill weeds began to be used after World War II, with widespread chemical spraying, in- creasing food productivity and esthetically improving the landscape became a reality. An unseen reality was happening at the same time, the.indiscrimant spraying of weeds has slowly polluted the air, water, and soil that defines our environment. Nature, itself, is chemical. The wanton use of man-made chemicals is disrupting nature's intricately balanced chemistry. In the larger context, preservation of this harmony in nature depends upon finding ways of thinking that more clearly defines "What is the role of man in sustaining the pyramid of living organisms that inhabit Planet Earth?" HERBICIDE USE IN ROLLING HILLS by Flavio Bisignano, Ph.D. CONTENTS I. What is a Weed? II. Methods to Control Weeds III. At Issue: Weed Killers, their Pros and Cons IV. Plant Ecology and the Ecological Role of Weeds V. Expanding the Concept of Ecology VI. Closing Thoughts VII. References I. What is a Weed? "Any plant growing where it is not wanted", defines a weed. For example, when dandelions are cultivated as fresh greens to be eaten - they are not perceived as weeds. When dandelions invade the lawn, they become a nuisance. The term "weed" is a non -technical word for many herbaceous (non -woody) plants growing wild . These are unwanted, self - propagating plants as opposed to cultivated plants whose seeds are deliberately sown. Why are some plants unwanted? 1. Any plant robbing the soil of nutrients and moisture stunts the growth of cultivated plants. 2. Root stems of some weeds multiply underground, choking out the root systems of wanted plants. 3. The resiliency of some weed seeds allow the seeds to be buried in soil remaining dormant for years and then germinate. 4. Weeds serve as hosts to fungi that spread to cultivated plants. Other weeds serve as a source for viruses. Some insects that directly attack cultivated plants, breed on weeds. 5. Weeds that grow in hayfields are of low food value. Some weeds eaten by cows leave an unpleasant flavor in milk. Buttercups are weeds that thrive in pastures where cows graze. However, they contain an irritating juice that cattle dislike. 6. Weeds with pointed seed pods may get caught in the coats of animals causing discomfort. Plants, wanted or unwanted, could not exist without soil. Without plants, no food chain could evolve. All green plants absorb mineral nutrients from the soil for metabolic activity. Particular species of plants adapt to particular kinds of soil. For example, the optimal environment for cactus plants is soil with low moisture content. The soil could not form without water and the atmosphere. Plants interact with elements in the soil to provide the nutrients needed for growth. Nitrogen, an essential nutrient cannot be used by the plant directly from the atmosphere. Nitrogen forms 16 percent of all living tissue. Atmospheric nitrogen is made available to plants by the process of nitrification. Geologically, the earth's crust is a shell of solid rock about 20 to 30 miles thick. Soil is the link between the rock shell and vegetation on the earth's surface. Soil is a mix of disintegrated rock and decayed organic matter that is populated with microscopic life. Capillaries throughout the particle mix are pore space occupying air and water. Soil formation is a weathering process. Atmospheric conditions and living organisms are in constant interaction with inorganic rock. Temperature is a powerful agent in fragmenting rock. Rocks are composed of various minerals (naturally occurring chemical elements of inorganic compounds). While all minerals expand in heat some expand more than others. The uneven expansion of diverse minerals crack rocks, causing crevices into which water seeps. In cold weather, the water freezes causing ice in the crevices to exert enough pressure to split rocks. Over the centuries, the cycle of freezing, thawing, and refreezing are the physical processes chemical weathering involves micro-organisms to convert elements from air and water into nutrients that plants can use. The metabolic activity of the soil is upon bacteria, fungi, and algae (algae is the traditional term for unrelated groups of photo synthetic organisms). An example: legumes would starve for lack of nitrogen without soil nitrogen -fixing bacteria to form root nodules on the plants. In the process, atmospheric nitrogen is converted into nitrogenous compounds. In simpler terms, the roots supply carbohydrates for the bacteria. In a complex process, these bacteria combine free nitrogen from the air with oxygen to form nitrates. Eventually, nitrogen as a vital element of living tissue, is present in the form of amino acids that make-up chains of protein (clover and alfalfa are examples of legumes). II. Methods to Control Weeds Cultivation: The mechanical removal of weeds by a garden tool such as a hoe. Crop Rotation: In farming, weeds can be kept i n check by planting a different crop in the same field every few years. For example, weeds invading a cornfield would be of a different plant species than the weeds found in a hayfield. Take over by new weeds attracted to a newly planted crop could starve out most weedseeds remaining in the soil attracted to the previous year's crop. Plant -eating insects: A biological control. An historic example, at the turn of this century the Klamath weed (goat weed) migrated from its native habitat in Europe. Having no ecology in this country - which means there were no natural predators to stop the goat weed spread to the Klamath river area in california Not until 1944, after devastating some two and a half million acres of land, were tow species of beetles imported from France. These beetles feed and reproduce on goatweed, gradually decreasing this toxic plant. In 1959, a ten year survey document the effectiveness of this biological control. Fertilizer with added insecticides/herbicides: Oarbinations exist for special lawn problems. the convenience is in the application of the already mixed product. However, the proper time to fertilize the grass may not be the best time to kill weeds. An example, Ortho's "Weed and Feed" is but one product available in garden centers. Weed -Killing Sprays: (active ingredients) vary in their action: Arsenic and Chlordane have been used to kill crabgrass; chlordane is a chlorinated hydrocarbon in which toxic deposits build-up in animal tissue in cumulative fashion. Arsenic in the weed killer sodium arsenate, is a carcinogen. (Carcinogenic can play either a direct or an indirect role in causing cancer). The "dinitro" herbicides are a metabolic stimulant that "burn" weeds. Aminotriazole (amitrol) is a mutagenic agent capable of altering genes. This is known as the cranberry -weed killer. Mutations assault chromosomes, thus allowing cells to multiply in a wild and unregulated manner. Other herbicides include 2,4 -D/2,4,5 -T and related compounds; IPC and CIPC, chemically related to carbarmates; all these are mutagens. In the application of weed killing products, use them according to the manufacturer's direction. Ideally, these chemicals are toxic only to weeds; but in reality, they threaten the food chain. An example, the herbicide 2,4-D temporarily disrupts nitrification. Selectively killing weeds with as little harm to wildlife as possible is to decide which approved commercial herbicide is the right product, and then to apply it in the right way, at the right time. The Product label informs you of: What is the active ingredient The toxicity rating recommended amount to use Storing and disposing of any used product/container The active ingredient•is the chemical toxin in the herbicidal product that kills targeted weeds. A toxin is any substance with the potential to harm living organisms. A targeted weed is a plant in which the roots/leaves will absorb a particular herbicide in a way that will disrupt normal plant growth. Ease and rate of absorption varies with both the weed species and chemical composition of the active ingredient. After weeds are killed, we need to know how quickly the active ingredient will biodegrade. This is the capacity of microbes in the soil to decompose a toxin into less hazardous substances. The longer toxic residues persist in the soil before biodegrading, the greater the threat to wildlife. Toxicity of the product varies with both its chemical composition, and level of concentration of the active ingredient. Toxicity ratings are indicated by signal words: Danger or Poison means highly toxic Warning means moderately toxic Caution means slightly toxic Use only the recommended amount. Apply the product according to directions. Time the application at a vulnerable stage in weed growth. If possible spot -treat. Herbicides vary in selectivity, which is defined in terms of killing only the targeted weeds in the presence of non -targeted plants. As with any other labeled product containing hazardous substances, adhere to directions for storing and/or disposing of any leftover herbicidal product/container. Careless disposal of hazardous substances may eventually seep into the groundwater and damage the water supply. For proper disposal of unused herbicidal products, contact the local sanitation department. They can tell you where to find an approved collections program or a recycling center for toxic substances. For further information about the use and environmental impact of herbicides, call (800) 858 -PEST. This is a 24 hour hotline, funded by the EPA and the Texas Tech University Health Sciences Center School of Medicine. III. At Issue: Pesticides herbicides into three Weed Killers, their Pros and Cons divide into insecticides for insect control and for weed control. Historically, pesticides group generations. First Generation: Pre - World War II Inorganic agents such as arsenates of lead, nicotine, and kerosene. In addition, formaldehyde gas was used to treat diseased seed and sulfur, to destroy spores in soil. Example: Arsenic, as an active ingredient, was an effective weed killer. the problem - arsenic dust washed form plants by rain trickled into streams and poisoned fish. Second generation: Post World War II Synthesized chemical agents. Two groups: chlorinated hydrocarbons (DDT) and organic. phosphates (malathion) and organic phosphates (malathion) Example: Herbicides 2,4-D and 2,4,5-T their toxicity is controversial. Third generation: Research continues to genetically engineer less toxic pesticides. Example: EPA approved gene -altered dead bacteria which gives off endotoxin, poisonous only to targeted insects. The use of man-made chemical weed killers (synthesized in the laboratory) increase the quantity of food and aesthetical improve the landscape. Nature, itself, is chemical. Example: In photosynthesis, sunlight converts water and carbon dioxide into carbohydrates. In this sense, synthesis means combining simple molecules to form a new substance. However, nature is intricately balanced and the misuse of man-made chemicals is disrupting this balance. One reason for the misuse of herbicides is the lack of understanding of the relationship between weeds and soil. Indiscriminant spraying pollutes more than targeted weeds. Chemical residues reduce the number of earthworms and other organisms that decompose soil. some weed species develop resistance to the herbicides designed to control them. Examples are ragweed and crabgrass. Herbicides have been defended as harmless to wild life because they were thought to be less toxic than insecticides. The cumulative chemical residues of herbicides have endangered wildlife habitat. to destruct homes and food of wildlife can be more devastating than direct killing. Chemical residue tends to concentrate in animal tissue as they pass up the food chain. One way to avoid misusing weed killers is to observe plants in their native habitat. Learn to identify diverse species of plants. Only then can yo selectively apply weed -killers target unwanted plants. IV. Plant Ecology and the Ecological Role of Weeds Plant ecology studies the dynamics of plant, animal, soil, and atmosphere that establishes food webs, they oxygen cycle, and the carbon cycle. Field botany observes and identifies species of plants in their native habitat. When land is barren and atmospheric conditions permit, self -propagating plants (weeds) succeed each other in a given order(lichens, mosses, herbs, shrubs, and trees) Descriptively, soil surfaces the earth to support vegetation. The ecological role of weeds can be found wherever a piece of land is stripped of vegetation and left idle. First, a dense ground cover is formed to hold the soil in place by annual plants. Completing their life cycle within a year, these weeds enrich the soil as they rot. The next weeds are biennials which have a two-year lease on life before being crowded out by perennials. Given more than a two-year life span, some biennials live many years. If the climate permits forest trees will grow. the longevity of forest trees will persist until ravage by fire/flood or cut into lumber by man. when vegetation is destructed and the ground i s bare, the ecological cycle begins anew. Nature emulated in landscaping begins with a better understanding of the self -propagating plant species and how they inter -relate with one another. V. Expanding the Concept of Ecology Ecologyis the study of the relationship between living things and the non -living elements within the environment. Our physical environment is the biosphere; which is made-up of land, water, and air. Planet earth's air supply is finite. Given only solar energy, life on earth is made possible by continually recycling and refreshing the air int eh production of elemental oxygen to sustain a balanced biosphere for the e pyramid of living organisms. Photosynthesis is the chemical process involving sunlight -capturing green plants to generate the air we breathe and the carbohydrates we eat. Oxygen production begins with plankton (free-floating, green microscopic plants) in the ocean. This is the earth's air - freshening system. An ecosystem is any environment where the web -of -life is self - renewing. Very large ecosystems are called biomes such as the rain forest and the Antarctica. Antarctica's barren "land" of ice is the native habitat for penguins. In sharp contrast, brightly colored birds are among the diversity of many species at home in the abundantly vegetated tropical rain forests, global ecosystems are interdependent with one another. This is harmony in nature. Breakdown of intricately balanced ecosystems are leaving gaps in the pyramid of living organisms when oxygen production form the oceans cannot keep pace with oxygen consumption by man, the entire biological structure is threatened. VI. Closing thoughts: 1. Identify the weeds that you want to keep in check 2. What are the options to control them? 3. If you decide on a herbicide follow manufacturer's directions to avoid misuse. The key point: know the pros and cons of the active ingredient 4. Stay updated on herbicidal products that may be available try to avoid products in which the active ingredient may leave a chemical residue in the soil that could get into the food chain. 5. As Rolling Hills residents observe plants and animals whose native habitat is in our. area. Learn how plants interrelate with one another to grow into a vegetate that provides food and shelter for wild life. REFERENCES All About Fertilizers, Soils, and Water. Ortho Books, Chevron Chemical Company. 1979. Brun, Gilbert D. "Plant Ecology and Field Botany", Understanding Botany A Laboratory Guide. Burgess Publishing Company, 1984. Carson, Rachel. The Silent Spring, Boston: Houghton Mifflin Company, 1962. Christensen, Clyde M. "The Weeds", The Book of Popular Science, Vol. 7, Grolier Inc., 1966. Encyclopedia Science Supplement, Grolier Inc. 1970. Cottam, Clarence, "Pesticide Pollution." 1974. Foster, Ruth S. " Plants and the Urban Ecosystems." 1976. Wolf, Biologically." Anthony, "Controlling Insects Gales, Donald Moore. Handbook of Wildflowers, Weeds, Wildlife, and Weather of the Palos Verdes Peninsula, Rolling Hills, 1988. Harte, John, et al. Toxics A to Z: A Guide to Everyday Pollution Hazards. Berkeley: University of California Press, 1991. Levine, Louis, City College of New York, ",Biotechnology" Grolier Encyclopedia, 1992 Yearbook. Schwartz, Linda. The Big Book of Questions and Answers: Earth. Publications International, LTD. 1992. Save the Diseases 65-69 "Using Pesticides Safely" Sunset: Garden Pests and Menlo Park: Sunset Publishing Corporation. 1993. Ca, opeo fl ny INCORPORATED JANUARY 24, 1957 JODY MURDOCK Mayor GINNY LEEUWENBURGH Mayor Pro Tem THOMAS F. HEINSHEIMER Councilmember GODFREY PERNELL Councilmember GORDANA SWANSON Councilmember Dr. Flavio Bisignano 18 Crest Road East Rolling Hills, CA 90274 February 15, 1994 NO. 2 PORTUGUESE BEND ROAD ROLLING HILLS, CALIF. 90274 (310) 377-1521 FAX: (310) 377-7288 Dear Dr. Bisignano: Enclosed with this letter is an updated version of the Herbicide Paper. Revisions made include, removal of the section on burning weeds, and a minor revision of the Bibliography. If you wish to make any further modifications to the paper, or have any questions, please do not hesitate to contact us at City Hall before Tuesday's Wildlife Committee meeting. Again, the City appreciates all the time and effort you placed in preparing this paper. Sncerely, /167-7 Stephen Y. Aryan Administrative Intern SYA:me C:/WP51DATA\HERB Printed on Recycled Paper. CALIFORNIA DEPARTMENT OF FOOD AND AGRICULTURE COUNTY AGRICULTURAL COMMISSIONER'S OFFICE NOTICE OF ERADICATION TREATMENT On // Z 8/O 7 at approximately your property was treated with: P.M., Spinosad - The ingredients in this product meet the requirements of the USDA National Organic Program. Precautions: • Avoid contact with treated trees and shrubs for four (4) hours. • Wait 24 hours before harvesting fruits and vegetables treated with Spinosad. • Wash all fruits and vegetables before eating, as you normally would. • To prevent the spread of this pest, freeze or process all fruits and vegetables before giving them to friends or neighbors. If you have any questions, please call ( 800) 491-1899 Thank you for your cooperation. Front and back yard treated Front yard treated Back yard treated Side yard treated BLOCK NUMBER 3605-6 Date 11/28/2007 60-232(10/98) OFICINA DEL COMISIONADO DE AGRICULTURA DEL CONDADO DEPARTAMENTO DE ALIMENTO Y AGRICULTURA AVISO DE TRATAMIENTO DE ERRADICACION El dia a aproximadamente la(s) A.M. P.M., se aplico un tratamiento a su propiedad. El tratamiento fue: Spinosad - Los ingredientes de este producto Henan los requisitos del USDA del Programa Nacional Organico. Precauciones: • Por cuatro (4) horas evite contacto con arboles y arbustos tratados.. • Espere 24 horas antes de cosechar las frutas y vegetales que fueron tratados con Spinosad. • Lave toda las frutas y vegetales antes de comerlos, como usted normalmente lo haria. Si usted tiene preguntas, por favor (lame ( 800) 491-1899 Gracias por su cooperacion. NIJMERO DE CUADRA 3605-6 Date 11/28/2007 ; -~-meeting of the City Council. Staff was directed to prepare a plaque for presentation to Mrs. Ginny Leeuwenburgh for her many years of service to the City. OPEN AGENDA - APPROXIMATELY 8:00 P.M. - PUBLIC COMMENT WELCOME Mayor Murdock introduced and welcomed Captain Jay Zuanich as the new Captain of the Los Angeles County Sheriff's Department, Lomita Station. MATTERS FROM MEMBERS OF THE CITY COUNCIL Councilmember Pernell commented on the memorandum prepared by staff at his request regarding what other cities have. done to regulate the backyard use of pesticides. City Manager Nealis reported that several cities in Northern California were queried on the subject: In response to Councilmember Pernell, City Manager Nealis stated that staff would provide updated research on this subject in 'six months. 7 Mayor Murdock indicated that Mayor Pro Tern Allen Lay will be representing the City at the Palos Verdes Peninsula Coordinating Council Peninsula Priorities Luncheon on Thursday. MATTERS FROM STAFF None. MATTERS FROM THE CITY ATTORNEY None. ADJOURNMENT Hearing no further business before the City Council, Mayor Murdock adjourned the meeting at 8:04 p.m. to the next regularly scheduled meeting of the City Council to be held on Monday, October 8, 2001 in the City Council Chambers, at City Hall, 2 Portuguese Bend Road, Rolling Hills, California. Approved, Mayor Minutes City Council Meeting 09/24/01 Respectfully submitted, Marilyn L. K rn Deputy City Clerk -3- i e144 WIZ/ling Jill, INCORPORATED JANUARY 24, 1957 NO. 2 PORTUGUESE BEND ROAD ROLLING HILLS, CALIF. 90274 (310) 377-1521 FAX: (310) 377-7288 E-mail: cityofrh@aol.com Agenda Item No.: 5.1 Mtg. Date: 07/16/01 TO: HONORABLE CHAIR AND MEMBERS OF THE WILDLIFE PRESERVATION COMMITTEE FROM: CRAIG NEALIS, CITY MANAGER SUBJECT: CONSIDERATION OF INFORMATION RELATIVE TO WILDLIFE AND PESTICIDES DATE: JULY 16, 2001 Councilmember Godfrey Pernell has suggested that information be made available at City Hall relating to wildlife and pesticides. Attached to this staff report is information that was gathered by Wildlife Preservation Committee Member Steve Shultz. RECOMMENDATION It is recommended that members of the Wildlife Preservation consider directing staff to make this information available at City Hall. CRN:mlk 07/16/01 wpcpesticide.s to Printed on Recycled Planer. Wildlife and Pesticides A practical guide to reducing the risk • Introduction • Potential Hazards to Wildlife • Effects of Pesticides on Wildlife • Assessing Pesticide Risk to Wildlife • Reducing Pesticide Exposure Risk • Pesticide Toxicity to Wildlife • Summary • Toxicity Tables Pesticides are widely used in agriculture today. Producers use pesticides because they are effective and generally reasonably priced. The benefits include reduced yield losses and timesavings to the producer, and lower food and fiber costs for consumer. There are some downside risks to pesticide use. Pesticide poisonings of people, livestock, and wildlife have occurred when proper care was not exercised. Pesticide applicators must be very careful to avoid these risks. Pesticides, when used with good judgement and care in accordance with label instructions, benefit both agriculture and the environment. Proper use ensures that food and wildlife production objectives can both be realized. Every pesticide applicator must accept responsibility to prevent or minimize the effects of pesticide applications on nontarget organisms. There are several things you as an applicator can do to reduce the risk of pesticide exposure to nontarget plants, animals and habitats. Potential Hazards to Wildlife In order to better protect wildlife from the risks of pesticide exposure it is necessary to understand what effects pesticides may have on wildlife. Several hundred different pesticides are used in agriculture today. Each one of these products has different characteristics that can affect the risk posed to different types of wildlife. While a particular pesticide may pose no harm to mammals, it may cause severe harm to aquatic or bird life. Knowing these differences will greatly assist you in making the proper pesticide use decision. There is much documentation showing that wildlife can be harmed by particular pesticides. The documentation includes laboratory toxicity studies on various types of wildlife, field trials that must be performed in order to register the pesticide, and reports of incidents of wildlife poisoning. In Oregon in the 1970s, aldrin and mercury treated seed grain killed thousands of wild geese and other wildlife. Thirty-six Canada geese were killed in 1988 as a result of an application of carbofuran (Furadan) and disulfoton (Di-Syston) in Idaho. Phorate (Thimet) was involved in the deaths of hundreds of waterfowl and several bald and golden eagles in South Dakota in 1989. Many of the incidents involving wildlife kills result from misuse or illegal applications. One such incident occurred in 1990 when an applicator in North Dakota illegally applied carbofuran (Furadan) to carcasses for predator control. He was found guilty of killing several forms of wildlife, possibly including a bald eagle. Effects of Pesticides on Wildlife Pesticides' effects on wildlife may be lethal, sublethal, acute, chronic, habitat related, or there may be no effect. In general the risk a pesticide poses to wildlife is related to the pesticide type, its toxicity, the proximity of the application to wildlife habitat, the dose, application rate, number of applications, the persistence of the pesticide in the environment, and its ability to concentrate in the wildlife food chain. These factors interact with food habits and behavior of individual wildlife species to produce a response. Pesticide Type In general, insecticides are more toxic to fish and wildlife than herbicides or fungicides. Some herbicides may harm wildlife by damaging the wildlife habitat. Many of the insecticides currently used are either the organophosphate or carbamate type. These insecticides work by interfering with the central nervous system of insects. The central nervous system of fish or wildlife may be affected the same way. The toxicity of the various organophosphate and carbamate insecticides ranges from slightly toxic products to products that are highly toxic. The more toxic products are generally restricted use pesticides, which require applicators to be certified by their state regulatory agency to purchase and apply products. Synthetic pyrethroid insecticide use has been increasing. These synthesized insecticides are based on naturally occurring pesticides, but have been modified to improve performance and persistence. Synthetic pyrethroids also work by interfering with the central nervous system. Synthetic pyrethroids are low to medium in toxicity to mammals and birds because they can quickly detoxify and excrete them. However, fish and aquatic invertebrates can not quickly detoxify or excrete synthetic pyrethroids, so they are highly susceptible to poisoning by these products. Herbicides and fungicides are generally low to moderately toxic to wildlife. Particular herbicides can have a large impact on the plant life making up the wildlife habitat. Direct Effects Wildlife can be exposed to pesticides directly by eating contaminated food or water, breathing pesticides, or by skin absorption. The type and magnitude of the effect depends on two factors, the pesticide toxicity and pesticide quantity (dose). If exposure causes the animal's death, it is referred to as a lethal effect. Young birds that eat or are fed pesticide treated insects are at great risk of suffering lethal pesticide exposure effects. Sublethal insecticide effects occur when damage to the central nervous system causes an animal to behave in a unusual manner. This behavior may affect the animal's ability to survive or reproduce. Some typical sublethal responses in birds exposed to pesticides include the inability to sing properly, establish a breeding territory, or attract a mate. Adults may be unable to care for themselves or their young properly, resulting in death to the nestlings or increased chance of predation. The lethal and sublethal effects of pesticides on wildlife and fish may occur from one exposure over a short time period (acute) or they may result from exposures to small amounts over a longer time period (chronic). Pesticides commonly used today do not persist as long in the environment as pesticides used years ago. The tradeoff is that the acute toxicity of some of these modem pesticides is higher than the older, more persistent chemicals. Indirect Effects Wildlife in general, and birds in particular, may also experience lethal or sublethal effects without being directly exposed to a pesticide. This typically occurs when a pesticide application destroys or disrupts food sources such as insects. Insects supply the protein necessary for growing birds. Studies indicate that the growth of young birds can be stunted in areas where insecticides have been used heavily, resulting in insect populations too low to meet young bird protein growth demands. Fish that feed on aquatic insects and animals may also show stunted growth in areas of heavy insecticide use because their primary food sources are killed. Inadequate diets also can affect fish reproduction and survival. Herbicides can reduce the amount of cover and make the habitat less suitable for nesting. Assessing Pesticide Risk to Wildlife To properly assess the need for pesticides and the risk to wildlife, information must be gathered on the condition of the crop, the pest situation, characteristics of candidate pesticides, present and expected weather, and some knowledge about the kinds and behavior of wildlife living in the area. The importance of good judgement, practical experience and common sense cannot be overemphasized. Prior to each and every pesticide application, the overall situation should be evaluated so that the expected benefits of a pesticide application are realized and potential hazards are minimized. Good information is necessary to make good judgements. Monitor Fields Regularly Field scouting must be done. It is important to be aware of the status of the field, the crop stage, general health, and yield potential of the crop, as well as the number and growth stage of the various pests that are present. Careful scouting will reveal any wildlife that may also be present. Most pests and most wildlife do not occur uniformly throughout a fold. Drawing a map of the field showing the locations of pest populations and wildlife along with recognizable landmarks can aid you in developing a pest control plan that avoids possible effects on wildlife. Identify Wildlife Signs, Seasons, and Habitats One way to ensure that wildlife will not be impacted by a pesticide is to make the application when wildlife are not present. Most wildlife signs can be easily determined while scouting the field. Virtually all agricultural crops will support some type of wildlife. A wide assortment of wildlife will likely be visible during most scouting trips. Areas where wildlife are most likely to be located are field perimeters and other areas where fields may come into contact with windbreaks, wetlands, livestock watering ponds, fence rows, abandoned farmsteads, grasslands or odd areas. Take note of areas where you actually see animals. Other evidence that wildlife are present and using the area includes signs such as tracks,.droppings, or foraging evidence. If numerous wildlife signs are present, pesticide applicators can reduce potential impacts to wildlife by marking such areas on a field map or leaving a flag in that area of a field. When spraying around sensitive areas, leave a buffer zone of at least one-half the width of a sprayer boom. Another way to minimize potential impacts to wildlife is to restrict spraying activities in these fields between the hours of 10 a.m. and 4 p.m. During this period, many wildlife will seek the protective cover of cropland, particularly taller row crops, as they wait out the day prior to beginning evening and early moming foraging activities. Critical Reproductive Periods and Habitats Most wildlife reproduction occurs from May 1 to late June and early July. This is perhaps the most critical for many of our resident and migratory wildlife and fish. To complete this reproduction, animals seek out suitable habitats. These habitats can include wetlands, windbreaks and shelterbelts, fencerows, rangelands, and croplands. Wildlife typically nest, birth, feed, and rear their young in areas that provide not only some type of protective cover from the elements and potential predators, but also sources of food. The transition zones between habitat types, where one plant community changes to another, are preferred. These edges usually produce the greatest variety of food plants, insects and seeds. This allows wildlife such as grouse, pheasants, and deer to feed without venturing too far from protective cover. For this reason, most upland gamebird nests can be found in or near such edges. Wetlands are important feeding and brood rearing habitats for waterfowl. Insecticides applied near wetlands by ground sprayers or aircraft can enter the habitat through drift or runoff and contaminate these areas. Depending on the insecticide type, food sources may be destroyed, causing sublethal effects or a direct loss of young wildlife. Similarly, shelterbelts and windbreaks are important habitats for many songbirds. Herbicide drift that results in injury to trees and other vegetation can impair the ability of such habitats to provide safe, secure nesting sites. Insecticide drift can kill nestlings and adult birds, as well as contaminate important insect food sources. Reducing Pesticide Exposure Risk Regular field scouting and a pest control plan should be a part of every producer's operation. Pests are best controlled by manipulating cropping conditions to put pests at a disadvantage to the crop or beneficial organisms. Man and his crops are in competition with pests, and ALL available methods for controlling pests should be considered, not just pesticides. i. Eliminate Unnecessary Pesticide Applications Through IPM Few applicators knowingly apply unnecessary pesticides because pesticides cost money. Every applicator should ask, will this application pay for itself? Growers should not substitute pesticides for good management. Pesticides are necessary but should only be part of a total pest control program, not the entire program. The best method of reducing risks to wildlife is to use integrated pest management (IPM) practices. IPM incorporates cultural methods such as crop rotation, date of planting, variety choices, and seeding rates with other methods of pest control to maintain pest populations at tolerable. levels. Under IPM, pesticides are used only when other methods are not successful and pest damage to crops might otherwise exceed the cost of control. Many pest management practices can help reduce the need for pesticides. Some additional control methods include crop competition, crop rotation, tillage and cultivation, sanitation, planting resistant varieties, planting weed and disease free seed, and using the natural controls present when possible. A good example of non -pesticide control is a competitive crop. An early established, well developed crop can do much to help control weeds. Plants emerging first have a competitive advantage over later emerging plants. Anything done to get quick crop emergence that evenlycovers the ground early will have a big impact on weeds. Later emerging weeds are at a tremendous disadvantage and may not cause yield and quality losses. The competitiveness of weeds and crops differs between species. Weeds such as wild oats, wild mustard, and kochia arc very competitive, while others, such as redcoat pigwecd and fuxtails are generally less competitive. Some crops ranked in order of decreasing competitiveness are rye, barley, conventional height wheat, semidwarf wheat, and flax. Choose the Pesticide Least Toxic to Non -target Organisms Choose the least toxic pesticide that will control the pest. Often more than one pesticide is registered for control of a particular pest in a particular crop. Take time to compare pesticides and make sure you choose the one BEST suited for the job. Many times the best choice will be the least expensive treatment, but that is not always the case. Sometimes the best choice would be a higher priced pesticide with fewer risks for nontarget plants and animals. Pesticide Toxicity to Wildlife Pesticide applicators can plan a pesticide application that is less toxic to wildlife by examining pesticide toxicity al,d pulcr►tial for environmental injury to wildlife and wildlife habitats. This information can be found in tables presented in the back of this publication. When an applicator has identified the specific crop pest situation and checked local crop production guides, a pesticide can be selected that minimizes risk to nontarget plants and animals and still achieves the desired level of control. If the selected pesticide still poses a high threat to wildlife, the applicator would at least be aware of the risk and can take the steps to minimize any potential threats by following recommendations in this publication. Read the Pesticide Label Certain pesticides pose a risk to wildlife or the environment. Some products are classified as RESTRICTED USE PESTICIDES because of environmental hazards. Restricted use pesticides should only be applied by a certified applicator who has been properly trained. Pesticides that pose environmental risks are labeled to warn the applicator what the risks could be and what steps should be taken to protect people, animals and the environment. These warnings can be found in the "Precautionary Statements" section of the label. The precautionary section is divided into subsections dealing with "Hazards to Humans or Domestic Animals," Environmental Hazard" and "Physical or Chemical Hazard." The risks to wildlife and the environment may be found in the "Environmental Hazard" section. It is a violation of federal law to apply pesticides in any way that is not consistent with label instructions. Hazards to Wildlife If a particular pesticide is especially hazardous to wildlife, it will be stated on the label. For example: • This product is highly toxic to bees. • This product is toxic to fish. • This product is toxic to birds and other wildlife. The label may indicate that the product causes undesirable effects in the environment. In this case, the precautionary statement may tell what to avoid doing. Labeling may indicate limitations imposed to protect wildlife, including endangered species. These limitations may include reduced rates, restrictions on types of application, or a ban on the pesticide's use within the species range. The.label also may indicate additional sources of information on proper application methods to reduce hazards. These statements explain special hazards that the pesticides may pose. They should help when choosing the safest product for a particular job and serve as a reminder to take extra precautions. General Environmental Statements General environmental statements appear on nearly every pesticide label as reminders of common sense actions needed to avoid contaminating the environment. The absence of any or all of these statements DOES NOT change the requirement to take adequate precautions. Sometimes the statements will follow a "specific toxicity statement" and provide practical steps to avoid harm to wildlife. Examples of general environmental statements include: • Do not apply when runoff is likely to occur. • Do not apply when weather conditions favor drift from treated areas. • Do not contaminate water when cleaning equipment or disposing of wastes. • Keep out of any body of water. • Do not allow drift on desirable plants or trees. • Do not apply when bees are likely to be in the area. • Do not apply where the water table is close to the surface. Note: It is the responsibility of every pesticide applicator to read and follow the label directions. Use the Lowest Effective Rate Many times the label will allow a range of rates to control a particular pest. Differences in pest size or stage, pest populations and environmental conditions can affect the amount of pesticide needed. Often pesticide rates at the lower end of the rate range can be used when pests are in sensitive growth stages, at lower populations and the weather and growing conditions are favorable. Use Buffer Zones An area between the area sprayed and a sensitive area is called a buffer zone. This area can be a grass strip or may even be part of the crop that is not treated. This buffer area will help trap pesticides and prevent them from entering sensitive areas by spray drift or by runoff. Spot Spraying Many times a pest is located only in a portion of the field. Spraying only the area where the pest is found, leaving the rest of the field untreated, reduces potential risks and saves time and money. Begin Spraying In the Middle of the Field Most wildlife will be present near the edges of a field. Spraying the field by starting in the middle of the field will allow wildlife time to escape or move out of the field area. Trap Areas Some farmers are experimenting with the use of trap areas. Farmers will seed these areas with an early maturing crop variety ahead of normal planting dates. These areas may attract pests and if pest populations develop in the trap area, a pesticide application can be made. Controlling pests in this manner can reduce chances that pesticides willbe required on the rest of the field. Check Weather Conditions A good applicator always checks the weather conditions before spraying. Weather conditions can greatly affect the pesticide exposure through spray drift or runoff. Don't apply pesticides just before rains because pesticides could run off the treated field with excess rainwater and potentially contaminate sensitive areas. Avoid spraying when weather conditions could cause spray drift into sensitive areas. Avoid Spray Drift Spray drift can cause damage to wildlife or wildlife habitat. The following measures are available to greatly reduce drift. Avoid spraying on windy days Check the wind speed and direction. If conditions could cause spray drift into sensitive areas, don't spray. If an application must be made you must take every precaution you can to prevent drift from entering sensitive areas. Another weather condition to avoid is a temperature inversion. Temperature inversions occur when cooler air is near the ground and is beneath warmer air. Very small spray droplets will remain suspended in the air and can move some distance. Use a nonvolatile formulation Some pesticides are volatile and can form vapors, usually on warmer (greater than 70 F) days, which can drift into susceptible areas. If there is an alternative pesticide or formulation that is not volatile and will control the pest, it should be used instead. Increase Droplet Size Spray nozzles produce spray dropletsof many different sizes. Larger droplets are heavier and drift less. Practices that increase droplet size will reduce drift, such as increasing nozzle size or water volume, reducing spray pressure or using a drift retardant. Use Larger Nozzle Larger nozzles allow you to apply the same volume �f spray with less spray pressure. Spray droplets willbe larger than those produced by a smaller nozzle with higher pressure. Increase Water Volume Increasing the water volume will decrease drift because water droplets will be larger and will tend to drift less. Use the Lowest Practical Pressure • Lower spray pressure will result in larger spray droplets that drift less than smaller droplets. If spray pressure is reduced too much the spray pattern that results will not be uniform. Newer nozzles such as the "LP" or "XR" type are designed to produce uniform spray patterns with pressures of 15 to 20 pounds per square inch. Use a Drift Retardant A drift retardant will help reduce spray drift by increasing the size of spray droplets.. Larger droplets tend to drift less than small droplets. Reduce Spray Boom Height Set spray booms at the lowest height that will give uniform coverage. The closer the boom is to the spray target the less chance there is for drift. Use a Shielded Sprayer Using a shielded sprayer will help reduce spray drift by protecting the spray from wind. Shielded sprayers allow a wider selection of spraying times during the day and more total spraying time per day. These time savers can be used to more precisely target crop areas and avoid sensitive areas. More information on spray drift can be found at your state's Cooperative Extension Service county office. Summary The responsibility to prevent or minimize the effects of pesticide applications on nontargct organisms rests with every pesticide applicator. Information concerning the proper use and application of a pesticide can be found on the product label. Reducing the risk of pesticide exposure to nontarget organisms requires applicators to incorporate crop scouting and IPM techniques with a knowledge of wildlife life cycles and habitats in developing a farm pesticide application plan: Development. of such a plan will insure not only the most cost effective means for controlling crop pest situations, but also result in the greatest reduction of risk of pesticide exposure to wildlife. Resource Material Apply Pesticides Correctly: A Guide for Commercial Applicators, U.S. Department of Agriculture and U.S. Environmental Protection Agency. Commercial and Private Applicator Core Manual: Initial Certification, September 1989, Cooperative Extension Service, Michigan State University. Dexter, A. Herbicide Spray Drift. 1986. NDSU Extension Service. A-657 revised. Extoxnet Cooperative Extension Offices, Cornell, U of Calif., Michigan State, Oregon State Univ. Facemire, F. Charles, 1991. Impact of agricultural chemicals on wetland habitats and associated biota with special reference to migratory birds. B 780, SDSU, Brookings, SD. 65 pp. Herbicide Handbook of the Weed Science Society of America. Sixth Ed., 1989, Weed Science Society of America, Champagne, Illinois, 61820. McBride, D.K.; D.E. Peterson, H.A. Lamey, 1988, Persistence and Mobility of Pesticides in Soil and Water, NDSU Extension Service. E-49, NDSU Fargo, ND 58105 Pesticide Applicator Training Manual: Core Manual, 2nd Ed., Chemicals -Pesticides Program, Cornell University, 1990. D. Rutz, Director, R. Gardner, W. Smith. Wildlife and Pesticides: A practical guide to reducing the risk (continued) Toxicity Tables These tables provide toxicity comparisons for commonly used pesticides. These comparisons are intended to give applicators the information needed to reduce the risk of an application to wildlife. INSECTICIDES Pesticide (Trade name) Family acephate Organo- (Orthene) phosphate Aldicarb Carbamate (Temik) azinphos Organo- methyl phosphate (Guthion) Bacillus Microbial Thuringiensis (various) . . carbaryl Carbamate (Sevin) carbofuran Carbamate (Furdan) chlorpyrifos (Lorsban) diazinon (various) Organo- phosphate Organo- phosphate dimethoate Organo- (Cygon) phosphate Toxicity class III -(Birds and mammals) I- (Fish/aquatic insects) I -Birds, fish, mammals and aquatic insects) I -(Mammals) II -IV (Birds) II - (Fish/aqurtic insects) V -(Birds and mammals) Documented effects on wildlife Moderate to slight acute oral toxicity to birds and mammals Reduction in ChE activity. contaminating wetlands, ponds, streams and rivers. Bird and mammal mortality Proper incorporation of granules. Consider reported after ingestion of weather and terrain to avoid runoff potentials into exposed granules. One of water areas. the most toxic carbamate pesticides. Extremely toxicto aquatic organisms. Extremely toxic to Scout fields to determine the presence of wildlife. mammals in formulations Avoid or delay direct application when wildlife is containing a high present. Exercise caution to reduce the risk of percentage of active ingredient. Highly toxic to fish and aquatic insects. No documented effects on wildlife. Best measures to reduce the risk of exposure Increase water volumes to reduce drift. Avoid use areas of high bird numbers. Use lowest recommended effective rates. Avoid III -IV -(Birds III- Moderate acute/chronic (Mammals) I -(Aquatic toxicity to birds, fish, and insects) I -(All) I -H -(Birds) II -III- Highly toxic to mammals (Mammls) I -(Fish and and birds through oral aquatic insects) Extremely toxic to fish and aquatic insects. III -(Mammals) I- Extremely toxic to birds (Birds, fish and aquatic and moderately toxic to insects) mammals. Toxic to bees, fish, and other aquatic organisms. I -(Birds, fish, and Moderate acute oral aquatic insects) III- toxicity to mammals. direct, drift, or runoff applications to water or wetland areas. Avoid contaminating ponds,lakes, and streams. Apply according to label directions. Avoid direct applications to wetlands and other waters. Reduce potentials for drift and runoff by mammals. Low persistence. using buffer zones. Toxic to aquatic insects. Highly toxic to all forms of Avoid applying this chemical when wildlife is wildlife even when applied present. Use buffer zones when applying near at lowest recommended wetlands,other waters, and wooded areas. Use an effective rate. alternate pestiicide. (Granular carbofuran has been voluntarily cancelled and will be phased out by 1994. Flowable is still registered.) • Avoid contaminating wetlands, lakes, ponds, and streams. Do not apply when wildlife are present. Applications should be made only after a careful evaluation. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid application (direct, drift or runoff) on water areas/wetlands. Use buffer zones near water and (Mammals) disulfoton Organo- I -(All) (Di-Syston) phosphate endosulfan (Thiodan) Chlorinated I -(Fish and aquatic Hydrocarbon insects) II -IV (Bird II (Mammals) esfenvalerate Pyrethroid (Asana) I (Fish) IV -(Bird and mammals) parathion Organo- I -(All) (methy ethyl) phosphate (Penncap-M various) fenvalerate Pyrethroid (Pydrin) fonofos Organo- (Dyfonate) phosphate malathion Organo- (Cythion) phosphate Extremely toxic to birds, shelterbelts. fish, and other aquatic organisms. Pheasants are particularly sensitive to this pesticide. Extremely toxic to birds, mammals, fish, bee and aquatic organisms. Secondary poisoning in birds eating treated insects has been reported. Fish kills associated with s) I- contaminated agricultural runoff. Concentrates of <1.3 ppm were sufficient to cause mortality. Highly toxic to aquatic organisms/insects. Highly toxic to fish, aquatic insects. No reported toxicity in birds/mammals. Ethyl and methyl parathion are extremely toxic to birds, mammals through both acute oral and dermal exposure at recommended application rates. These chemicals are highly toxic to bees fish and other aquatic organisms. I -(Fish) IV-V(Bird and See Esfenvalerate mammals) I(All) Highly toxic to fish, mammals and birds due to chemical action, high field use and relatively long persistence. Used as a granular treatment. III -(Birds and No documented effects on mammals) I -(Fish and wildlife (birds/ mammals) aquatic insects) methidathion Organo- II(All) (Supracide phosphate OP) phorate Organo- I(All) (Thimet) phosphate when used at recommended application rates. Toxic to bees, fish and other aquatic organism. High acute oral toxicity to birds/mammals, bees and fish. Extremely high oral and dermal toxicity has been documented in birds and mammals after exposure to pesticide. Wildlife deaths reported are related to • ingestion of improperly incorporated granules, in areas subject to flooding and run off. Uptake of chemical in plants may also Proper field scouting to include a careful evaluation of potential wildlife exposure will reduce the risk. Do not apply when wildlife is present. Caution should be taken to avoid risks associated with agricultural runoff. The use of buffer zone will reduce risk associated with use of this pesticide. Measures to reduce the risks to wildlife. Avoid applications (direct, drift, runoff in water bodies/ wetlands. Use lowest recommended effective rates and buffer zones near water. Prior to applying parathion a thorough scouting of the field should be conducted. Field applications of parathion should be made prior to 10 a.m. or after 4 p.m. to minimize drift and leave buffer zone near critical wildlife habitats such as windbreaks and wetlands. Do not apply when wildlife are present. See esfenvalerate. Complete incorporation of the product into the soil will minimize wildlife exposure risks. Consider weather and terrain to avoid runoff contamination. Avoid application (direct, drift or runoff) on water areas/wetlands. Use near buffer zones near water. Careful scouting of field to identify the presence of wildlife and the subsequent avoidance of such area and critical wildlife habitats during application will minimize wildlife exposure risks. In areas subject to flooding and runoff and where wildlife are present in large concentrations (migrations) the use of this pesticide should be carefully evaluated. The pesticide must be properly incorporated. terbufos Organo- (Counter) phosphate permethin Synthetic (Ambush pyrethroid Pounce) HERBICIDES Pesticide (Trade name) Family 2,4-D Phenoxy I(All) I -(Fish and aquatic insects) V -(Birds and mammals) Toxicity class III -IV -(Birds and mammals) II - (Fish and other aquatic organisms) 2,4-D Amine 2,4-D Ester (see 2,4,-D) acifluorfen Biphenol HI -V -(Birds) IV - (Blazer) ether alachlor Acetanilide (various) atrazine Triazine (various) bentazon Benzothia- (various) diazoles • (Mammals) I- II(Fish and • aquatic insects) IV -V -(Birds and mammals) I -(Fish and aquatic insects) IV -V -(Birds and mammals) IV - (Fish) III -IV -(Birds, mammals and fish) bromoxyni Benzonitrile I -(Fish and 1 (Buctril) aquatic insects) II -IV -(Mammals and birds) clopyralid Pyridine IV -V -(Birds and (Stinger) mammals) II cause wildlife exposure. Extremely toxic to lab mammals. Potential for greatest impact due to ingestion of granules. Extremely toxic to aquatic organisms. No documented field effects on birds or mammals. Documented effects on wildlife Moderately toxic to birds and mammals. Highly toxic to insects, fish. A reduction of birds broad- leaved plants from applications can result in a reduction in the nest numbers of waterfowl and other upland nesting birds. Use of a non toxic oil vehicle during application increases toxicity of the chemical to egg embryos. Spray drift can harm wooded areas. No documented impacts on birds or mammals. Toxic to aquatic organisms. May damage susceptible foliage (cover). No documented impacts on birds and mammals. Highly toxic to aquatic insects and fish. Slightly toxic to birds at high concentrations. Indirect effects on aquatic fauna may result as the chemical impacts aquatic plant species. Toxic to fish and aquatic invertebrates at high concentrations. No documented impacts on birds and mammals. Moderately toxic to Rainbow trout. Extremely toxic to aquatic invertebrates No documented impacts on birds and mammals. No documented impacts on wildlife. Spillage, failure to cover granules, heavy rains or high winds could expose granules increasing the risk. If such conditions exist do not apply if wildlife is present. In areas subject to flooding and runoff and where wildlife are present in large concentrations (migrations) the use of this pesticide should be carefully evaluated. The pesticide must be properly incorporated. Risk can be reduced if applied as an in -furrow or modified in -furrow application. Prevent direct, applications or drift and runoff into wetlands and other water. Use a buffer zone if applied near water areas. Best measures to reduce the risk of exposure In areas where waterfowl and other upland nest apply with a water based spray mixture. Spot spray where possible to reduce impacts on potential nest cover. Avoid spray drift. Apply amine formulation where drift is a concern. Use a buffer zone when applied in wooded areas, or near water. Avoid spray drift. Use buffer zones near surface water. Avoid contaminating ponds, lakes, wetlands, and streams. Avoid spray drift and runoff contamination of wetlands and other water areas by using buffer zones. Avoid contaminating ponds, lakes, wetlands, and streams. To minimize the impacts of agricultural runoff carrying this chemical into wetlands and other waters employ buffer zones. Use at lowest effective rate.Use with caution in areas where groundwater contamination is likely. Avoid contaminating ponds, lakes, wetlands, and streams. Use buffer zones to reduce potential impacts to aquatic habitats. Do not apply when conditions favor drift. Avoid contaminating ponds, lakes, wetlands, and streams. Avoid spray drift. Avoid contaminating ponds, lakes, wetlands, and streams. Use buffer zones if applying near water areas. Avoid contaminating ponds, lakes, wetlands, and cyanazine Triazine $ (Bladex) cycloate . Thio- (Ro-Neet) carbamate desmedop Carbamate ham (Betanex) dicamba Benzoic (Banvel) Acid diclofop (Hoelon) Aryloxy- phenoxy- propionic Acid (Fish) III -IV -(Birds and mammals) V -(Birds) IV - (Mammals) I - (Fish and aquatic organisms) IV -(Birds and No documented field effects in mammals) I -(Fish wildlife. Low toxicity to laboratory and aquatic animals. Toxic to fish. insects). IV -(Birds mammals, fish, and aquatic insects) V -(Birds) IV - (Mammals) I - (Fish, and aquatic insects) No documented field effects on wildlife. Slightly toxic to aquatic invertebrates. No documented field effects on wildlife. difenzoqu Bipyridilium IV -V -(Birds) IV- No documented field effects on at (Avenge) EPTC Thio- (Eptam) carbamate ethalflurali Dinitro= n aniline (Sonalan) fenoxapro Aryloxy- p (Whip) phenoxy- (Option) propionic Acid fluazifop Aryloxy- (Fusilade) phenoxy- propionic Acid glyphosate Amino Acid (Roundup) (Rodeo) Amino Acid imaza- Imidazoline methabenz (Assert) MCPA- Phenoxy- amine carboxylic MCPA- Acid ester metsulfuro Sulfonyl n (Ally) Urea Nicosulfur Sulfonyl- on (Mammals) II- wildlife. (Fish) I -(Aquatic insects) IV -V (Birds and mammals) I -(Fish and aquatic insects) IV -V (Birds and mammals) I - (Fish) IV -V (Birds and mammals) I -(Fish and aquatic insects) IV -V (Birds and mammals) I -(Fish and aquatic insects) IV -V (Birds and mammals) I -(Fish and aquatic insects) III -IV Fish and aquatic insects. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. Rodeo is slightly toxic to aquatic organisms unlike its counterpart Round -up. IV -V (Birds and No documented field effects on mammals) II- wildlife. Low toxicity in lab birds and (Fish and aquatic mammals. insects) III -IV (Birds and No documented field effects on mammals) I- wildlife. Low toxicity in lab birds and III(Fish and mammals. aquatic insects) IV -V (Birds and No documented field effects on mammals) II -III wildlife. Low toxicity in lab birds and (Fish and aquatic mammals. insects) IV -V -(Birds and No documented field effects on mammals) IV- wildlife. Slightly toxic to aquatic invertebrates. No documented impacts in birds or mammals. No documented field effects in wildlife. Low acute oral and dermal toxicity in laboratory mammals. Toxic to fish. streams. Use buffer zones if applying near wetland or other waters. Use caution in areas where groundwater contamination is likely. Apply according to label instructions. Avoid contaminating wetlands, ponds, lakes, and streams. Apply according to label instructions. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Apply according to label instructions. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Use drift precautions. Apply the amine formulation in areas where drift is a concern. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Apply according to label directions. Avoid spray drift. paraquat (Cyclone) (Gramoxo ne- Extra) pendimeth Dinitro- alin anilien (Prowl) picloram Pyridine (Tordon) ' • primisulfu Sulforiyl- ron • ure a ' (Beacon) quizalofop Aryloxy- (Assure) phenoxy- propionic Acid sethoxydi Cyclohex- m (Poast) anedione x> - thifensulfu Sulfonyl- ron urea (Pinnacle) triallate Thiocarb- (Fargo) `amate • tribenuron ,Sulfonyl- (Express) urea trifluralin Dinitro- (various) aniline (Fish and aquatic invertabrates) I -(Fish and aquatic organisms) (waterfowl embroyos, embroyos, mammals/bird) IV -(Birds and mammals) I -(Fish and aquatic insects) IV -V (Birds and mammals) I - (Fish) IV -V -(Birds, mammals, fish and aquatic insects) IV -V (Birds and mammals) I - (Fish) IV -V (Birds and mammals) IV - (Fish and aquatic insects) IV -V -(Birds mammals and aquatic insects) II -(Fish) IV -V -(Birds and mammals) I -II - (Fish and aquatic insects) IV -V (Birds, mammals and fish) III (Aquatic invertebrates) IV -(Birds and mammals) I -(Fish and aquatic insects) FUNGICIDES Pesticide (Trade name) Family benomyl Benzimida- (Benlate) zole • chlorothaloni Aromatic 1 (Bravo) iprodione (Rovral) Toxic to fish and other aquatic Use a buffer zone when applying near wetlands organisms, duck egg embryos. slightly or other water areas. Avoid direct applications to toxic to mammals and birds. wildlife and nests. No documented field effects on wildlife. No documented field effects on wildlife. Low toxicity in lab birds and mammals.Toxic to early life stage of fish. No documented field effects on wildlife. No documented field effects on wildlife. Low toxicity in lab birds and mammals. Avoid contaminating wetlands, lakes, ponds and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Use buffer zones when applying near water areas. Should not be used where groundwater contamination is likely. Apply accordin& to label directions. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. No documented field effects on Avoid contaminating wetlands, ponds, lakes, and wildlife. Low toxicity in lab birds and streams. mammals. No documented field effects on wildlife. Slightly toxic to aquatic invertebrates. Avoid spray deft. Avoid contaminating wetlands, ponds, lakes, and streams. Very low acute and subacute toxicity Avoid contaminating wetlands, ponds, lakes, and to birds and mammals. Highly toxic to streams. fish and aquatic insects. No documented field effect on Avoid spray drift and contaminating wetlands, wildlife. ponds, lakes, and streams. High toxicity to aquatic invertebrate Avoid contaminating wetlands, ponds, lakes, and and fish. streams. Toxicity class V -(Birds and mammals) I -(Fish) V -(Birds and mammals) I -(Fish and aquatic insects) Dicarboximide V -(Birds and mammals) I -(Fish and Documented effects on wildlife Toxic to fish and aquatic insects. No documented field effects on wildlife. No documented field effects on wildlife Best measures to reduce the risk of exposure Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and mancozeb (Dithane, Manzate, Penncozeb) propiconazol e (Tilt) thiabendazol e (Mertect) Ethylenebis dithio- carbamate Triazole aquatic insects) V -(Birds and mammals) I -(Fish and effects on wildlife. aquatic insects) IV -V -(Birds and mammals) I -(Fish and effects on wildlife aquatic insects) No documented field No documented field Benzimidazole V -(Birds and No documented field mammals) I -(Fish and effects on wildlife aquatic insects) triadimefon Triazole (Bayleton) thiophanate methyl (Topsin-M) V -(Birds and No documented field mammals) I -(Fish and effects on wildlife aquatic insects) Benzimidazole IV -V -(Birds and mamals) I -(Fish and aquatic insects) No documented field effects on wildlife Toxicity class data is based on acute oral rate median lethal dose (LDSO) valu chemical. The five toxicity classes used are: Class 1 - Extremely toxic II - Highly toxic III - Moderately toxic IV - Slightly toxic V - Relatively toxic LDSO < 40 mg/kg • LDSO 41-200 mg/kg LDSO 201-1,000 mg/kg LDSO 1001-5,000 mg/kg LDSO > 5,000 mg/kg streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. es for acute toxicity comparisons among City opeollin9 Agenda Item No.: 3-D Mtg. Date: 03/25/02 INCORPORATED JANUARY 24, 1957 NO. 2 PORTUGUESE BEND ROAD ROLLING HILLS, CALIF. 90274 (310) 377-1521 FAX: (310) 377-7288 E-mail: cityofrh@aol.com MEMORANDUM TO: CRAIG R. NEALIS, CITY MANAGER FROM: APRIL HOUSTON, ADMINISTRATWE INTERN SUBJECT: PESTICIDE ORDINANCE FOLLOW-UP ON NORTHERN CALIFORNIA CITIES OF SEBASTOPOL AND FAIRFAX DATE: MARCH 19, 2002 In following up on Councilmember Pernell's inquiries regarding the regulation of backyard use of pesticides at our City Council meeting six months ago; I spoke with the City of Sebastopol and the Town of Fairfax. The City Clerk at Sebastopol said that their proposed ordinance was never adopted, and has not been reconsidered by the City Council. However, when speaking with the Town Clerk of Fairfax, she said that their Pesticide Ordinance has been in effect for a year and it has not resulted in any citations. She stated that the ordinance is more of a courtesy to residence, requiring public notification 48 hours prior to pesticide use; and that pesticide companies are also required to post notifications. She added that there have been a few requests for pesticide ordinance packets from the community. (I have attached the brochure packet that they faxed to us). In addition, the Fairfax Town Clerk indicated that they have been threatened by pesticide industries for a possible litigation under the provision that state law regarding pesticides preempts local jurisdiction. Please let me know if you require further information ajh pesticide.memo Printed on Recycled Paper. 44 Exceptions • to notification provisions of this chapter not apply to the following: • 'he use of an aerosol product with a directed j, in containers of eighteen fluid ounces or when used to protect individuals from an inent threat from stinging.and biting insects, iding venomous spiders, bees, wasps and ets. This section shall not exempt from ication the use of any fogger product or sol product that discharges to a wide are; 'he use of non-volatile insect or rodent bait in nper resistant container; The use of boric acid; I'he use of horticultural soap and oils that do :ontain synthetic pesticides or synergists; [he application of a granular pesticide, where iular.pesticide means any ground applied solid icicle that is not a dust or powder; - The application of a pesticide by direct ction into a plant; The spot application of a pesticide, where spot Iication means the application of pesticide in manually pressurized .or non -pressurized tainer of thirty-two ounces or less to an area of and less than nine square feet. N ine square feet maximum area to be exempted once per year ►rohibit a cumulative exception. 0.50 nualnotification of Ordinance No. 687 shall be en by the Town to all businesses' in Fairfax that 1 pesticides and all listed Marin County ;finesses that apply pesticides as a regular vice to their customers. .10.60 Enforcement: e first violation of'this chapter within a three ai• period shall constitute a public nuisance. The second violation within the same three year period shall constitute an infraction. The third violation within the same three. year period shall constitute a misdemeanor and the penalties will be applied according to existing law. 8.40.70 Education: Education will be a key component of success for this ordinance. In that light it is suggested that residents refer to the county of Marin and it's Master Gardener Program to learn about Integrated Pest Management (IPM) techniques and how they can utilize such a program at their residence. Information may also be obtained from the Marin Stormwater Pollution Prevention Program (MCSTOPP), the Marin Agricultural Commissioner's office, and the University of California Agricultural Extension office in Novato. For additional information, or to obtain a Pesticides Alert Neighbor Notification form, please contact staff (it Town Hall. The Pesticides Alert Neighbor Notification form may be reproduced for compliance with the noticing requirements. TOWN OF FAIRFAX PESTICIDE ORDINANCE 142 Bolinas Road Fairfax, CA 94930 415-453-1584 8T9IE t' Ib Xt.d Idd .d0 NMOl FAIRFAX TOWN CODE TITLE 8 HEALTH AND SAFETY CHAPTER 8.40 esticides, the Prohibition of Use on airfax Parks, Open Space Parcels, and ul lights of Way Including Both Aerial pi al King and Ground Applications and the ublic Notice of Pesticide Use on Private roperty .40.010 Purpose: 'he use of pesticides with known carcinogens in Town of Fairfax is of such great concern to ►e Town Council that in order to protect the ealth, safety and welfare of Fairfax residents this rdinance is being adopted. The Town Council is ormalizing Fairfax's official policyofNOTusing ,esticides on Fairfax parks, open space parcels nc ►lic rights of way including both aerial pr_, ...g and ground applications; and, requiring t►blic notice entitled "neighbor notification" 'rior to pesticide use on private property. tesidents of Fairfax have a right to know when 'esticides are being used in their neighborhood on Irivate property iii order to allow time to take irecautions to protect themselves, their family, nets and property from the hazards of pesticide :xposure. The headwaters for Corte Madera Creek are the Fairfax and San Anselmo (Cascade) Creeks which traverse the town limits. Coho salmon and steelhead (native to these creeks) have been listed as threatened under the Federal endangered Species Act. 8.40.010 Definition: Pesticide: For purposes herein, pesticide shall mean any spray adjuvant, substance or mixture of substances, which is intended to be used for defoliating plats, regulating plant growth or for preventing, destroying, repelling, or mitigating any pest which may infest or be detrimental to vegetation, man, animals or households, or be present in any agricultural or non-agricultural environment, including fungicides, herbicides, insecticides, nematicides, rodenticides, desiccants, defoliants, and plant growth regulators. 8.40.30 The use of pesticides on Fairfax parks, open space parcels and public rights of way and buildings owned and maintained by the Town of Fairfax, is hereby prohibited 8.40.31 Use: The "use" shall be defined as both aerial and ground spraying and or dusting and all other ground application. 8.40.32 Exceptions: The only exceptions to the use of pesticides under section 8.40.30 are the same as those found in section 8.40.44; and, in addition an exception may be approved by a 2/3's super majority vote of the full Town council with a mandatory finding that the health, safety and welfare of the community is so threatened that an emergency exists, that no reasonable alternative is available and the prohibition of the use of pesticides would ,create the potential for allowing a significant adverse impact on the town. • 8.40.40 Neighbor notification: Prior to the use of pesticides on private property notice shall be required (see listed exception, Section 8.40.44) 8.40.41 Timing of Notice: Neighbors of the affected properties shall receive a minimum of 48 hours notice prior to the application of pesticides. 8.40.42 Type of notices required: A visible 8 '/, x 11 Pesticides Alert notice on a form approved by the Town of Fairfax shall be posted in a conspicuous place on the front of the property where the pesticide application will occur and an approved written notice delivered 48 hours in advance either by a mail service or a hand delivered 8 '/2 x 11 notice attached to an accessible front door or front gate if locked of every separate residential unit within 150 feet of the posted property. The notice shall include the address and approximate location of the pesticide application, date and estimated time of use, the type of pesticide being used and an appropriate 800 number for information regarding the product content and potential impacts. The notice shall remain posted for 48 hours after pesticide use. 8.40.43 Distance of notification coverage: All separate residential units within 150 feet of the parcel where pesticide application is to occur shall receive proper written notification as set forth in section 8.40.42. 4m • IV 0' •N .tD N W 8T9TE909Tb XV.delIdd J0 NM01 .D • G) m 'N Ciiy RAn9 �ue� INCORPORATED JANUARY 24, 1957 NO. 2 PORTUGUESE BEND ROAD ROLLING HILLS, CALIF. 90274 (310) 377-1521 FAX: (310) 377-7288 E-mail: cityotrh@aol.com MEMORANDUM TO: CRAIG R. NEALIS, CITY MANAGER FROM: LINDSEY BLEY, ADMINISTRATIVE INTERN SUBJECT: NOTICES OF PESTICIDE USE DATE: SEPTEMBER 10, 2001 The City of Sabastopol recently proposed an ordinance to require notification to neighbors prior to pesticide use. As of September 5 nothing had been decided, but the city is considering putting together a citizen committee to help decide whether an ordinance is necessary. However, the Town of Fairfax has an approved Pesticide Ordinance to require the notice of pesticide use. Overall, the two ordinances have the same basic requirements. The ordinances contain the following information: Timing of notice: Properties must be notified 48 hours in advanced prior to pesticide use. Type of notice: A Pesticides Alert notice must be posted in front of the property where the pesticides will be applied on a visible 8-i/2 by 11 sheet approved by the city. The notice must also be either hand delivered or sent through mail service 48 hours in advance to any residential unit within 150 from the posted property. Included in the notice: The notice should include the address and location of the pesticide application, date, time, type of pesticide, and an 800 number that would provide information on the pesticide being used. Exceptions: -non aerosol products with a direct spray in a container of 18 fluid ounces or less, when used to prevent individuals from an imminent threat from stinging or biting insects. -The use of non-volatile insect or rodent bait in a tamper resistant container. -The use of boric acid. -The use of horticultural soap and oils that do not contain synthetic pesticides or synergists. -Application of granular pesticides ( not a dust or a powder) Printed on Recycled Paper. fri •4JY— -Application of pesticides through direct injection into a plant. -Spot application of pesticides, in a manually pressurized container of thirty two ounces or less to an area of less than nine square feet. Enforcement: Within a three year period, the first violation will constitute a public nuisance, the second violation will constitute an infraction, and the third violation will constitute a misdemeanor and the penalties will be applied according to existing law. Note: Differences in the two Ordinances • .. The proposed ordinance for the City of Sebastopol requires neighbor notification prior to the use of brand name products such as Round -up and Weeds be Gone, on private property. • The Town of Fairfax requires the notice to remain posted for 48 hours after the application of pesticides. Please let me know if you require further information. lcb pesticide.memo TO: CRAIG R. NEALIS, CITY MANAGER FROM: LINDSEY BLEY, ADMINISTRATIVE INTERN SUBJECT: PESTICIDES DATE: SEPTEMBER 5, 2001 The following is a summary of the information contained in the attached packet "Wildlife and Pesticides: A practical guide to reducing the risk." The packet includes information on the risks of using pesticides and the harmful effects that pesticides have on humans, livestock, and wildlife when proper care is not exercised during application. Wildlife may be exposed to pesticides through contaminated food or water, breathing pesticides, or even by skin absorption. The magnitude of the effect depends on; the pesticides toxicity and the quantity used. There are many different kinds of pesticides; however, according to the packet insecticides pose the greatest threat to wildlife. The insecticides that are currently used are either the organophosphate or carbamate type. The packet goes on to explain that Wildlife may experience lethal or sublethal effects without direct exposure by destroying or disrupting a food source. Included in the packet of information are ways to reduce the risks involved with pesticide use. There are a number of suggestions of what to do before the application of pesticides, what to look for to avoid any potential hazards, and even a specific method that is referred to as being the best method of reducing the risks to wildlife, the integrated pest management (IPM) practices. Under IPM pesticides are only used when other methods are not successful. These methods include; crop rotation, cultivation, planting resistant varieties, planting weed and disease free °seed, and using the natural controls present. Overall, the packet contains some important information pertaining to proper pesticide use, including a detailed list of what to do and not to do when applying pesticides. 15 rn�e.2o� kook:. --.c,' ��- 4 Wildlife and Pesticides: A practical guide to reducing the risk • Introduction • Potential Hazards to Wildlife • Effects of Pesticides on Wildlife • Assessing Pesticide Risk to Wildlife • Reducing Pesticide Exposure Risk • Pesticide Toxicity to Wildlife • Summary • Toxicity Tables Pesticides are widely used in agriculture today. Producers use pesticides because they are effective and generally reasonably priced. The benefits include reduced yield losses and timesavings to the producer, and lower food and fiber costs for consumer. There are some downside risks to pesticide use. Pesticide poisonings of people, livestock, and wildlife have occurred when proper care was not exercised. Pesticide applicators must be very careful to avoid these risks. Pesticides, when used with good judgement and care in accordance with label instructions, benefit both agriculture and the environment. Proper use ensures that food and wildlife production objectives can both be realized. Every pesticide applicator must accept responsibility to prevent or minimize the effects of pesticide applications on nontarget organisms. There are several things you as an applicator can do to reduce the risk of pesticide exposure to nontarget plants, . animals and habitats. Potential Hazards to Wildlife In order to better protect wildlife from the risks of pesticide exposure it is necessary to understand what effects pesticides may have on wildlife. Several hundred different pesticides are used in agriculture today. Each one of these products has different characteristics that can affect the risk posed to different types of wildlife. While a particular pesticide may pose no harm to mammals, it may cause severe harm to aquatic or bird life. Knowing these differences will greatly assist you in making the proper pesticide use decision. There is much documentation showing that wildlife can be harmed by particular pesticides. The documentation includes laboratory toxicity studies on various types of wildlife, field trials that must be performed in order to register the pesticide, and reports of incidents of wildlife poisoning. In Oregon in the 1970s, aldrin and mercury treated seed grain killed thousands of wild geese and other wildlife. Thirty-six Canada geese were killed in 1988 as a result of an application of carbofuran (Furadan) and disulfoton (Di-Syston) in Idaho. Phorate (Thimet) was involved in the deaths of hundreds of waterfowl and several bald and golden eagles in South Dakota m 1989. Many of the incidents involving wildlife kills result from misuse or illegal applications. One such incident occurred in 1990 when an applicator in North Dakota illegally applied carbofuran (Furadan) to carcasses for predator control. He was found guilty of killing several forms of wildlife, possibly including a bald eagle. Effects of Pesticides on Wildlife Pesticides' effects on wildlife may be lethal, sublethal, acute, chronic, habitat related, or there may be no effect. In general the risk a pesticide poses to wildlife is related to the pesticide type, its toxicity, the proximity of the application to wildlife habitat, the dose, application rate, number of applications, the persistence of the pesticide in the environment, and its ability to concentrate in the wildlife food chain. These factors interact with food habits and behavior of individual wildlife species to produce a response. Pesticide Type In general, insecticides are more toxic to fish and wildlife than herbicides or fungicides. Some herbicides may harm wildlife by damaging the wildlife habitat. Many of the insecticides currently used are either the organophosphate or carbamate type. These insecticides work by interfering with the central nervous system of insects. The central nervous system of fish or wildlife may be affected the same way. The toxicity of the various organophosphate and carbamate insecticides ranges from slightly toxic products to products that are highly toxic. The more toxic products are generally restricted use pesticides, which require applicators to be certified by their state regulatory agency to purchase and apply products. Synthetic pyrethroid insecticide use has been increasing. These synthesized insecticides are based on naturally occurring pesticides, but have been modified to improve performance and persistence. Synthetic pyrethroids also work by interfering with the central nervous system. Synthetic pyrethroids are low to medium in toxicity to mammals and birds because they can quickly detoxify and excrete them`However, fish and aquatic invertebrates can not quickly detoxify or excrete synthetic pyrethroids, so they are highly susceptible to poisoning by these products. Herbicides and fungicides are generally low to moderately toxic to wildlife. Particular herbicides can have a large impact on the plant life making up the wildlife habitat. Direct Effects Wildlife can be exposed to pesticides directly by eating contaminated food or water, breathing pesticides, or by skin absorption. The type and magnitude of the effect depends on two factors, the_pesticide toxicity and pesticide quantity (dose). If exposure causes the animal's death, it is referred to as a lethal effect. Young birds that eat or are fed pesticide treated insects are at great risk of suffering lethal pesticide exposure effects. Sublethal insecticide effects occur when damage to the central nervous system causes an animal to behave in a unusual manner. This behavior may affect the animal's ability to survive or reproduce. Some typical sublethal responses in birds exposed to pesticides include the inability to sing properly, establish a breeding territory, or attract a mate. Adults may be unable to care for themselves or their young properly, resulting in death to the nestlings or increased chance of predation. The lethal and sublethal effects of pesticides on wildlife and fish may occur from one exposure over a short time period (acute) or they may result from exposures to small amounts over a longer time period (chronic). Pesticides commonly used today do not persist as long in the environment as pesticides used years ago. The tradeoff is that the acute toxicity of some of these modern pesticides is higher than the older, more persistent chemicals. Indirect Effects Wildlife in general, and birds in particular, may also experience lethal or sublethal effects without being directly exposed to a pesticide. This typically occurs when a pesticide application destroys or disrupts food sources such as insects. Insects supply the protein necessary for growing birds. Studies indicate that the growth of young birds can be stunted in areas where insecticides have been used heavily, resulting in insect populations too low to meet young bird protein growth demands. Fish that feed on aquatic insects and animals may also show stunted growth in areas of heavy insecticide use because their primary food sources are killed. Inadequate diets also can affect fish reproduction and survival. Herbicides can reduce the amount of cover and make the habitat less suitable for nesting. Assessing Pesticide Risk to Wildlife To properly assess the need for pesticides and the risk to wildlife, information must be gathered on the condition of the crop, the pest situation, characteristics of candidate pesticides, present and expected weather, and some knowledge about the kinds and behavior of wildlife living in the area. The importance of good judgement, practical experience and common sense cannot be overemphasized. Prior to each and every pesticide application, the overall situation should be evaluated so that the expected benefits of a pesticide application are realized and potential hazards are minimized. Good information is necessary to make good judgements. Monitor Fields Regularly Field scouting must be done. It is important to be aware of the status of the field, the crop stage, general health, and yield potential of the crop, as well as the number and growth stage of the various pests that are present. Careful scouting will reveal any wildlife that may also be present. Most pests and most wildlife do not occur uniformly throughout a field. Drawing a map of the field showing the locations of pest populations and wildlife along with recognizable landmarks can aid you in developing a pest control plan that avoids possible effects on wildlife. Identify Wildlife Signs, Seasons, and Habitats One way to ensure that wildlife will not be impacted by a pesticide is to make the application when wildlife are not present. Most wildlife signs can be easily determined while scouting the fold. Virtually all agricultural crops will support some type of wildlife. A.wide assortment of wildlife will likely be visible during most scouting trips. Areas where wildlife are most likely to be located are field perimeters and other areas where fields may come into contact with windbreaks, wetlands, livestock watering ponds, fence rows, abandoned farmsteads, grasslands or odd areas. Take note of areas where you actually see animals. Other evidence that wildlife are present and using the area includes signs such as tracks, droppings, or foraging evidence. If numerous wildlife signs arc present, pesticide applicators can reduce potential impacts to wildlife by marking such areas on a field map or leaving a flag in that area of a field. When spraying around sensitive areas, leave a buffer zone of at least one-half the width of a sprayer boom. Another way to minimize potential impacts to wildlife is to restrict spraying activities in these fields between the hours of 10 a.m. and 4 p.m. During this period, many wildlife will seek the protective cover of cropland, particularly taller row crops, as they wait out the day prior to beginning evening and early morning foraging activities. Critical Reproductive Periods and Habitats Most wildlife reproduction occurs from May 1 to late June and early July. This is perhaps the most critical for many of our resident and migratory wildlife and fish. To complete this reproduction, animals seek out suitable habitats. These habitats can include wetlands, windbreaks and shelterbelts, fencerows, rangelands, and croplands. Wildlife typically nest, birth, feed, and rear their young in areas that provide not only some type of protective coyer from the elements and potential predators, but also sources of food. The transition zones between habitat types, where one plant community changes to another, are preferred. These edges usually produce the greatest variety of food plants, insects and seeds. This allows wildlife such as grouse, pheasants, and deer to feed without venturing too far from protective cover. For this reason, most upland gamebird nests can be found in or near such edges. Wetlands are important feeding and brood rearing habitats for waterfowl. Insecticides applied near wetlands by ground sprayers or aircraft can enter the habitat through drift or runoff and contaminate these areas. Depending on the insecticide type, food sources may be destroyed, causing sublethal effects or a direct loss of young wildlife. Similarly, shelterbelts and windbreaks are important habitats for many songbirds. Herbicide drift that results in injury to trees and other vegetation can impair the ability of such habitats to provide safe, secure nesting sites. Insecticide drift can kill nestlings and adult birds, as well as contaminate important insect food sources. Reducing Pesticide Exposure Risk Regular field scouting and a pest control plan should be a part of every producer's operation. Pests are best controlled by manipulating cropping conditions to put pests at a disadvantage to the crop or beneficial organisms. Man and his crops are in competition with pests, and ALL available methods for controlling pests should be considered, not just pesticides. Eliminate Unnecessary Pesticide Applications Through IPM .Few applicators knowingly apply unnecessary pesticides because pesticides cost money. Every applicator should ask, will this application pay for itself? Growers should not substitute pesticides for good management. Pesticides are necessary but should only he part of a total pest control program, not the entire program. The -best method of reducing risks to wildlife is to use integrated` pest management (IPM)' practices. IPM incorporates cultural methods such as crop rotation, date of planting, variety choices, and seeding rates with other methods of pest control to mammta •pest populations at tolerable levels. Under IPM, pesticides are used only when other methods are not successful and pest damage to crops might otherwise exceed the cost of control. Many pest management practices can help reduce the need for pesticides. Some additional control methods include crop competition, crop rotation, tillage and cultivation, sanitation, planting resistant varieties, planting weed and disease free seed, and using the natural controls present when possible. A good example of non -pesticide control is a competitive crop. An early established, well developed crop can do much to help control weeds. Plants emerging first have a competitive advantage over later emerging plants. Anything done to get quick crop emergence that evenly covers the ground early will have a big impact on weeds. Later emerging weeds are ata tremendous disadvantage and may not cause yield and quality losses. The competitiveness of weeds and crops differs between species. Weeds such as wild oats, wild mustard, and kochia are very competitive, while others, such' as redroot pigweed and foxtails are generally less competitive. Some crops ranked in order of decreasing competitiveness are rye, barley, conventional height wheat, semidwvarf wheat, and flax. Choose the Pesticide Least Toxic to Non -target Organisms Choose the least toxic pesticide that will control the pest. Often more than one pesticide is registered for control of a particular pest in a particular crop. Take time to compare pesticides and make sure you choose the one BEST suited for the job. Many times the best choice will be the least expensive treatment, but that is not always the case. Sometimes the best choice would be a higherpriced pesticide with fewer risks for nontarget plants and animals. Pesticide Toxicity to Wildlife Pesticide applicators can plan a pesticide application that is less toxic to wildlife by examining pesticide toxicity and potential for environmental injury to wildlife and wildlife habitats. This information can be found in tables presented in the back of this publication. When an applicator has identified the specific crop pest situation and checked local crop production guides, a pesticide can be selected that minimizes risk to nontarget plants and animals and still achieves the desired level of control. If the selected pesticide still poses a high threat to wildlife, the applicator would at least be aware of the -risk and can take the steps to minimize any potential threats by following recommendations in this publication. Read the Pesticide Label Certain pesticides pose a risk to wildlife or the environment. Some products are classified as RESTRICTED USE PESTICIDES because of.environmental hazards. Restricted use pesticides should only be applied by a certified applicator who_ has been properly trained. • Pesticides that pose environmental risks are labeled to warn the applicator what the risks could be and what steps should be taken to protect people, animals and the environment. These.wamings can be found in the "Precautionary Statements'.section of the label. The precautionary section is divided into subsections dealing with "Hazards to Humans or Domestic Animals," Environmental Hazard" and "Physical or Chemical Hazard." The risks to wildlife and the environment may be found in the "Environmental Hazard" section. It is a violation of federal law to apply pesticides in any way that is not consistent with label instructions. Hazards to Wildlife If a particular pesticide is especially hazardous to wildlife, it will, be stated on the label. For example: • . This product is highly toxic to bees. • This product is toicic.to fish. • This product is toxic to birds and other wildlife. The label may indicate that the product causes undesirable effects in the environment. In this case, the precautionary statement may tell what to avoid doing. Labeling may•mdIcatelimitations.imposed.to pr..otect;w,ildli.fe',yinclu'di g endangered -species. These limitations may include reduced rates, restrictions on types of application, or a ban on the pesticide's use witliiiTthe species range. The labclial— ^o ay mdicato-additional--sources-of information-on-proper=application=methods-to-reduce-hazardc: These statements explain special hazards that the pesticides may pose. They should+help when choosing the safest product for a particular job and serve as a reminder to take extra precautions. General Environmental Statements General-environmental_Tstatements:appearon=nearlyev—e pesticiderlabel:as:reminders-fof_commonusense-actions-neededto avoid contaminatingtheenvironment3The-absence=ofanyonall ofithese:statements.DOES=N:OTYchangeahezequirement.to dakezadequate:precautionsa Sometimes the statements will follow a "specific toxicity statement" and provide practical steps to avoid harm to wildlife. Examples of general environmental statements include: • Do not apply when runoff is likely to occur. • Do not apply when weather conditions favor drift from treated areas. • Do not contaminate water when cleaning equipment or disposing of wastes. • Keep out of any body of water. • Do not allow drift on desirable plants or trees. • Do not apply when bees are likely to be in the area. • Do not apply where the water table is close to the surface. Note:ILbis:the responsibility -of every-peshctde-applicator-tolread-and=follow:theLLlabel-directions: Use the Lowest Effective Rate Many times the label will allow a range of rates to -control a particular pest: Differences in pest size or stage, pest populations, t'and environmental conditions can affect the amount of pesticide needed. Often pesticide rates at the lower end of the rate range can be used when pests are in sensitive growth stages, at lower populations and the weather and growing conditions are favorable. Use Buffer Zones Anarea between•the area sprayed and a sensitive area is called a buffer zone. This area can be a grass strip or may even be part of the crop that is not treated. This buffer area will help trap pesticides and prevent them from entering sensitive areas by spray drift or by runoff Spot Spraying Many. times a pest is located only in a portion of the field. Spraying only the area where the pest is found, leaving the rest of the (field untreated, reduces potential risks and saves time and money. Begin Spraying In the Middle of the Field Most wildlife will be present near the edges of a field. Spraying the field by starting in the middle of the field will allow wildlife time to escape or move out of the field area. Trap Areas Some farmers are experimenting with the use of trap areas. Farmers will seed these areas with an early maturing crop variety ahead of normal planting dates. These areas may attract pests and if pest populations develop in the trap area, a pesticide application can be made. Controlling pests in this manner can reduce chances that pesticides will be required on the rest of the field. Check Weather Conditions A -good applicator always checks the weather conditions before spraying. Weather conditions can greatly affect the pesticide exposure through spray drift or runoff. Don't apply pesticides just before rains because pesticides could run off the treated field with excess rainwater and potentially contaminate sensitive areas. Avoid spraying when weather conditions could cause spray drift into sensitive areas. Avoid Spray Drift Spray drift can cause damage to wildlife or wildlife habitat. The following measures are available to greatly reduce drift, Avoid spraying on windy days Check the wind speed and direction. If conditions could cause spray drift into sensitive areas, don't spray. If an application must be made you must take every precaution you can to prevent drift from entering sensitive areas. Another weather condition to avoid is a temperature inversion. Temperature inversions occur when cooler air is near the ground and is beneath warmer air. Very small spray droplets will remain suspended in the air and can move some distance. Use a nonvolatile formulation Some pesticides are volatile and can form vapors, usually on warmer (greater than 70 F) days, which can drift into susceptible areas. If there is an alternative pesticide or formulation that is not' volatile and will control the pest, it should be used instead. Increase Droplet Size Spray nozzles produce spray droplets of many different sizes. Larger droplets are heavier and drift less. Practices that increase droplet size will reduce drift, such as increasing nozzle size or water volume, reducing spray pressure or using a drift retardant. Use Larger Nozzle Larger nozzles allow you to apply the same volume of spray with less spray pressure. Spray droplets will be larger than those produced by a smaller nozzle with higher pressure. Increase Water Volume Increasing the water volume will decrease drift because water droplets will be larger and will tend to drift less. Use the Lowest Practical Pressure Lower spray pressure will result in larger spray droplets that drift less than smaller droplets. If spray pressure is reduced too much the spray pattern that results will not be uniform. Newer nozzles such as the "LP" or "XR" type are designed to produce uniform spray patterns with pressures of 15 to 20 pounds per square inch. Use a Drift Retardant A drift retardant will help reduce spray drift by increasing the size of spray droplets. Larger droplets tend to drift less than small droplets. Reduce Spray Boom Height Set spray booms at the lowest height that will give uniform coverage. The closer the boom is to the spray target the less chance there is for drift. Use a Shielded Sprayer Using a shielded sprayer will help reduce spray drift by protecting the spray from wind. Shielded sprayers allow a wider selection of spraying times during the day and more total spraying time per day. These time savers can be used to more precisely target crop areas and avoid sensitive areas. More information on spray drift can be found at your state's Cooperative Extension Service county office. Summary The responsibility to prevent or minimize the effects of pesticide applications on nontarget organisms rests with every pesticide applicator. Information concerning the proper use and application of a pesticide can be found on the product label. Reducing the risk of pesticide exposure to nontarget organisms requires applicators to incorporate crop scouting and IPM ,techniques with a knowledge of wildlife life cycles and habitats in developing a farm pesticide application plan: Development. of such a plan will insure not only the most cost effective means for controlling crop pest situations, but also result in the greatest reduction of risk of pesticide exposure' to wildlife. Resource Material Apply Pesticides Correctly: A Guide for Commercial Applicators, U.S. Department of Agriculture and U.S. Environmental Protection Agency. Commercial and Private Applicator Core Manual: Initial Certification, September 1989, Cooperative Extension Service, Michigan State University. Dexter, A. Herbicide Spray Drift. 1986. NDSU Extension Service. A-657 revised. Extoxnet Cooperative Extension Offices, Comell, U of Calif., Michigan State, Oregon State Univ. Facemire, F. Charles, 1991. Impact of agricultural chemicals on wetland habitats and associated biota with special reference to migratory birds. B 780, SDSU, Brookings, SD. 65 pp. Herbicide Handbook of the Weed Science Society of America. Sixth Ed., 1989, Weed Science Society of America, Champagne, Illinois, 61820. McBride,.D.K., D.E. Peterson, H.A. Lamey, 1988, Persistence and Mobility of Pesticides in Soil and Water, NDSU Extension Service. E-49, NDSU Fargo, ND 58105 Pesticide Applicator Training Manual: Core Manual, 2nd Ed., Chemicals -Pesticides Program, Cornell University, 1990. D. Rutz, Director, R. Gardner, W. Smith. Wildlife and Pesticides: A practical guide to reducing the risk (continued) Toxicity Tables These tables provide toxicity comparisons for commonly used pesticides. These comparisons are intended to give applicators the information needed to reduce the risk of an application to wildlife. INSECTICIDES Pesticide (Trade name) Family acephate Organo- (Orthene) phosphate Aldicarb Carbamate (Temik) azinphos Organo- ,uethyl phosphate (Guthion) Bacillus Microbial Thuringiensis (various) carbaryl Carbamate (Sevin) carbofuran Carbamate (Furdan) chlorpyrifos (Lorsban) diazinon (various) Organo- phosphate Organo- phosphate dimethoate Organo- (Cygon) phosphate Toxicity class III -(Birds and mammals) I- (Fish/aquatic insects) Documented effects on wildlife Moderate to slight acute oral toxicity to birds and mammals Reduction in ChE activity. Best measures to reduce the risk of exposure Increase water volumes to reduce drift. Avoid use areas of high bird numbers. Use lowest recommended effective rates. Avoid contaminating wetlands, ponds, streams and rivers. 1 -Birds, fish, mammals Bird and mammal mortality Proper incorporation of granules. Consider and aquatic insects) reported after ingestion of weather and terrain to avoid runoff potentials into exposed granules. One of water areas. the most toxic carbamate pesticides. Extremely toxicto aquatic organisms. I -(Mammals) I1 -IV Extremely toxic to Scout fields to determine the presence of wildlife. (Birds) 11 - mammals in formulations Avoid or delay direct application when wildlife is (Fish/aqurtic insects) containing a high present. Exercise caution to reduce the risk of V -(Birds and mammals) III -IV -(Birds III - (Mammals) I -(Aquatic insects) 1 -(All) I -II -(Birds) II -III- Highly toxic to mammals (Mammls) I -(Fish and and birds through oral aquatic insects) Extremely toxic to fish and aquatic insects. III -(Mammals) I- Extremely toxic to birds (Birds, fish and aquatic and moderately toxic to insects) mammals. Toxic to bees, fish, and other aquatic organisms. I -(Birds, fish, and Moderate acute oral aquatic insects) III- toxicity to mammals. percentage of active ingredient. Highly toxic to fish and aquatic insects: No documented effects on wildlife. direct, drift, or runoff applications to water or wetland areas. Avoid contaminating ponds,lakes, and streams. Apply according to label directions. Moderate acute/chronic • Avoid direct applications to wetlands and other toxicity to birds, fish, and waters. Reduce potentials for drift and runoff by mammals. Low persistence. using buffer zones. Toxic to aquatic insects. Highly toxic to all forms of Avoid applying this chemical when wildlife is wildlife even when applied present. Use buffer zones when applying near at lowest recommended wetlands, other waters, and wooded areas. Use an effective rate. alternate pestiicide. (Granular carbofuran has been voluntarily cancelled and will be phased out by 1994. Flowable is still registered.) Avoid contaminating wetlands, lakes, ponds, and streams. Do not apply when wildlife are present. Applications should be made only after a careful evaluation. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid application (direct, drift or runoff) on water areas/wetlands. Use buffer zones near water and (Mammals) disulfoton Organo- I -(All) (Di-Syston) phosphate endosulfan (Thiodan) esfenvalerate (Asana) Extremely toxic to birds, fish, and other aquatic organisms. Pheasants are particularly sensitive to this pesticide. Extremely toxic to birds, mammals, fish, bee and aquatic organisms. Secondary poisoning in birds eating treated insects has been reported. shelterbelts. Proper field scouting to include a careful evaluation of potential wildlife exposure will reduce the risk. Do not apply when wildlife is present. Chlorinated I -(Fish and aquatic Fish kills associated with Caution should be taken to avoid risks associated Hydrocarbon insects) I1 -IV (Birds) I- contaminated agricultural with agricultural runoff The use of buffer zone II (Mammals) runoff. Concentrates of will reduce risk associated with use of this <1.3 ppm were sufficient to pesticide. • cause mortality. Highly toxic to aquatic organisms/insects. Pyrethroid I (Fish) IV -(Bird and Highly toxic to fish, Measures to reduce the risks to wildlife. Avoid mammals) aquatic insects. No reported applications (direct, drift, runoff in water bodies,/ parathion Organo- • I -(All) (methy ethyl) phosphate (Penncap-M .various) fenvalerate Pyrethroid (Pydrin) fonofos Organo- (Dyfonate) phosphate malathion (Cythion) methidathion Organo- (Supracide OP) phorate (Thimet) I -(Fish) N-V(Bird and mammals) I(AII) toxicity in birds/mammals. Ethyl and methyl parathion are extremely toxic to birds, mammals through both acute oral and dermal exposure at recommended application rates. These chemicals are highly toxic to bees fish and other aquatic organisms. See Esfenvalerate wetlands. Use lowest recommended effective - rates and buffer zones near water. Prior to applying parathion a thorough scouting of the field should be conducted. Field applications of parathion should be made prior to 10 a.m. or after 4 p,m. to minimize drift and leave buffer zone near critical wildlife habitats such as windbreaks and wetlands. Do not apply when wildlife are present. See esfenvalerate. Highly toxic to fish, Complete incorporation of the product into the mammals and birds due to soil will minimize wildlife exposure risks. chemical action, high field Consider weather and terrain to avoid runoff use and relatively long contamination. persistence. Used as a granular treatment. Organo- III -(Birds and No documented effects on Avoid application (direct, drift or runoff) on water phosphate mammals) I -(Fish and wildlife (birds/ mammals) areas/wetlands. Use near buffer zones near water. aquatic insects) when used at recommended application rates. Toxic to bees, fish and other aquatic organism. • II(All) High acute oral toxicity to Careful scouting of field to identify the presence phosphate Organo- I(All) phosphate birds/mammals, bees and fish. Extremely high oral and dermal toxicity has been documented in birds and mammals after exposure to pesticide. Wildlife deaths reported are related to ingestion of improperly incorporated granules, in areas subject to flooding and run off. Uptake of chemical in plants may also of wildlife and the subsequent avoidance of such area and critical wildlife habitats during ,application will minimize wildlife exposure risks. In areas subject to flooding and runoff and where wildlife are present in large concentrations (migrations) the use of this pesticide should be carefully evaluated. The pesticide must be properly incorporated. terbufos (Counter) Organo- I(All) phosphate permethin Synthetic (Ambush pyrethroid Pounce) HERBICIDES Pesticide (Trade name) Family 2,4-D Phenoxy 2,4-D Amine 2,4-D Ester (see 2,4,-D) acifluorfen Biphenol (Blazer) ether alachlor Acetanilide (various) atrazine Triazine (various) bentazon Benzothia- (various) diazoles I -(Fish and aquatic insects) V -(Birds and mammals) cause wildlife exposure. Extremely toxic to lab mammals. Potential for greatest impact due to ingestion of granules. Extremely toxic to aquatic organisms. No documented field effects on birds or mammals. Toxicity class Documented effects on wildlife III -IV -(Birds and Moderately toxic to birds and mammals) II - (Fish and other aquatic organisms) III -V -(Birds) IV - (Mammals) I- II(Fish and aquatic insects) mammals. Highly toxic to insects, fish. A reduction of birds broad- leaved plants from applications can result in a reduction in the nest numbers of waterfowl and other upland nesting birds. Use of a non toxic oil vehicle during application increases toxicity of the chemical to egg embryos. Spray drift can harm wooded areas. No documented impacts on birds or mammals. Toxic to aquatic organisms. May damage susceptible foliage (cover). IV -V -(Birds and No documented impacts on birds and mammals) I -(Fish mammals. Highly toxic to aquatic insects and fish. and aquatic insects) IV -V -(Birds and Slightly toxic to birds at high mammals) IV - (Fish) HI -IV -(Birds, mammals and fish) bromoxyni Benzonitrile I -(Fish and 1 (Buctril) aquatic insects) II -IV -(Mammals and birds) clopyralid Pyridine IV -V -(Birds and (Stinger) mammals) II - concentrations. Indirect effects on aquatic fauna may result as the chemical impacts aquatic plant species. Toxic to fish and aquatic invertebrates at high concentrations. No documented impacts on birds and mammals. Moderately toxic to Rainbow trout. Extremely toxic to aquatic invertebrates No documented impacts on birds and mammals. No documented impacts on wildlife. Spillage, failure to cover granules, heavy rains or high winds could expose granules increasing the risk. If such conditions exist do not apply if wildlife is present. In areas subject to flooding and runoff and where wildlife are present in large concentrations (migrations) the use of this pesticide should be carefully evaluated. The pesticide must be properly incorporated. Risk can be reduced if applied as an in -furrow or modified in -furrow application. Prevent direct, applications or drift and runoff into wetlands and other water. Use a buffer zone if applied near water areas. Best measures to reduce the risk of exposure In areas where waterfowl and other upland nest apply with a water based spray mixture. Spot spray where possible to reduce impacts on potential nest cover. Avoid spray drift. Apply amine formulation where drift is a concern. Use a buffer zone when applied in wooded areas, or near water. Avoid spray drift. Use buffer zones near surface water. Avoid contaminating ponds, lakes, wetlands, and streams. Avoid spray drift and runoff contamination of wetlands and other water areas by using buffer zones. Avoid contaminating ponds, lakes, wetlands, and streams. To minimize the impacts of agricultural runoff carrying this chemical into wetlands and other waters employ buffer zones. Use at lowest effective rate.Use with caution in areas where groundwater contamination is likely. Avoid contaminating ponds, lakes, wetlands, and streams. Use buffer zones to reduce potential impacts to aquatic habitats. Do not apply when conditions favor drift. Avoid contaminating ponds, lakes, wetlands, and streams. Avoid spray drift. Avoid contaminating ponds, lakes, wetlands, and streams. Use buffer zones if applying near water areas. Avoid contaminating ponds, lakes, wetlands, and ethalflurali Dinitro- n aniline (Sonalan) fenoxapro Aryloxy- p (Whip) phenoxy- (Option) propionic Acid fluazifop Aryloxy- (Fusilade) phenoxy- propionic Acid glyphosate Amino Acid (Roundup) (Rodeo) Amino Acid cyanazine Triazine (Bladex) cycloate Thio- (Ro-Neet) carbamate desmedop Carbamate ham (Betanex) dicamba Benzoic (Banvel) Acid diclofop (Hoelon) Aryloxy- phenoxy- propionic Acid (Fish) 11I -IV -(Birds and mammals) V -(Birds) IV- (Mammals)1- (Fish and aquatic organisms) IV -(Birds and mammals) I -(Fish and aquatic insects). IV -(Birds mammals, fish, and aquatic insects) V -(Birds) IV - (Mammals) I - (Fish, and aquatic insects) difenzoqu Bipyridilium IV -V -(Birds) IV - at (Mammals) II - (Avenge) (Fish) I -(Aquatic insects) EPTC Thio- . IV -V (Birds and (Eptam) carbamate mammals) I -(Fish and aquatic insects) IV -V (Birds and mammals) I - (Fish) IV -V (Birds and mammals) I -(Fish and aquatic insects) IV -V (Birds and No documented field effects on mammals) I -(Fish wildlife. Low toxicity in lab birds and and aquatic mammals. insects) IV -V (Birds and No documented field effects on mammals) I -(Fish wildlife. Low toxicity in lab birds and and aquatic mammals. insects) III -IV Fish and aquatic insects. imaza- Imidazoline IV -V (Birds and methabenz mammals) II - (Assert) (Fish and aquatic insects) MCPA- Phenoxy- III -IV (Birds and amine carboxylic mammals) I- MCPA- Acid I11(Fish and ester aquatic insects) metsulfuro Sulfonyl IV-V'(Birds and n (Ally) Urea mammals) II -III (Fish and aquatic insects) Nicosulfur Sulfonyl- IV -V -(Birds and on mammals) IV - Rodeo is slightly toxic to aquatic organisms unlike its counterpart Round -up. No documented field effects on Slightly toxic to aquatic invertebrates. No documented impacts in birds or mammals. No documented field effects in wildlife. Low acute oral and dermal toxicity in laboratory mammals. Toxic to fish. No documented field effects in wildlife. Low toxicity to laboratory animals. Toxic to fish. No documented field effects on wildlife. Slightly toxic to aquatic invertebrates. No documented field effects on wildlife. No documented field effects on wildlife. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. streams. Use buffer zones if applying near wetland or other waters. Use caution in areas where groundwater contamination is likely. Apply according to label instructions. Avoid contaminating wetlands, ponds, lakes, and streams. Apply according to label instructions. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Apply according to label instructions. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and wildlife. Low toxicity in lab birds and streams. mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Avoid contaminating wetlands, ponds, lakes, and streams. Use drift precautions. Apply the amine formulation in areas where drift is a concern. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Apply according to label directions. Avoid spray drift. paraquat (Cyclone) (Gramoxo ne- Extra) pendimeth Dinitro- alin (Prowl) picloram (Tordon) (Fish and aquatic invertabrates) Bipyridilium I -(Fish and aquatic organisms) 11 -111 - (waterfowl embroyos, mammals/bird) IV -(Birds and anilien mammals) I -(Fish and aquatic insects) Pyridine IV -V (Birds and mammals) I - (Fish) primisulfu Sulfonyl- ron (Beacon) urea quizalofop Aryloxy- (Assure) phenoxy- propionic Acid sethoxydi Cyclohex- m (Poast) anedione thifensulfu Sulfonyl- ron urea (Pinnacle) triallate Thiocarb- (Fargo) amate tribenuron Sulfonyl- (Express) urea trifluralin Dinitro- (various) aniline FUNGICIDES Pesticide (Trade name) Family benomyl Benzimida- (Benlate) zole chlorothaloni Aromatic I (Bravo). iprodione (Rovral) IV -V -(Birds, mammals, fish and aquatic insects) IV -V (Birds and mammals) I - (Fish) • IV -V (Birds and mammals) IV - (Fish and aquatic insects) I V -V -(Birds mammals and aquatic insects) II -(Fish) IV -V -(Birds and mammals). 1 -II - (Fish and aquatic insects) IV -V (Birds, mammals and fish) III (Aquatic invertebrates) IV -(Birds and mammals) I -(Fish and aquatic insects) Toxic to fish and other aquatic Use a buffer zone when applying near wetlands organisms, duck cgg embryos. slightly or other water areas. Avoid direct applications to toxic to mammals and birds. wildlife and nests. No documented,field effects on wildlife. No documented field effects on wildlife. Low toxicity m lab birds and mammals.Toxic to early life stage of fish. No documented field effects on wildlife. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Slightly toxic to aquatic invertebrates. Avoid contaminating wetlands, lakes, ponds and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Use buffer zones when applying near water areas. Should not be used where groundwater contamination is likely. Apply according to label directions. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Very low acute and subacute toxicity Avoid contaminating wetlands, ponds, lakes, and to birds and mammals. Highly toxic to streams. fish and aquatic insects. No documented field effect on wildlife. High toxicity to aquatic invertebrate and fish. Toxicity class V -(Birds and mammals) I -(Fish) V -(Birds and mammals) I -(Fish and effects on wildlife. aquatic insects) Documented effects on wildlife Toxic to fish and aquatic insects. No documented field Dicarboximide V -(Birds and No documented field mammals) I -(Fish and effects on wildlife Avoid spray drift and contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Best measures to reduce the risk of exposure Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid • contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid . contaminating wetlands, lakes, ponds, and mancozeb Ethylenebis (Dithane, dithio- Manzate, • carbamate Penncozeb) propiconazol Triazole e (Tilt) aquatic insects) V -(Birds and mammals) I -(Fish and effects on wildlife. aquatic insects) No documented field IV -V -(Birds and No documented field mammals) 1 -(Fish and effects on wildlife aquatic insects) thiabendazol Benzimidazole V -(Birds and No documented field e (Mertect) mammals) I -(Fish and effects on wildlife aquatic insects) triadimefon Triazole (Bayleton) thiophanate methyl (Topsin-M) V -(Birds and No documented field mammals) I -(Fish and effects on wildlife aquatic insects) Benzimidazole IV -V -(Birds and mamals) I -(Fish and aquatic insects) No documented field effects on wildlife Toxicity class data is based on acute oral rate median lethal dose (LDSO) values chemical. The five toxicity classes used are: Class I - Extremely toxic LDSO < 40 mg/kg II - Highly toxic LDSO 41-200 mg/kg III - Moderately toxic LDSO 201-1,000 mg/kg IV - Slightly toxic • LDSO 1001-5,000 mg/kg V - Relatively toxic LDSO > 5,000 mg/kg streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. for acute toxicity comparisons among Wildlife and Pesticides: A practical guide to reducing the risk This information was obtained from NDSU Extension Service, North Dakota State University of Agriculture and Applied Science, and U.S. Department of Agriculture cooperating. • Introduction • Potential Hazards to Wildlife • Effects of Pesticides on Wildlife • Assessing Pesticide Risk to Wildlife • Reducing Pesticide Exposure Risk • Pesticide Toxicity to Wildlife • Summary • Toxicity Tables Pesticides are widely used in agriculture today. Producers use pesticides because they are effective and generally reasonably priced. The benefits include reduced yield losses and timesavings to the producer, and lower food and fiber costs for consumer. There are some downside risks to pesticide use. Pesticide poisonings of people, livestock, and wildlife have occurred when proper care was not exercised. Pesticide applicators must be very careful to avoid these risks. Pesticides, when used with good judgement and care in accordance with label instructions, benefit both agriculture and the environment. Proper use ensures that food and wildlife production objectives can both be realized. Every pesticide applicator must accept responsibility to prevent or minimize the effects of pesticide applications on nontarget organisms. There are several things you as an applicator can do to reduce the risk of pesticide exposure to nontarget plants, animals and habitats. Potential Hazards to Wildlife In order to better protect wildlife from the risks of pesticide exposure it is necessary to understand what effects pesticides may have on wildlife. Several hundred different pesticides are used in agriculture today. Each one of these products has different characteristics that can affect the risk posed to different types of wildlife. While a particular pesticide may pose no harm to mammals, it may cause severe harm to aquatic or bird life. Knowing these differences will greatly assist you in making the proper pesticide use decision. There is much documentation showing that wildlife can be harmed by particular pesticides. The documentation includes laboratory toxicity studies on various types of wildlife, field trials that must be performed in order to register the pesticide, and reports of incidents of wildlife poisoning. In Oregon in the 1970s, aldrin and mercury treated seed grain killed thousands of wild geese and other wildlife. Thirty-six Canada geese were killed in 1988 as a result of an application of carbofuran (Furadan) and disulfoton (Di-Syston) in Idaho. Phorate (Thimet) was involved in the deaths of hundreds of waterfowl and several bald and golden eagles in South Dakota in 1989. Many of the incidents involving wildlife kills result from misuse or illegal applications. One such incident occurred in 1990 when an applicator in North Dakota illegally applied carbofuran (Furadan) to -1- i J carcasses for predator control. He was found guilty of killing several forms of wildlife, possibly including a bald eagle. Effects of Pesticides on Wildlife Pesticides' effects on wildlife may be lethal, sublethal, acute, chronic, habitat related, or there may be no effect. In general the risk a pesticide poses to wildlife is related to the pesticide type, its toxicity, the proximity of the application to wildlife habitat, the dose, application rate, number of applications, the persistence of the pesticide in the environment, and its ability to concentrate in the wildlife food chain. These factors interact with food habits and behavior of individual wildlife species to produce a response. Pesticide Type In general, insecticides are more toxic to fish and wildlife than herbicides or fungicides. Some herbicides may harm wildlife by damaging the wildlife habitat. Many of the insecticides currently used are either the organophosphate or carbamate type. These insecticides work by interfering with the central nervous system of insects. The central nervous system of fish or wildlife may be affected the same way. The toxicity of the various organophosphate and carbamate insecticides ranges from slightly toxic products to products that are highly toxic. The more toxic products are generally restricted use pesticides, which require applicators to be certified by their state regulatory agency to purchase and apply products. Synthetic pyrethroid insecticide use has been increasing. These synthesized insecticides are based on naturally occurring pesticides, but have been modified to improve performance and persistence. Synthetic pyrethroids also work by interfering with the central nervous system. Synthetic pyrethroids are low to medium in toxicity to mammals and birds because they can quickly detoxify and excrete them. However, fish and aquatic invertebrates can not quickly detoxify or excrete synthetic pyrethroids, so they are highly susceptible to poisoning by these products. Herbicides and fungicides are generally low to moderately toxic to wildlife. Particular herbicides can have a large impact on the plant life making up the wildlife habitat. Direct Effects Wildlife can be exposed to pesticides directly by eating contaminated food or water, breathing pesticides, or by skin absorption. The type and magnitude of the effect depends on two factors, the pesticide toxicity and pesticide quantity (dose). If exposure causes the animal's death, it is referred to as a lethal effect. Young birds that eat or are fed pesticide treated insects are at great risk of suffering lethal pesticide exposure effects. Sublethal insecticide effects occur when damage to the central nervous system causes an animal to behave in a unusual manner. This behavior may affect the animal's ability to survive or reproduce. Some typical sublethal responses in birds exposed to pesticides include the inability to sing properly, establish a breeding territory, or attract a mate. Adults may be unable to care for themselves or their young properly, resulting in death to the nestlings or increased chance of predation. The lethal and sublethal effects of pesticides on wildlife and fish may occur from one exposure over a short time period (acute) or they may result from exposures to small amounts over a longer time period (chronic). Pesticides commonly used today do not persist as long in the environment as pesticides used years ago. The tradeoff is that the acute toxicity of some of these modern pesticides is higher than the older, more persistent chemicals. -2- Indirect Effects Wildlife in general, and birds in particular, may also experience lethal or sublethal effects without being directly exposed to a pesticide. This typically occurs when a pesticide application destroys or disrupts food sources such as insects. Insects supply the protein necessary for growing birds. Studies indicate that the growth of young birds can be stunted in areas where insecticides have been used heavily, resulting in insect populations too low to meet young bird protein growth demands. Fish that feed on aquatic insects and animals may also show stunted growth in areas of heavy insecticide use because their primary food sources are killed. Inadequate diets also can affect fish reproduction and survival. Herbicides can reduce the amount of cover and make the habitat less suitable for nesting. Assessing Pesticide Risk to Wildlife To properly assess the need for pesticides and the risk to wildlife, information must be gathered on the condition of the crop, the pest situation, characteristics of candidate pesticides, present and expected weather, and some knowledge about the kinds and behavior of wildlife living in the area. The importance of good judgement, practical experience and common sense cannot be overemphasized. Prior to each and every pesticide application, the overall situation should be evaluated so that the expected benefits of a pesticide application are realized and potential hazards are minimized. Good information is necessary to make good judgements. Monitor Fields Regularly Field scouting must be done. It is important to be aware of the status of the field, the crop stage, general health, and yield potential of the crop, as well as the number and growth stage of the various pests that are present. Careful scouting will reveal any wildlife that may also be present. Most pests and most wildlife do not occur uniformly throughout a field. Drawing a map of the field showing the locations of pest populations and wildlife along with recognizable landmarks can aid you in developing a pest control plan that avoids possible effects on wildlife. Identify Wildlife Signs, Seasons, and Habitats One way to ensure that wildlife will not be impacted by a pesticide is to make the application when wildlife are not present. Most wildlife signs can be easily determined while scouting the field. Virtually all agricultural crops will support some type of wildlife. A wide assortment of wildlife will likely be visible during most scouting trips. Areas where wildlife are most likely to be located are field perimeters and other areas where fields may come into contact with windbreaks, wetlands, livestock watering ponds, fence rows, abandoned farmsteads, grasslands or odd areas. Take note of areas where you actually see animals. Other evidence that wildlife are present and using the area includes signs such as tracks, droppings, or foraging evidence. If numerous wildlife signs are present, pesticide applicators can reduce potential impacts to wildlife by marking such areas on a field map or leaving a flag in that area of a field. When spraying around sensitive areas, leave a buffer zone of at least one-half the width of a sprayer boom. Another way to minimize potential impacts to wildlife is to restrict spraying activities in these fields between the hours of 10 a.m. and 4 p.m. During this period, many wildlife will seek the protective cover of cropland, particularly taller row crops, as they wait out the day prior to beginning evening and early morning foraging activities. -3- Critical Reproductive Periods and Habitats Most wildlife reproduction occurs from May 1 to late June and early July. This is perhaps the most critical for many of our resident and migratory wildlife and fish. To complete this reproduction, animals seek out suitable habitats. These habitats can include wetlands, windbreaks and shelterbelts, fencerows, rangelands, and croplands. Wildlife typically nest, birth, feed, and rear their young in areas that provide not only some type of protective cover from the elements and potential predators, but also sources of food. The transition zones between habitat types, where one plant community changes to another, are preferred. These edges usually produce the greatest variety of food plants, insects and seeds. This allows wildlife such as grouse, pheasants, and deer to feed without venturing too far from protective cover. For this reason, most upland gamebird nests can be found in or near such edges. Wetlands are important feeding and brood rearing habitats for waterfowl. Insecticides applied near wetlands by ground sprayers or aircraft can enter the habitat through drift or runoff and contaminate these areas. Depending on the insecticide type, food sources may be destroyed, causing sublethal effects or a direct loss of young wildlife. Similarly, shelterbelts and windbreaks are important habitats for many songbirds. Herbicide drift that results in injury to trees and other vegetation can impair the ability of such habitats to provide safe, secure nesting sites. Insecticide drift can kill nestlings and adult birds, as well as contaminate important insect food sources. Reducing Pesticide Exposure Risk Regular field scouting and a pest control plan should be a part of every producer's operation. Pests are best controlled by manipulating cropping conditions to put pests at a disadvantage to the crop or beneficial organisms. Man and his crops are in competition with pests, and ALL available methods for controlling pests should be considered, not just pesticides. Eliminate Unnecessary Pesticide Applications Through IPM Few applicators knowingly apply unnecessary pesticides because pesticides cost money. Every applicator should ask, will this application pay for itself? Growers should not substitute pesticides for good management. Pesticides are necessary but should only be part of a total pest control program, not the entire program. The best method of reducing risks to wildlife is to use integrated pest management (IPM) practices. IPM incorporates cultural methods such as crop rotation, date of planting, variety choices, and seeding rates with other methods of pest control to maintain pest populations at tolerable levels. Under IPM, pesticides are used only when other methods are not successful and pest damage to crops might otherwise exceed the cost of control. Many pest management practices can help reduce the need for pesticides. Some additional control methods include crop competition, crop rotation, tillage and cultivation, sanitation, planting resistant varieties, planting weed and disease free seed, and using the natural controls present when possible. A good example of non -pesticide control is a competitive crop. An early established, well developed crop can do much to help control weeds. Plants emerging first have a competitive advantage over later emerging plants. Anything done to get quick crop emergence that evenly covers the ground early will have a big impact on weeds. Later emerging weeds are at a tremendous disadvantage and may not cause yield and quality losses. The competitiveness of weeds and crops differs between species. Weeds such as -4- wild oats, wild mustard, and kochia are very competitive, while others, such as redroot pigweed and foxtails are generally less competitive. Some crops ranked in order of decreasing competitiveness are rye, barley, conventional height wheat, semidwarf wheat, and flax. Choose the Pesticide Least Toxic to Non -target Organisms Choose the least toxic pesticide that will control the pest. Often more than one pesticide is registered for control of a particular pest in a particular crop. Take time to compare pesticides and make sure you choose the one BEST suited for the job. Many times the best choice will be the least expensive treatment, but that is not always the case. Sometimes the best choice would be a higher priced pesticide with fewer risks for nontarget plants and animals. Pesticide Toxicity to Wildlife Pesticide applicators can plan a pesticide application that is less toxic to wildlife by examining pesticide toxicity and potential for environmental injury to wildlife and wildlife habitats. This information can be found in tables presented in the back of this publication. When an applicator has identified the specific crop pest situation and checked local crop production guides, a pesticide can be selected that minimizes risk to nontarget plants and animals and still achieves the desired level of control. If the selected pesticide still poses a high threat to wildlife, the applicator would at least be aware of the risk and can take the steps to minimize any potential threats by following recommendations in this publication. Read the Pesticide Label Certain pesticides pose a risk to wildlife or the environment. Some products are classified as RESTRICTED USE PESTICIDES because of environmental hazards. Restricted use pesticides should only be applied by a certified applicator who has been properly trained. • Pesticides that pose environmental risks are labeled to warn the applicator what the risks could be and what steps should be taken to protect people, animals and the environment. These warnings can be found in the "Precautionary Statements" section of the label. The precautionary section is divided into subsections dealing with "Hazards to Humans or Domestic Animals," Environmental Hazard" and "Physical or Chemical Hazard." The risks to wildlife and the environment may be found in the "Environmental Hazard" section. It is a violation of federal law to apply pesticides in any way that is not consistent with label instructions. Hazards to Wildlife If a particular pesticide is especially hazardous to wildlife, it will be stated on the label. For example: • This product is highly toxic to bees. • This product is toxic to fish. • This product is toxic to birds and other wildlife. The label may indicate that the product causes undesirable effects in the environment. In this case, the precautionary statement may tell what to avoid doing. Labeling may indicate limitations imposed to protect wildlife, including endangered species. These limitations may include reduced rates, restrictions on types of application, or a ban on the pesticide's use within the species range. The label also may indicate additional sources of information on proper application methods to reduce hazards. -5- These statements explain special hazards that the pesticides may pose. They should help when choosing the safest product for a particular job and serve as a reminder to take extra precautions. General Environmental Statements General environmental statements appear on nearly every pesticide label as reminders of common sense actions needed to avoid contaminating the environment. The absence of any or all of these statements DOES NOT change the requirement to take adequate precautions. Sometimes the statements will follow a "specific toxicity statement" and provide practical steps to avoid harm to wildlife. Examples of general environmental statements include: • Do not apply when runoff is likely to occur. • Do not apply when weather conditions favor drift from treated areas. • Do not contaminate water when cleaning equipment or disposing of wastes. • Keep out of any body of water. • Do not allow drift on desirable plants or trees. • Do not apply when bees are likely to be in the area. • Do not apply where the water table is close to the surface. Note: It is the responsibility of every pesticide applicator to read and follow the label directions. Use the Lowest Effective Rate Many times the label will allow a range of rates to control a particular pest. Differences in pest size or stage, pest populations and environmental conditions can affect the amount of pesticide needed. Often pesticide rates at the lower end of the rate range can be used when pests are in sensitive growth stages, at lower populations and the weather and growing conditions are favorable. Use Buffer Zones An area between the area sprayed and a sensitive area is called a buffer zone. This area can be a grass strip or may even be part of the crop that is not treated. This buffer area will help trap pesticides and prevent them from entering sensitive areas by spray drift or by runoff. Spot Spraying Many times a pest is located only in a portion of the field. Spraying only the area where the pest is found, leaving the rest of the field untreated, reduces potential risks and saves time and money. Begin Spraying In the Middle of the Field - Most wildlife will be present near the edges of a field. Spraying the field by starting in the middle of the field will allow wildlife time to escape or move out of the field area. Trap Areas Some farmers are experimenting with the use of trap areas. Farmers will seed these areas with an early maturing crop variety ahead of normal planting dates. These areas may attract pests and if pest populations develop in the trap area, a pesticide application can be made. Controlling pests in this manner can reduce chances that pesticides will be required on the rest of the field. -6- Check Weather Conditions A good applicator always checks the weather conditions before spraying. Weather conditions can greatly affect the pesticide exposure through spray drift or runoff. Don't apply pesticides just before rains because pesticides could run off the treated field with excess rainwater and potentially contaminate sensitive areas. Avoid spraying when weather conditions could cause spray drift into sensitive areas. Avoid Spray Drift Spray drift can cause damage to wildlife or wildlife habitat. The following measures are available to greatly reduce drift. Avoid spraying on windy days Check the wind speed and direction. If conditions could cause spray drift into sensitive areas, don't spray. If an application must be made you must take every precaution you can to prevent drift from entering sensitive areas. Another weather condition to avoid is a temperature inversion. Temperature inversions occur when cooler air is near the ground and is beneath warmer air. Very small spray droplets will remain suspended in the air and can move some distance. Use a nonvolatile formulation Some pesticides are volatile and can form vapors, usually on warmer (greater than 70 F) days, which can drift into susceptible areas. If there is an alternative pesticide or formulation that is not volatile and will control the pest, it should be used instead. Increase Droplet Size Spray nozzles produce spray droplets of many different sizes. Larger droplets are heavier and drift less. Practices that increase droplet size will reduce drift, such as increasing nozzle size or water volume, reducing spray pressure or using a drift retardant. Use Larger Nozzle Larger nozzles allow you to apply the same volume of spray with less spray pressure. Spray droplets will be larger than those produced by a smaller nozzle with higher pressure. Increase Water Volume Increasing the water volume will decrease drift because water droplets will be larger and will tend to drift less. Use the Lowest Practical Pressure Lower spray pressure will result in larger spray droplets that drift less than smaller droplets. If spray pressure is reduced too much the spray pattern that results will not be uniform. Newer nozzles such as the "LP" or "XR" type are designed to produce uniform spray patterns with pressures of 15 to 20 pounds per square inch. Use a Drift Retardant A drift retardant will help reduce spray drift by increasing the size of spray droplets. Larger droplets tend to drift less than small droplets. -7- Reduce Spray Boom Height Set spray booms at the lowest height that will give uniform coverage. The closer the boom is to the spray target the less chance there is for drift. Use a Shielded Sprayer Using a shielded sprayer will help reduce spray drift by protecting the spray from wind. Shielded sprayers allow a wider selection of spraying times during the day and more total spraying time per day. These time savers can be used to more precisely target crop areas and avoid sensitive areas. More information on spray drift can be found at your state's Cooperative Extension Service county office. Summary The responsibility to prevent or minimize the effects of pesticide applications on nontarget organisms rests with every pesticide applicator. Information concerning the proper use and application of a pesticide can be found on the product label. Reducing the risk of pesticide exposure to nontarget organisms requires applicators to incorporate crop scouting and IPM techniques with a knowledge of wildlife life cycles and habitats in developing a farm pesticide application plan. Development of such a plan will insure not only the most cost effective means for controlling crop pest situations, but also result in the greatest reduction of risk of pesticide exposure to wildlife. Resource Material Apply Pesticides Correctly: A Guide for Commercial Applicators, U.S. Department of Agriculture and U.S. Environmental Protection Agency. Commercial and Private Applicator Core Manual: Initial Certification, September 1989, Cooperative Extension Service, Michigan State University. Dexter, A. Herbicide Spray Drift. 1986. NDSU Extension Service. A-657 revised. Extoxnet Cooperative Extension Offices, Cornell, U of Calif., Michigan State, Oregon State Univ. Facemire, F. Charles, 1991. Impact of agricultural chemicals on wetland habitats and associated biota with special reference to migratory birds. B.780, SDSU, Brookings, SD. 65 pp. Herbicide Handbook of the Weed Science Society of America. Sixth Ed., 1989, Weed Science Society of America, Champagne, Illinois, 61820. McBride, D.K., D.E. Peterson, H.A. Lamey, 1988, Persistence and Mobility of Pesticides in Soil and Water, NDSU Extension Service. E-49, NDSU Fargo, ND 58105 Pesticide Applicator Training Manual: Core Manual, 2nd Ed., Chemicals -Pesticides Program, Cornell University, 1990. D. Rutz, Director, R. Gardner, W. Smith. -8- Wildlife and Pesticides: A practical guide to reducing the risk (continued) Toxicity Tables These tables provide toxicity comparisons for commonly used pesticides. These comparisons are intended to give applicators the information needed to reduce the risk of an application to wildlife. INSECTICIDES Pesticide (Trade name) Family acephate Organo- (Orthene) phosphate Aldicarb (Temik) Carbamate azinphos methyl Organo- (Guthion) phosphate Bacillus Microbial Thuringiensis (various) carbaryl (Sevin) Carbamate carbofuran Carbamate (Furdan) Toxicity class I11 -(Birds and mammals) I- (Fish/aquatic insects) I -Birds, fish, mammals and aquatic insects) Documented effects on wildlife Moderate to slight acute oral toxicity to birds and mammals Reduction in ChE activity. Bird and mammal mortality reported after ingestion of exposed granules. One of the most toxic carbamate pesticides. Extremely toxicto aquatic organisms. I -(Mammals) 1I -IV (Birds) I1 - Extremely toxic to mammals in (Fish/aqurtic insects) formulations containing a high percentage of active ingredient. Highly toxic to fish and aquatic insects. Best measures to reduce the risk of exposure Increase water volumes to reduce drift. Avoid use areas of high bird numbers. Use lowest recommended effective rates. Avoid contaminating wetlands, ponds, streams and rivers. Proper incorporation of granules. Consider weather and terrain to avoid runoff potentials into water areas. Scout fields to determine the presence of wildlife. Avoid or delay direct application when wildlife is present. Exercise caution to reduce the risk of direct, drift, or runoff applications to water or wetland areas. Avoid contaminating ponds,lakes, and streams. V -(Birds and mammals) No documented effects on wildlife. Apply according to label directions. III -IV -(Birds 111 -(Mammals) I- Moderate acute/chronic toxicity to (Aquatic insects) birds, fish, and mammals. Low persistence. Toxic to aquatic insects. 1 -(All) Highly toxic to all forms of wildlife even when applied at lowest recommended effective rate. -9- Avoid direct applications to wetlands and other waters. Reduce potentials for drift and runoff by using buffer zones. Avoid applying this chemical when wildlife is present. Use buffer zones when applying near wetlands, other waters, and wooded areas. Use an alternate pestiicide. (Granular carbofuran has been voluntarily cancelled and will be phased out by 1994. Flowable is still registered.) chlorpyrifos (Lorsban) Organo- phosphate diazinon (various) Organo- dimethoate (Cygon) I -II -(Birds) 11-III-(Mammis) I- Highly toxic to mammals and birds (Fish and aquatic insects) through oral Extremely toxic to fish and aquatic insects. III -(Mammals) I -(Birds, fish phosphate and aquatic insects) Organo- phosphate disulfoton (Di- Organo- Syston) phosphate endosulfan (Thiodan) • I -(Birds, fish, and aquatic insects) III -(Mammals) I -(All) Avoid contaminating wetlands, lakes, ponds, and streams. Do not apply when wildlife are present. Extremely toxic to birds and Applications should be made only after a careful evaluation. moderately toxic to mammals. Toxic Avoid contaminating wetlands, ponds, lakes, and streams. to bees, fish, and other aquatic organisms. Moderate acute oral toxicity to mammals. Extremely toxic to birds, fish, and other aquatic organisms. Pheasants are particularly sensitive to this pesticide. Extremely toxic to birds, mammals, fish, bee and aquatic organisms. Secondary poisoning in birds eating treated insects has been reported. Chlorinated I -(Fish and aquatic insects) 11- Fish kills associated with Hydrocarbon IV (Birds) I -II (Mammals) contaminated agricultural runoff. Concentrates of <1.3 ppm were sufficient to cause mortality. Highly toxic to aquatic organisms/insects. esfenvalerate Pyrethroid I (Fish) IV -(Bird and (Asana) mammals) parathion (methy Organo- ethyl) (Penncap- phosphate M various) fenvalerate (Pydrin) 1 -(All) Pyrethroid I -(Fish) IV-V(Bird and mammals) Highly toxic to fish, aquatic insects. No reported toxicity in birds/mammals. Ethyl and methyl parathion are extremely toxic to birds, mammals through both acute oral and dermal exposure at recommended application rates. These chemicals are highly toxic to bees fish and other aquatic organisms. See Esfenvalerate -10- Avoid application (direct, drift or runoff) on water areas/wetlands. Use buffer zones near water and shelterbelts. Proper field scouting to include a careful evaluation of potential wildlife exposure will reduce the risk. Do not apply when wildlife is present. Caution should be taken to avoid risks associated with agricultural runoff. The use of buffer zone will reduce risk associated with use of this pesticide. Measures to reduce the risks to wildlife. Avoid applications (direct, drift, runoff in water bodies/ wetlands. Use lowest recommended effective rates and buffer zones near water. Prior to applying parathion a thorough scouting of the field should be conducted. Field applications of parathion should be made prior to 10 a.m. or after 4 p.m. to minimize drift and leave buffer zone near critical wildlife habitats such as windbreaks and wetlands. Do not apply when wildlife are present. See esfenvalerate. fonofos (Dyfonate) malathion (Cythion) Organo- phosphate Organo- phosphate methidathion Organo- (Supracide OP) phosphate phorate (Thimet) Organo- phosphate terbufos (Counter) Organo- phosphate permethin Synthetic (Ambush Pounce) pyrethroid I(AII) III -(Birds and mammals) I - (Fish and aquatic insects) II(All) 1(Al1) Highly toxic to fish, mammals and birds due to chemical action, high field use and relatively long persistence. Used as a granular treatment. Complete incorporation of the product into the soil will minimize wildlife exposure risks. Consider weather and terrain to avoid runoff contamination. No documented effects on wildlife Avoid application (direct, drift or runoff) on water areas/wetlands. (birds/ mammals) when used at Use near buffer zones near water. recommended application rates. Toxic to bees, fish and other aquatic organism. High acute oral toxicity to birds/mammals, bees and fish. Extremely high oral and dermal toxicity has been documented in birds and mammals after exposure to pesticide. Wildlife deaths reported are related to ingestion of improperly incorporated granules, in areas subject to flooding and run off. Uptake of chemical in plants may also cause wildlife exposure. I(A11) Extremely toxic to lab mammals. Potential for greatest impact due to ingestion of granules. I -(Fish and aquatic insects) V- Extremely toxic to aquatic (Birds and mammals) organisms. No documented field effects on birds or mammals. Careful scouting of field to identify the presence of wildlife and the subsequent avoidance of such area and critical wildlife habitats during application will minimize wildlife exposure risks. In areas subject to flooding and runoff and where wildlife are present in large concentrations (migrations) the use of this pesticide should be carefully evaluated. The pesticide must be properly incorporated. Spillage, failure to cover granules, heavy rains or high winds could expose granules increasing the risk. If such conditions exist do not apply if wildlife is present. In areas subject to flooding and runoff and where wildlife are present in large concentrations (migrations) the use of this pesticide should be carefully evaluated. The pesticide must be properly incorporated. Risk can be reduced if applied as an in -furrow or modified in -furrow application. Prevent direct, applications or drift and runoff into wetlands and other water. Use a buffer zone if applied near water areas. -11- HERBICIDES Pesticide (Trade name) 2,4-D Family Phenoxy 2,4-D Amine 2,4-D Ester (see 2,4,-D) acifluorfen Biphenol ether (Blazer) alachlor Acetanilide (various) atrazine Triazine (various) bentazon Benzothia- (various) diazoles bromoxynil Benzonitrile (Buctril) clopyralid Pyridine (Stinger) Toxicity class III -IV -(Birds and mammals) II -(Fish and other aquatic organisms) III -V -(Birds) IV - (Mammals) I-II(Fish and aquatic insects) IV -V -(Birds and mammals) I -(Fish and aquatic insects) IV -V -(Birds and mammals) IV -(Fish) Documented effects on wildlife Moderately toxic to birds and mammals. Highly toxic to insects, fish. A reduction of birds broad- leaved plants from applications can result in a reduction in the nest numbers of waterfowl and other upland nesting birds. Use of a non toxic oil vehicle during application increases toxicity of the chemical to egg embryos. Spray drift can harm wooded areas. No documented impacts on birds or mammals. Toxic to aquatic organisms. May damage susceptible foliage (cover). No documented impacts on birds and mammals. Highly toxic to aquatic insects and fish. Slightly toxic to birds at high concentrations. Indirect effects on aquatic fauna may result as the chemical impacts aquatic plant species. Toxic to fish and aquatic invertebrates at high concentrations. III -IV -(Birds, mammals No documented impacts on birds and mammals. and fish) Moderately toxic to Rainbow trout. I -(Fish and aquatic insects) II -IV - (Mammals and birds) IV -V -(Birds and mammals) 1I -(Fish) Extremely toxic to aquatic invertebrates No documented impacts on birds and mammals. No documented impacts on wildlife. -12- Best measures to reduce the risk of exposure In areas where waterfowl and other upland nest apply with a water based spray mixture. Spot spray where possible to reduce impacts on potential nest cover. Avoid spray drift. Apply amine formulation where drift is a concern. Use a buffer zone when applied in wooded areas, or near water. Avoid spray drift. Use buffer zones near surface water. Avoid contaminating ponds, lakes, wetlands, and streams. Avoid spray drift and runoff contamination of wetlands and other water areas by using buffer zones. Avoid contaminating ponds, lakes, wetlands, and streams. To minimize the impacts of agricultural runoff carrying this chemical into wetlands and other waters employ buffer zones. Use at lowest effective rate.Use with caution in areas where groundwater contamination is likely. Avoid contaminating ponds, lakes, wetlands, and streams. Use buffer zones to reduce potential impacts to aquatic habitats. Do not apply when conditions favor drift. Avoid contaminating ponds, lakes, wetlands, and streams. Avoid spray drift. Avoid contaminating ponds, lakes, wetlands, and streams. Use buffer zones if applying near water areas. Avoid contaminating ponds, lakes, wetlands, and streams. cyanazine Triazine (Bladex) III -IV -(Birds and mammals) cycloate (Ro- Thio- carbamate V -(Birds) IV- Neet) (Mammals) I -(Fish and aquatic organisms) desmedopham Carbamate (Betanex) dicamba (Banvel) diclofop (Hoelon) Benzoic Acid Aryloxy- phenoxy- propionic Acid difenzoquat Bipyridilium (Avenge) EPTC (Eptam) ' IV -(Birds and mammals) I -(Fish and aquatic insects). IV -(Birds mammals, fish, and aquatic insects) V -(Birds) IV - (Mammals) I -(Fish, and aquatic insects) IV -V -(Birds) IV - (Mammals) II -(Fish) I - (Aquatic insects) Thio- carbamate IV -V (Birds and mammals) I -(Fish and aquatic insects) ethalfluralin Dinitro- aniline (Sonalan) fenoxaprop Aryloxy- (Whip) phenoxy- (Option) propionic Acid fluazifop Aryloxy- (Fusilade) phenoxy- propionic Acid IV -V (Birds and mammals) I -(Fish) IV -V (Birds and mammals) I -(Fish and aquatic insects) IV -V (Birds and mammals) I -(Fish and aquatic insects) Slightly toxic to aquatic invertebrates. No documented impacts in birds or mammals. No documented field effects in wildlife. Low acute oral and dermal toxicity in laboratory mammals. Toxic to fish. No documented field effects in wildlife. Low toxicity to laboratory animals. Toxic to fish. Use buffer zones if applying near wetland or other waters. Use caution in areas where groundwater contamination is likely. Apply according to label instructions. Avoid contaminating wetlands, ponds, lakes, and streams. Apply according to label instructions. Avoid contaminating wetlands, ponds, lakes, and streams. No documented field effects on wildlife. Slightly Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, toxic to aquatic invertebrates. and streams. No documented field effects on wildlife. No documented field effects on wildlife. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. -13- Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. glyphosate Amino Acid (Roundup) (Rodeo) imaza- methabenz (Assert) Amino Acid Imidazoline MCPA-amine Phenoxy- MCPA-ester carboxylic Acid metsulfuron (Ally) Sulfonyl Urea Nicosulfuron Sulfonyl- paraquat Bipyridilium (Cyclone) (Gramoxone- Extra) IV -V (Birds and mammals) I -(Fish and aquatic insects) III -IV Fish and aquatic insects. IV -V (Birds and mammals) II -(Fish and aquatic insects) III -IV (Birds and mammals) 1-III(Fish and aquatic insects) IV -V (Birds and mammals) 11-I1I (Fish and aquatic insects) IV -V -(Birds and mammals) IV -(Fish and aquatic invertabrates) I -(Fish and aquatic organisms) 1I -I11 - (waterfowl embroyos, mammals/bird) pendimethalin Dinitro- anilien IV -(Birds and (Prowl) mammals) I -(Fish and aquatic insects) picloram (Tordon) Pyridine "IV -V (Birds and mammals) I -(Fish) primisulfuron Sulfonyl- urea (Beacon) No documented field effects on wildlife. Low Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Apply according to label instructions. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. toxicity in lab birds and mammals. Rodeo is slightly toxic to aquatic organisms unlike its counterpart Round -up. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Toxic to fish and other aquatic organisms, duck egg embryos. slightly toxic to mammals and birds. No documented field effects on wildlife. No documented field effects on wildlife. Low toxicity in lab birds and mammals.Toxic to early life stage of fish. IV -V -(Birds, mammals, No documented field effects on wildlife. fish and aquatic insects) Avoid contaminating wetlands, ponds, lakes, and streams. Use drift precautions. Apply the amine formulation in areas where drift is a concern. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Apply according to label directions. Avoid spray drift. Use a buffer zone when applying near wetlands or other water areas. Avoid direct applications to wildlife and nests. Avoid contaminating wetlands, lakes, ponds and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Use buffer zones when applying near water areas. Should not be used where groundwater contamination is likely. Apply according to label directions. Avoid spray drift. -14- quizalofop (Assure) Aryloxy- phenoxy- propionic Acid sethoxydim Cyclohex- (Poast) . anedione thifensulfuron Sulfonyl- urea (Pinnacle) trial l ate (Fargo) tribenuron (Express) trifluralin (various) Thiocarb- amate Sulfonyl- urea Dinitro- aniline FUNGICIDES Pesticide (Trade name) benomyl (Benlate) IV -V (Birds and mammals) 1 -(Fish) No documented field effects on wildlife. Low Avoid contaminating wetlands, ponds, lakes, and streams. toxicity in lab birds and mammals. IV -V (Birds and No documented field effects on wildlife. Low mammals) IV -(Fish and toxicity in lab birds and mammals. aquatic insects) IV -V -(Birds mammals and aquatic insects) II - (Fish) IV -V -(Birds and mammals) I -II -(Fish and aquatic insects) IV -V (Birds, mammals and fish) III (Aquatic invertebrates) IV -(Birds and mammals) I -(Fish and aquatic insects) Family Benzimida- zole chlorothalonil Aromatic (Bravo) iprodione (Rovral) mancozeb No documented field effects on wildlife. Slightly toxic to aquatic invertebrates. Very low acute and subacute toxicity to birds and mammals. Highly toxic to fish and aquatic insects. No documented field effect on wildlife. High toxicity to aquatic invertebrate and fish. Toxicity class V -(Birds and mammals) I - (Fish) V -(Birds and mammals) I -(Fish and aquatic insects) Documented effects on wildlife Toxic to fish and aquatic insects. No documented field effects on wildlife. Dicarboximide V -(Birds and mammals) I -(Fish No documented field effects on and aquatic insects) wildlife Ethylenebis dithio- V -(Birds and mammals) I -(Fish No documented field effects on -15- Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift and contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Best measures to reduce the risk of exposure Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating (Dithane, Manzate, Penncozeb) propiconazole (Tilt) thiabendazole (Mertect) triadimefon (Bayleton) thiophanate methyl (Topsin- M) carbamate Triazole Benzimidazole Triazole Benzimidazole Toxicity class data is based on acute Class I - Extremely toxic II - Highly toxic Ill - Moderately toxic IV - Slightly toxic V - Relatively toxic and aquatic insects) IV -V -(Birds and mammals) I - (Fish and aquatic insects) V -(Birds and mammals) 1 -(Fish and aquatic insects) V -(Birds and mammals) I -(Fish and aquatic insects) IV -V -(Birds and mamals) I - (Fish and aquatic insects) wildlife. wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. No documented field effects on wildlife No documented field effects on wildlife No documented field effects on wildlife No documented field effects on wildlife Apply according to label instruction. wetlands, lakes, ponds, and streams. applying near water. Apply according to label instruction. wetlands, lakes, ponds, and streams. applying near water. Apply according to label instruction. wetlands, lakes, ponds, and streams. applying near water. Apply according to label instruction. wetlands, lakes, ponds, and streams. applying near water. Avoid contaminating Use a buffer zone when Avoid contaminating Use a buffer zone when Avoid contaminating Use a buffer zone when Avoid contaminating Use a buffer zone when oral rate median lethal dose (LDSO) values for acute toxicity comparisons among chemical. The five toxicity classes used are: LDSO < 40 mg/kg LDSO 41-200 mg/kg LDSO 201-1,000 mg/kg LDSO 1001-5,000 mg/kg LDSO > 5,000 mg/kg -16- Subj: Wildlife and sticides Source Date: Tuesday, August 21, 2001 6:50:19 AM. From: swshultz@shultzsteel.com To: cityofrh@aol.com NDSU Extension Service, North Dakota State University of Agriculture and Applied Science, and U.S. Department of Agriculture cooperating ------------------ Headers --------------------- Return-Path: <swshultz@shultzsteel.com> Received: from rly-yd04.mx.aol.com (rly-yd04.mail.aol.com [172.18.150.4]) by air-yd01.mail.aol.com (v80.17) with ESMTP id MAILINYD19-0821095019; Tue, 21 Aug 2001 09:50:19 -0400 Received: from koufax.shultzsteel.com (koufax.shultzsteel.com [209.101.171.114]) by rly- yd04.mx.aol.com (v80.17) with ESMTP id MAILRELAYINYD410-0821094956; Tue, 21 Aug 2001 09:49:56 -0400 Received: by koufax with Internet Mail Service (5.5.2650.21) id <PJO6FG74>; Tue, 21 Aug 2001 06:54:54 -0700 Message-ID:<50C1B9D7DED2D41192EA0001026CO2190173B7@koufax> From: Steve Shultz <swshultz@shultzsteel.com> To: "Craig Nealis (E-mail)" <cityofrh@aol.com> Subject: Wildlife and Pesticides Source . Date: Tue, 21 Aug 2001 06:54:54 -0700 MIME -Version: 1.0 X -Mailer: Internet Mail Service (5.5.2650.21) Content -Type: text/plain 8/21/.01 America Online : Cityofrh Page 1 City tRotr.�nS.��� INCORPORATED JANUARY 24, 1957 NO. 2 PORTUGUESE BEND ROAD ROLLING HILLS, CALIF. 90274 (310) 377-1521 FAX: (310) 377-7288 E-mail: cityofrh@aol.com Agenda Item No.: 5.1 Mtg. Date: 07/16/01 TO: HONORABLE CHAIR AND MEMBERS OF THE WILDLIFE PRESERVATION COMMITTEE FROM: CRAIG NEALIS, CITY MANAGER SUBJECT: CONSIDERATION OF INFORMATION RELATIVE TO WILDLIFE AND PESTICIDES DATE: JULY 16, 2001 Councilmember Godfrey Pernell has suggested that information be made available at City Hall relating to wildlife and pesticides. Attached to this staff report is information that was gathered by Wildlife Preservation Committee Member Steve Shultz. RECOMMENDATION It is recommended that members of the Wildlife Preservation consider directing staff to make this information available at City Hall. CRN:mlk 07/16/01 wpcpesticide.s to Do IA - Printed on Recycled Paper. Wildlife and Pesticides: A practical guide to reducing the risk • Introduction • Potential Hazards to Wildlife • Effects of Pesticides on Wildlife • Assessing Pesticide Risk to Wildlife • Reducing Pesticide Exposure Risk • Pesticide Toxicity to Wildlife • Summary • Toxicity Tables Pesticides are widely used in agriculture today. Producers use pesticides because they are effective and generally reasonably priced. The benefits include reduced yield losses and timesavings to the producer, and lower food and fiber costs for consumer. There are some downside risks to pesticide use. Pesticide poisonings of people, livestock, and wildlife have occurred when proper care was not exercised. Pesticide applicators must be very careful to avoid these risks. Pesticides, when used with good judgement and care in accordance with label instructions, benefit both agriculture and the environment. Proper use ensures that food and wildlife production objectives can both be realized. Every pesticide applicator must accept responsibility to prevent or minimize the effects of pesticide applications on nontarget organisms. There are several things you as an applicator can do to reduce the risk of pesticide exposure to nontarget plants, animals and habitats. Potential Hazards to Wildlife In order to better protect wildlife from the risks of pesticide exposure it is necessary to understand what effects pesticides may have on wildlife. Several hundred different pesticides are used in agriculture today. Each one of these products has different characteristics that can affect the risk posed to different types of wildlife. While a particular pesticide may pose no harm to mammals, it may cause severe harm to aquatic or bird life. Knowing these differences will greatly assist you in making the proper pesticide use decision. There is much documentation showing that wildlife can be harmed by particular pesticides. The documentation includes laboratory toxicity studies on various types of wildlife, field trials that must be performed in order to register the pesticide, and reports of incidents of wildlife poisoning. In Oregon in the 1970s, aldrin and mercury treated seed grain killed thousands of wild geese and other wildlife. Thirty-six Canada geese were killed in 1988 as a result of an application of carbofuran (Furadan) and disulfoton (Di-Syston) in Idaho. Phorate (Thimet) was involved in the deaths of hundreds of waterfowl and several bald and golden eagles in South Dakota in 1989. Many of the incidents involving wildlife kills result from misuse or illegal applications. One such incident occurred in 1990 when an applicator in North Dakota illegally applied carbofuran (Furadan) to carcasses for predator control. He was found guilty of killing several forms of wildlife, possibly including a bald eagle. Effects of Pesticides on Wildlife Pesticides' effects on wildlife may be lethal, sublethal, acute, chronic, habitat related, or there may be no effect. In general the risk a pesticide poses to wildlife is related to the pesticide type, its toxicity, the proximity of the application to wildlife habitat, the dose, application rate, number of applications, the persistence of the pesticide in the environment, and its ability to concentrate in the wildlife food chain. These factors interact with food habits and behavior of individual wildlife species to produce a response. Pesticide Type In general, insecticides are more toxic to fish and wildlife than herbicides or fungicides. Some herbicides may harm wildlife by damaging the wildlife habitat. Many of the insecticides currently used are either the organophosphate or carbamate type. These insecticides work by interfering with the central nervous system of insects. The central nervous system of fish or wildlife may be affected the same way. The toxicity of the various organophosphate and carbamate insecticides ranges from slightly toxic products to products that are highly toxic. The more toxic products are generally restricted use pesticides, which require applicators to be certified by their state regulatory agency to purchase and apply products. Synthetic pyrethroid insecticide use has been increasing. These synthesized insecticides are based on naturally occurring pesticides, but have been modified to improve performance and persistence. Synthetic pyrethroids also work by interfering with the central nervous system. Synthetic pyrethroids are low to medium in toxicity to mammals and birds because they can quickly detoxify and excrete them. However, fish and aquatic invertebrates can not quickly detoxify or excrete synthetic pyrethroids, so they are highly susceptible to poisoning by these products. Herbicides and fungicides are generally low to moderately toxic to wildlife. Particular herbicides can have a large impact on the plant life making up the wildlife habitat. Direct Effects Wildlife can be exposed to pesticides directly by eating contaminated food or water, breathing pesticides, or by skin absorption. The type and magnitude of the effect depends on two factors, the,pesticide toxicity and pesticide quantity (dose). If exposure causes the animal's death, it is referred to as a lethal effect. Young birds that eat or are fed pesticide treated insects are at great risk of suffering lethal pesticide exposure effects. Sublethal insecticide effects occur when damage to the central nervous system causes an animal to behave in a unusual manner. This behavior may affect the animal's ability to survive or reproduce. Some typical sublethal responses in birds exposed to pesticides include the inability to sing properly, establish a breeding territory, or attract a mate. Adults may be unable to care for themselves or their young properly, resulting in death to the nestlings or increased chance of predation. The lethal and sublethal effects of pesticides on wildlife and fish may occur from one exposure over a short time period (acute) or they may result from exposures to small amounts over a longer time period (chronic). Pesticides commonly used today do not persist as long in the environment as pesticides used years ago. The tradeoff is that the acute toxicity of some of these modern pesticides is higher than the older, more persistent chemicals. Indirect Effects Wildlife in general, and birds in particular, may also experience lethal or sublethal effects without being directly exposed to a pesticide. This typically occurs when a pesticide application destroys or disrupts food sources such as insects. Insects supply the protein necessary for growing birds. Studies indicate that the growth of young birds can be stunted in areas where insecticides have been used heavily, resulting in insect populations too low to meet young bird protein growth demands. Fish that feed on aquatic insects and animals may also show stunted growth in areas of heavy insecticide use because their primary food sources are killed. Inadequate diets also can affect fish reproduction and survival. Herbicides can reduce the amount of cover and make the habitat less suitable for nesting. Assessing Pesticide Risk to Wildlife To properly assess the need for pesticides and the risk to wildlife, information must be gathered on the condition of the crop, the pest situation, characteristics of candidate pesticides, present and expected weather, and some knowledge about the kinds and behavior of wildlife living in the area. The importance of good judgement, practical experience and common sense cannot be overemphasized. Prior to each and every pesticide application, the overall situation should be evaluated so that the expected benefits of a pesticide application are realized and potential hazards are minimized. Good information is necessary to make good judgements. Monitor Fields Regularly Field scouting must be done. It is important to be aware of the status of the field, the crop stage, general health, and yield potential of the crop, as well as the number and growth stage of the various pests that are present. Careful scouting will reveal any wildlife that may also be present. Most pests and most wildlife do not occur uniformly throughout a field. Drawing a map of the field showing the locations of pest populations and wildlife along with recognizable landmarks can aid you in developing a pest control plan that avoids possible effects on wildlife. Identify Wildlife Signs, Seasons, and Habitats One way to ensure that wildlife will not be impacted by a pesticide is to make the application when wildlife are not present. Most wildlife signs can be easily determined while scouting the field. Virtually all agricultural crops will support some type of wildlife. A wide assortment of wildlife will likely be visible during most scouting trips. Areas where wildlife are most likely to be located are field perimeters and other areas where fields may come into contact with windbreaks, wetlands, livestock watering ponds, fence rows, abandoned farmsteads, grasslands or odd areas. Take note of areas where you actually see animals. Other evidence that wildlife are present and using the area includes signs such as tracks, droppings, or foraging evidence. If numerous wildlife signs are present, pesticide applicators can reduce potential impacts to wildlife by marking such areas on a field map or leaving a flag in that area of a field. When spraying around sensitive areas, leave a buffer zone of at least one-half the width of a sprayer boom. Another way to minimize potential impacts to wildlife is to restrict spraying activities in these fields between the hours of 10 a.m. and 4 p.m. During this period, many wildlife will seek the protective cover of cropland, particularly taller row crops, as they wait out the day prior to beginning evening and early morning foraging activities. Critical Reproductive Periods and Habitats Most wildlife reproduction occurs from May 1 to late June and early July. This is perhaps the most critical for many of our resident and migratory wildlife and fish. To complete this reproduction, animals seek out suitable habitats. These habitats can include wetlands, windbreaks and shelterbelts, fencerows, rangelands, and croplands. Wildlife typically nest, birth, feed, and rear their young in areas that provide not only some type of protective cover from the elements and potential predators, but also sources of food. The transition zones between habitat types, where one plant community changes to another, are preferred. These edges usually produce the greatest variety of food plants, insects and seeds. This allows wildlife such as grouse, pheasants, and deer to feed without venturing too far from protective cover. For this reason, most upland gamebird nests can be found in or near such edges. Wetlands are important feeding and brood rearing habitats for waterfowl. Insecticides applied near wetlands by ground sprayers or aircraft can enter the habitat through drift or runoff and contaminate these areas. Depending on the insecticide type, food sources may be destroyed, causing sublethal effects or a direct loss of young wildlife. Similarly, shelterbelts and windbreaks are important habitats for many songbirds. Herbicide drift that results in injury to trees and other vegetation can impair the ability of such habitats to provide safe, secure nesting sites. Insecticide drift can kill nestlings and adult birds, as well as contaminate important insect food sources. Reducing Pesticide Exposure Risk Regular field scouting and a pest control plan should be a part of every producer's operation. Pests are best controlled by manipulating cropping conditions to put pests at a disadvantage to the crop or beneficial organisms. Man and his crops are in competition with pests, and ALL available methods for controlling pests should be considered, not just pesticides. Eliminate Unnecessary Pesticide Applications Through IPM Few applicators knowingly apply unnecessary pesticides because pesticides cost money. Every applicator should ask, will this application pay for itself? Growers should not substitute pesticides for good management. Pesticides are necessary but should only be part of a total pest control program, not the entire program. The best method of reducing risks to wildlife is to use integrated pest management (IPM) practices. IPM incorporates cultural methods such as crop rotation, date of planting, variety choices, and seeding rates with other methods of pest control to maintain pest populations at tolerable levels. Under IPM, pesticides are used only when other methods are not successful and pest damage to crops might otherwise exceed the cost of control. Many pest management practices can help reduce the need for pesticides. Some additional control methods include crop competition, crop rotation, tillage and cultivation, sanitation, planting resistant varieties, planting weed and disease free seed, and using the natural controls present when possible. A good example of non -pesticide control is a competitive crop. An early established, well developed crop can do much to help control weeds. Plants emerging first have a competitive advantage over later emerging plants. Anything done to get quick crop emergence that evenly covers the ground early will have a big impact on weeds. Later emerging weeds are at a tremendous disadvantage and may not cause yield and quality losses. The competitiveness of weeds and crops differs between species. Weeds such as wild oats, wild mustard, and kochia are very competitive, while others, such as redroot pigweed and foxtails are generally less competitive. Some crops ranked in order of decreasing competitiveness are rye, barley, conventional height wheat, semidwarf wheat, and flax. Choose the Pesticide Least Toxic to Non -target Organisms Choose the least toxic pesticide that will control the pest. Often more than one pesticide is registered for control of a particular pest in a particular crop. Take time to compare pesticides and make sure you choose the one BEST suited for the job. Many times the best choice will be the least expensive treatment, but that is not always the case. Sometimes the best choice would be a higher priced pesticide with fewer risks for nontarget plants and animals. Pesticide Toxicity to Wildlife Pesticide applicators can plan a pesticide application that is less toxic to wildlife by examining pesticide toxicity and potential for environmental injury to wildlife and wildlife habitats. This information can be found in tables presented in the back of this publication. When an applicator has identified the specific crop pest situation and checked local crop production guides, a pesticide can be selected that minimizes risk to nontarget plants and animals and still achieves the desired level of control. If the selected pesticide still poses a high threat to wildlife, the applicator would at least be aware of the risk and can take the steps to minimize any potential threats by following recommendations in this publication. Read the Pesticide Label Certain pesticides pose a risk to wildlife or the environment. Some products are classified as RESTRICTED USE PESTICIDES because of environmental hazards. Restricted use pesticides should only be applied by a certified applicator who has been properly trained. Pesticides that pose environmental risks are labeled to warn the applicator what the risks could be and what steps should be taken to protect people, animals and the environment. These wamings can be found in the "Precautionary Statements" section of the label. The precautionary section is divided into subsections dealing with "Hazards to Humans or Domestic Animals," Environmental Hazard" and "Physical or Chemical Hazard." The risks to wildlife and the environment may be found in the "Environmental Hazard" section. It is a violation of federal law to apply pesticides in any way that is not consistent with label instructions. Hazards to Wildlife If a particular pesticide is especially hazardous to wildlife, it will be stated on the label. For example: • This product is highly toxic to bees. • This product is toxic to fish. • This product is toxic to birds and other wildlife. The label may indicate that the product causes undesirable effects in the environment. In this case, the precautionary statement may tell what to avoid doing. Labeling mayindicate limitations imposed to protect wildlife, including endangered species. These limitations may include reduced rates, restrictions on types of application, or a ban on the pesticide's use within the species range. The label also may indicate additional sources of information on proper application methods to reduce hazards. These statements explain special hazards that the pesticides may pose. They should help when choosing the safest product for a particular job and serve as a reminder to take extra precautions. General Environmental Statements General environmental statements appear on nearly every pesticide label as reminders of common sense actions needed to avoid contaminating the environment. The absence of any or all of these statements DOES NOT change the requirement to take adequate precautions. Sometimes the statements will follow a "specific toxicity statement" and provide practical steps to avoid harm to wildlife. Examples of general environmental statements include: • Do not apply when runoff is likely to occur. • Do not apply when weather conditions favor drift from treated areas. • Do not contaminate water when cleaning equipment or disposing of wastes. • Keep out of any body of water. • Do not allow drift on desirable plants or trees. • Do not apply when bees are likely to be in the area. • Do not apply where the water table is close to the surface. Note: It is the responsibility of every pesticide applicator to read and follow the label directions. Use the Lowest Effective Rate Many times the label will allow a range of rates to control a particular pest. Differences in pest size or stage, pest populations and environmental conditions can affect the amount of pesticide needed. Often pesticide rates at the lower end of the rate range can be used when pests are in sensitive growth stages, at lower populations and the weather and growing conditions are favorable. Use Buffer Zones An area between the area sprayed and a sensitive area is called a buffer zone. This area can be.a grass strip or may even be part of the crop that is not treated. This buffer area will help trap pesticides and prevent them from entering sensitive areas by spray drift or by runoff. Spot Spraying Many times a pest is located only in a portion of the field. Spraying only the area where the pest is found, leaving the rest of the field untreated, reduces potential risks and saves time and money. Begin Spraying In the Middle of the Field Most wildlife will be present near the edges of a field. Spraying the field by starting in the middle of the field will allow wildlife time to escape or move out of the field area. Trap Areas Some farmers are experimenting with the use of trap areas. Farmers will seed these areas with an early maturing crop variety ahead of normal planting dates. These areas may attract pests and if pest populations develop in the trap area, a pesticide application can be made. Controlling pests in this manner can reduce chances that pesticides will be required on the rest of the field. Check Weather Conditions A good applicator always checks the weather conditions before spraying. Weather conditions can greatly affect the pesticide exposure through spray drift or runoff. Don't apply pesticides just before rains because pesticides could run off the treated field with excess rainwater and potentially contaminate sensitive areas. Avoid spraying when weather conditions could cause spray drift into sensitive areas. Avoid Spray Drift Spray drift can cause damage to wildlife or wildlife habitat. The following measures are available to greatly reduce drift. Avoid spraying on windy days Check the wind speed and direction. If conditions could cause spray drift into sensitive areas, don't spray. If an application must be made you must take every precaution you can to prevent drift from entering sensitive areas. Another weather condition to avoid is a temperature inversion. Temperature inversions occur when cooler air is near the ground and is beneath warmer air. Very small spray droplets will remain suspended in the air and can move some distance. Use a nonvolatile formulation Some pesticides are volatile and can form vapors, usually on warmer (greater than 70 F) days, which can drift into susceptible areas. If there is an alternative pesticide or formulation that is not volatile and will control the pest, it should be used instead. Increase Droplet Size Spray nozzles produce spray droplets of many different sizes. Larger droplets are heavier and drift less. Practices that increase droplet size will reduce drift, such as increasing nozzle size or water volume, reducing spray pressure or using a drift retardant. Use Larger Nozzle Larger nozzles allow you to apply the same volume of spray with less spray pressure. Spray droplets will be larger than those produced by a smaller nozzle with higher pressure. Increase Water Volume Increasing the water volume will decrease drift because water droplets will be larger and will tend to drift less. Use the Lowest Practical Pressure Lower spray pressure will result in larger spray droplets that drift less than smaller droplets. If spray pressure is reduced too much the spray pattern that results will not be uniform. Newer nozzles such as the "LP" or "XR" type are designed to produce uniform spray patterns with pressures of 15 to 20 pounds per square inch. Use a Drift Retardant A drift retardant will help reduce spray drift by increasing the size of spray droplets. Larger droplets tend to drift less than small droplets. Reduce Spray Boom Height Set spray booms at the lowest height that will give uniform coverage. The closer the boom is to the spray target the less chance there is for drift. Use a Shielded Sprayer Using a shielded sprayer will help reduce spray drift by protecting the spray from wind. Shielded sprayers allow a wider selection of spraying times during the day and more total spraying time per day. These time savers can be used to more precisely target crop areas and avoid sensitive areas. More information on spray drift can be found at your state's Cooperative Extension Service county office. Summary The responsibility to prevent or minimize the effects of pesticide applications on nontarget organisms rests with every pesticide applicator. Information concerning the proper use and application of a pesticide can be found on the product label. Reducing the risk of pesticide exposure to nontarget organisms requires applicators to incorporate crop scouting and IPM techniques with a knowledge of wildlife life cycles and habitats in developing a farm pesticide application plan. Development. of such a plan will insure not only the most cost effective means for controlling crop pest situations, but also result in the greatest reduction of risk of pesticide exposure to wildlife. Resource Material Apply Pesticides Correctly: A Guide for Commercial Applicators, U.S. Department of Agriculture and U.S. Environmental Protection Agency. Commercial and Private Applicator Core Manual: Initial Certification, September 1989, Cooperative Extension Service, Michigan State University. Dexter, A. Herbicide Spray Drift. 1986. NDSU Extension Service. A-657 revised. Extoxnet Cooperative Extension Offices, Cornell, U of Calif., Michigan State, Oregon State Univ. Facemire, F. Charles, 1991. Impact of agricultural chemicals on wetland habitats and associated biota with special reference to migratory birds. B 780, SDSU, Brookings, SD. 65 pp. Herbicide Handbook of the Weed Science Society of America. Sixth Ed., 1989, Weed Science Society of America, Champagne, Illinois, 61820. • McBride, D.K., D.E. Peterson, H.A. Lamey, 1988, Persistence and Mobility of Pesticides in Soil and Water, NDSU Extension Service. E-49, NDSU Fargo, ND 58105 Pesticide Applicator Training Manual: Core Manual, 2nd Ed., Chemicals -Pesticides Program, Cornell University, 1990. D. Rutz, Director, R. Gardner, W. Smith. Wildlife and Pesticides: A practical guide to reducing the risk (continued) Toxicity Tables These tables provide toxicity comparisons for commonly used pesticides. These comparisons are intended to give applicators the information needed to reduce the risk of an application to wildlife. INSECTICIDES Pesticide (Trade name) Family acephate Organo- (Orthene) phosphate Aldicarb Carbamate (Temik) azinphos Organo- methyl phosphate (Guthion) Bacillus Microbial Thuringiensis (various) carbaryl Carbamate (Sevin) carbofuran Carbamate (Furdan) chlorpyrifos (Lorsban) diazinon (various) Organo- phosphate Organo- phosphate dimethoate Organo- (Cygon) phosphate I -H -(Birds) II -III- Highly toxic to mammals (Mammls) I -(Fish and and birds through oral aquatic insects) Extremely toxic to fish and aquatic insects. III -(Mammals) I- Extremely toxic to birds (Birds, fish and aquatic and moderately toxic to insects) mammals. Toxic to bees, fish, and other aquatic organisms. I -(Birds, fish, and Moderate acute oral aquatic insects) III- toxicity to mammals. I -(Mammals) II -IV (Birds) II - (Fish/aqurtic insects) V -(Birds and mammals) Toxicity class III -(Birds and mammals) I- (Fish/aquatic insects) Documented effects on wildlife Moderate to slight acute oral toxicity to birds and mammals Reduction in ChE activity. Best measures to reduce the risk of exposure Increase water volumes to reduce drift. Avoid use areas of high bird numbers. Use lowest recommended effective rates. Avoid contaminating wetlands, ponds, streams and rivers. I -Birds, fish, mammals Bird and mammal mortality Proper incorporation of granules. Consider and aquatic insects) reported after ingestion of weather and terrain to avoid runoff potentials into exposed granules. One of water areas. the most toxic carbamate pesticides. Extremely toxicto aquatic organisms. Extremely toxic to mammals in formulations containing a high percentage of active ingredient. Highly toxic to fish and aquatic insects. No documented effects on wildlife. III -IV -(Birds lII- Moderate acute/chronic Scout fields to determine the presence of wildlife. Avoid or delay direct application when wildlife is present. Exercise caution to reduce the risk of direct, drift, or runoff applications to water or wetland areas. Avoid contaminating ponds,lakes, and streams. Apply according to label directions. Avoid direct applications to wetlands and other (Mammals) I -(Aquatic toxicity to birds, fish, and waters. Reduce potentials for drift and runoff by insects) mammals. Low persistence. using buffer zones. Toxic to aquatic insects. I -(All) Highly toxic to all forms of Avoid applying this chemical when wildlife is wildlife even when applied present. Use buffer zones when applying near at lowest recommended wetlands,other waters, and wooded areas. Use an effective rate. alternate pestiicide. (Granular carbofuran has been voluntarily cancelled and will be phased out by 1994. Flowable is still registered.) Avoid contaminating wetlands, lakes, ponds, and streams. Do not apply when wildlife are present. Applications should be made only after a careful evaluation. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid application (direct, drift or runoff) on water areas/wetlands. Use buffer zones near water and (Mammals) Extremely toxic to birds, fish, and other aquatic organisms. Pheasants are particularly sensitive to this pesticide. Extremely toxic to birds, mammals, fish, bee and aquatic organisms. Secondary poisoning in birds eating treated insects has been reported. endosulfan Chlorinated I -(Fish and aquatic Fish kills associated with (Thiodan) Hydrocarbon insects) II -IV (Birds) I- contaminated agricultural II (Mammals) runoff. Concentrates of <1.3 ppm were sufficient to pesticide. cause mortality. Highly toxic to aquatic organisms/insects. esfenvalerate Pyrethroid I (Fish) IV -(Bird and Highly toxic to fish, Measures to reduce the risks to wildlife. Avoid aquatic insects. No reported applications (direct, drift, runoff in water bodies/ toxicity in birds/mammals. wetlands. Use lowest recommended effective rates and buffer zones near water. Ethyl and methyl parathion Prior to applying parathion a thorough scouting of are extremely toxic to the field should be conducted. Field applications birds, mammals through of parathion should be made prior to 10 a.m. or both acute oral and dermal after 4 p.m. to minimize drift and leave buffer exposure at recommended zone near critical wildlife habitats such as application rates. These windbreaks and wetlands. Do not apply when chemicals are highly toxic wildlife are present. to bees fish and other aquatic organisms. See Esfenvalerate See esfenvalerate. disulfoton Organo- I -(All) (Di-Syston) phosphate shelterbelts. Proper field scouting to include a careful evaluation of potential wildlife exposure will reduce the risk. Do not apply when wildlife is present. Caution should be taken to avoid risks associated with agricultural runoff. The use of buffer zone will reduce risk associated with use of this (Asana) mammals) parathion Organo- I -(All) (methy ethyl) phosphate (Penncap-M various) • fenvalerate Pyrethroid I -(Fish) IV-V(Bird and (Pydrin) mammals) fonofos Organo- I(A11) (Dyfonate) phosphate malathion Organo- (Cythion) phosphate III -(Birds and mammals) I -(Fish and aquatic insects) methidathion Organo- II(AII) (Supracide phosphate OP) phorate Organo- I(All) (Thimet) phosphate Highly toxic to fish, mammals and birds due to chemical action, high field use and relatively long persistence. Used as a granular treatment. No documented effects on wildlife (birds/ mammals) when used at recommended application rates. Toxic to bees, fish and other aquatic organism. High acute oral toxicity to birds/mammals, bees and fish. Extremely high oral and dermal toxicity has been documented in birds and mammals after exposure to pesticide. Wildlife deaths reported are related to ingestion of improperly incorporated granules, in areas subject to flooding and run off. Uptake of chemical in plants may also Complete incorporation of the product into the soil will minimize wildlife exposure risks. Consider weather and terrain to avoid runoff contamination. Avoid application (direct, drift or runoff) on water areas/wetlands. Use near buffer zones near water. Careful scouting of field to identify the presence of wildlife and the subsequent avoidance of such area and critical wildlife habitats during application will minimize wildlife exposure risks. In areas subject to flooding and runoff and where wildlife are present in large concentrations (migrations) the use of this pesticide should be carefully evaluated. The pesticide must be properly incorporated. terbufos Organo- (Counter) phosphate permethin Synthetic (Ambush pyrethroid Pounce) HERBICIDES Pesticide (Trade name) Family 2,4-D Phenoxy 2,4-D Amine 2,4-D Ester (see 2,4,-D) acifluorfen Biphenol (Blazer) ether alachlor Acetanilide (various) atrazine Triazine (various) bentazon Benzothia- (various) diazoles I(All) I -(Fish and aquatic insects) V -(Birds and mammals) Toxicity class III -IV -(Birds and mammals) II - (Fish and other aquatic organisms) III -V -(Birds) IV - (Mammals) I- II(Fish and aquatic insects) IV -V -(Birds and mammals) I -(Fish and aquatic insects) IV -V -(Birds and mammals) IV - (Fish) III -IV -(Birds, mammals and fish) bromoxyni Benzonitrile I -(Fish and 1(Buctril) aquatic insects) 1I -IV -(Mammals and birds) clopyralid Pyridine IV -V -(Birds and (Stinger) mammals) II - cause wildlife exposure. Extremely toxic to lab mammals. Potential for greatest impact due to ingestion of granules. Extremely toxic to aquatic organisms. No documented field effects on birds or mammals. Documented effects on wildlife Moderately toxic to birds and mammals. Highly toxic to insects, fish. A reduction of birds broad- leaved plants from applications can result in a reduction in the nest numbers of waterfowl and other upland nesting birds. Use of a non toxic oil vehicle during application increases toxicity of the chemical to egg embryos. Spray drift can harm wooded areas. No documented impacts on birds or mammals. Toxic to aquatic organisms. May damage susceptible foliage (cover). No documented impacts on birds and mammals. Highly toxic to aquatic insects and fish. Slightly toxic to birds at high concentrations. Indirect effects on • aquatic fauna may result as the chemical impacts aquatic plant species. Toxic to fish and aquatic invertebrates at high concentrations. No documented impacts on birds and mammals. Moderately toxic to Rainbow trout. Extremely toxic to aquatic invertebrates No documented impacts on birds and mammals. No documented impacts on wildlife. Spillage, failure to cover granules, heavy rains or high winds could expose granules increasing the risk. If such conditions exist do not apply if wildlife is present. In areas subject to flooding and runoff and where wildlife are present in large concentrations (migrations) the use of this pesticide should be carefully evaluated. The pesticide must be properly incorporated. Risk can be reduced if applied as an in -furrow or modified in -furrow application. Prevent direct, applications or drift and runoff into wetlands and other water. Use a buffer zone if applied near water areas. Best measures to reduce the risk of exposure In areas where waterfowl and other upland nest apply with a water based spray mixture. Spot spray where possible to reduce impacts on potential nest cover. Avoid spray drift. Apply amine formulation where drift is a concern. Use a buffer zone when applied in wooded areas, or near water. Avoid spray drift. Use buffer zones near surface water. Avoid contaminating ponds, lakes, wetlands, and streams. Avoid spray drift and runoff contamination of wetlands and other water areas by using buffer zones. Avoid contaminating ponds, lakes, wetlands, and streams. To minimize the impacts of agricultural runoff carrying this chemical into wetlands and other waters employ buffer zones. Use at lowest effective rate.Use with caution in areas where groundwater contamination is likely. Avoid contaminating ponds, lakes, wetlands, and streams. Use buffer zones to reduce potential impacts to aquatic habitats. Do not apply when conditions favor drift. Avoid contaminating ponds, lakes, wetlands, and streams. Avoid spray drift. Avoid contaminating ponds, lakes, wetlands, and streams. Use buffer zones if applying near water areas. Avoid contaminating ponds, lakes, wetlands, and cyanazine Triazine (Bladex) cycloate (Ro-Neet) Thio- carbamate desmedop Carbamate ham (Betanex) dicamba Benzoic (Banvel) Acid diclofop (Hoelon) difenzoqu at (Avenge) Aryloxy- phenoxy- propionic Acid Bipyridilium EPTC Thio- (Eptam) carbamate ethalflurali Dinitro- aniline (Sonalan) fenoxapro p (Whip) (Option) fluazifop (Fusilade) (Fish) III -IV -(Birds and mammals) V -(Birds) IV - (Mammals) I - (Fish and aquatic organisms) IV -(Birds and mammals) I-(Fis and aquatic insects). IV -(Birds mammals, fish, and aquatic insects) V -(Birds) IV - (Mammals) I- wildlife. (Fish, and aquatic insects) IV -V -(Birds) IV - (Mammals) II - (Fish) I -(Aquatic insects) IV -V (Birds and mammals) I -(Fish and aquatic insects) IV -V (Birds and mammals) I - (Fish) Aryloxy- IV -V (Birds and phenoxy- mammals) I -(Fish propionic and aquatic Acid insects) Aryloxy- IV -V (Birds and phenoxy- mammals) I -(Fish propionic and aquatic Acid insects) glyphosate Amino Acid IV -V (Birds and (Roundup) mammals) I -(Fish and aquatic insects) (Rodeo) Amino Acid III -IV Fish and aquatic insects. imaza- methabenz (Assert) MCPA- Phenoxy- amine carboxylic MCPA- Acid ester metsulfuro Sulfonyl n (Ally) Urea, Nicosulfur Sulfonyl- on Imidazoline a I ( I m IV -V (Birds and mammals) II - Fish and aquatic nsects) II -IV (Birds and mammals) I- II(Fish and quatic insects) V -V (Birds and mammals) II -III Fish and aquatic nsects) V -V -(Birds and ammals) IV - Slightly toxic to aquatic invertebrates. No documented impacts in birds or mammals. No documented field effects in wildlife. Low acute oral and dermal toxicity in laboratory mammals. Toxic to fish. No documented field effects in h wildlife. Low toxicity to laboratory animals. Toxic to fish. No documented field effects on wildlife. Slightly toxic to aquatic invertebrates. No documented field effects on No documented field effects on wildlife. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. Rodeo is slightly toxic to aquatic organisms unlike its counterpart Round -up. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. streams. Use buffer zones if applying near wetland or other waters. Use caution in areas where groundwater contamination is likely. Apply according to label instructions. Avoid contaminating. wetlands, ponds, lakes, and streams. Apply according to label instructions. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Apply according to label instructions. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Use drift precautions. Apply the amine formulation in areas where drift is a concern. Avoidcontaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Apply according to label directions. Avoid spray drift. paraquat Bipyridilium (Cyclone) (Granioxo ne- Extra) pendimeth Dinitro- alin anilien (Prowl) picloram Pyridine (Tordon) primisulfu Sulfonyl- ron urea (Beacon) quizalofop Aryloxy- (Assure) phenoxy- • propionic Acid sethoxydi Cyclohex- m (Poast) anedione thifensulfu Sulfonyl- ron urea (Pinnacle) triallate Thiocarb- (Fargo) amate tribenuron Sulfonyl- (Express) urea trifluralin Dinitro- (various) aniline (Fish and aquatic invertabrates) I -(Fish and aquatic organisms) (waterfowl embroyos, embroyos, mammals/bird) IV -(Birds and No documented field effects on Avoid contaminating wetlands, lakes, ponds and mammals) I -(Fish wildlife. streams. and aquatic insects) IV -V (Birds and No documented field effects on Avoid contaminating wetlands, ponds, lakes, and mammals) I- wildlife. Low toxicity in lab birds and streams. Avoid spray drift. Use buffer zones (Fish) mammals.Toxic to early life stage of when applying near water areas. Should not be . fish. Toxic to fish and other aquatic Use a buffer zone when applying near wetlands organisms, duck egg embryos. slightly or other water areas. Avoid direct applications to toxic to mammals and birds. wildlife and nests. IV -V -(Birds, mammals, fish and aquatic insects) IV -V (Birds and mammals) I - (Fish) IV -V (Birds and mammals) IV - (Fish and aquatic insects) IV -V -(Birds mammals and aquatic insects) II -(Fish) IV -V -(Birds and mammals) I -II - (Fish and aquatic insects) IV -V (Birds, mammals and fish) III (Aquatic invertebrates) IV -(Birds and mammals) I -(Fish and aquatic insects) FUNGICIDES Pesticide (Trade name) Family benomyl Benzimida- (Benlate) zole • chlorothaloni Aromatic 1 (Bravo) iprodione (Rovral) No documented field effects on wildlife. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Slightly toxic to aquatic invertebrates. Very low acute and subacute toxicity to birds and mammals. Highly toxic to fish and aquatic insects. No documented field effect on wildlife. used where groundwater contamination is likely. Apply according to label directions. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift and contaminating wetlands, ponds, lakes, and streams. High toxicity to aquatic invertebrate Avoid contaminating wetlands, ponds, lakes, and and fish. streams. Toxicity class V -(Birds and mammals) I -(Fish) V -(Birds and • mammals) I -(Fish and aquatic insects) Dicarboximide V -(Birds and mammals) I -(Fish and Documented effects on wildlife Toxic•to fish and aquatic insects. No documented field effects on wildlife. No documented field effects on wildlife Best measures to reduce the risk of exposure Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and mancozeb Ethylenebis (Dithane, dithio- Manzate, carbamate Penncozeb) propiconazol Triazole e (Tilt) aquatic insects) V -(Birds and mammals) I -(Fish and aquatic insects) IV -V -(Birds and mammals) 1 -(Fish and aquatic insects) thiabendazol Benzimidazole V -(Birds and e (Mertect) mammals) I -(Fish and aquatic insects) triadimefon Triazole (Bayleton) thiophanate methyl (Topsin-M) V -(Birds and mammals) I -(Fish and aquatic insects) Benzimidazole IV -V -(Birds and mamals) I -(Fish and aquatic insects) chemical. The five toxicity classes used are: Class I - Extremely toxic II - Highly toxic III - Moderately toxic IV - Slightly toxic V - Relatively toxic No documented field effects on wildlife. No documented field effects on wildlife No documented field effects on wildlife No documented field effects on wildlife No documented field effects on wildlife LDSO < 40 mg/kg LDSO 41-200 mg/kg LDSO 201-1,000 mg/kg LDSO 1001-5,000 mg/kg LDSO > 5,000 mg/kg streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. values for acute toxicity comparisons among Wildlife and Pesticides: A practical guide to reducing the risk • Introduction • Potential Hazards to Wildlife • Effects of Pesticides on Wildlife • Assessing Pesticide Risk to Wildlife • Reducing Pesticide Exposure Risk • Pesticide Toxicity to Wildlife • Summary • Toxicity Tables Pesticides are widely used in agriculture today. Producers use pesticides because they are effective and generally reasonably priced. The benefits include reduced yield losses and timesavings to the producer, and lower food and fiber costs for consumer. There are some downside risks to pesticide use. Pesticide poisonings of people, livestock, and wildlife have occurred when proper care was not exercised. Pesticide applicators must be very careful to avoid these risks. Pesticides, when used with good judgement and care in accordance with label instructions, benefit both agriculture and the environment. Proper use ensures that food and wildlife production objectives can both be realized. Every pesticide applicator must accept responsibility to prevent or minimize the effects of pesticide applications on nontarget organisms. There are several things you as an applicator can do to reduce the risk of pesticide exposure to nontarget plants, animals and habitats. Potential Hazards to Wildlife In order to better protect wildlife from the risks of pesticide exposure it is necessary to understand what effects pesticides may have on wildlife. • Several hundred different pesticides are used in agriculture today. Each one of these products has different characteristics that can affect the risk posed to different types of wildlife. While a particular pesticide may pose no harm to mammals, it may cause severe harm to aquatic or bird life. Knowing these differences will greatly assist you in making the proper pesticide use decision. There is much documentation showing that wildlife can be harmed by particular pesticides. The documentation includes laboratory toxicity studies on various types of wildlife, field trials that must be performed in order to register the pesticide, and reports of incidents of wildlife poisoning. In Oregon in the 1970s, aldrin and mercury treated seed grain killed thousands of wild geese and other wildlife. Thirty-six Canada geese were killed in 1988 as a result of an application of carbofuran (Furadan) and disulfoton (Di-Syston) in Idaho. Phorate (Thimet) was involved in the deaths of hundreds of waterfowl and several bald and golden eagles in South Dakota in 1989. Many of the incidents involving wildlife kills result from misuse or illegal applications. One such incident occurred in 1990 when an applicator in North Dakota illegally applied carbofuran (Furadan) to carcasses for predator control. He was found guilty of killing several forms of wildlife, possibly including a bald eagle. Effects of Pesticides on Wildlife Pesticides' effects on wildlife may be lethal, sublethal, acute, chronic, habitat related, or there may be no effect. In general the risk a pesticide poses to wildlife is related to the pesticide type, its toxicity, the proximity of the application to wildlife habitat, the dose, application rate, number of applications, the persistence of the pesticide m the environment, and its ability to concentrate in the wildlife food chain. These factors interact with food habits and behavior of individual wildlife species to produce a response. Pesticide Type In general, insecticides are more toxic to fish and wildlife than herbicides or fungicides. Some herbicides may harm wildlife by damaging the wildlife habitat. Many of the insecticides currently used are either the organophosphate or carbamate type. These insecticides work by interfering with the central nervous system of insects. The central nervous system of fish or wildlife may be affected the same way. The toxicity of the various organophosphate and carbamate insecticides ranges from slightly toxic products to products that are highly toxic. The more toxic products are generally restricted use pesticides, which require applicators to be certified by their state regulatory agency to purchase and apply products. Synthetic pyrethroid insecticide use has been increasing. These synthesized insecticides are based on naturally occurring pesticides, but have been modified to improve performance and persistence. Synthetic pyrethroids also work by interfering with the central nervous system. Synthetic pyrethroids are low to medium in toxicity to mammals and birds because they can quickly detoxify and excrete them. However, fish and aquatic invertebrates can not quickly detoxify or excrete synthetic pyrethroids, so they are highly susceptible to poisoning by these products. Herbicides and fungicides are generally low to moderately toxic to wildlife. Particular herbicides can have a large impact on the plant life making up the wildlife habitat. Direct Effects Wildlife can be exposed to pesticides directly by eating contaminated food or water, breathing pesticides, or by skin absorption. The type and magnitude of the effect depends on two factors, the pesticide toxicity and pesticide quantity (dose). If exposure causes the animal's death, it is referred to as a lethal effect. Young birds that eat or are fed pesticide treated insects are at great risk of suffering lethal pesticide exposure effects. Sublethal insecticide effects occur when damage to the central nervous system causes an animal to behave in a unusual manner. This behavior may affect the animal's ability to survive or reproduce. Some typical sublethal responses in birds exposed to pesticides include the inability to sing properly, establish a breeding territory, or attract a mate. Adults may be unable to care for themselves or their young properly, resulting in death to the nestlings or increased chance of predation. The lethal and sublethal effects of pesticides on wildlife and fish may occur from one exposure over a short time period (acute) or they may result from exposures to small amounts over a longer time period (chronic). Pesticides commonly used today do not persist as long in the environment as pesticides used years ago. The tradeoff is that the acute toxicity of some of these modem pesticides is higher than the older, more persistent chemicals. Indirect Effects Wildlife in general, and birds in particular, may also experience lethal or sublethal effects without being directly exposed to a pesticide. This typically occurs when a pesticide application destroys or disrupts food sources such as insects. Insects supply the protein necessary for growing birds. Studies indicate that the growth of young birds can be stunted in areas where insecticides have been used heavily, resulting in insect populations too low to meet young bird protein growth demands. Fish that feed on aquatic insects and animals may also show stunted growth in areas of heavy insecticide use because their primary food sources are killed. Inadequate diets also can affect fish reproduction and survival. Herbicides can reduce the amount of cover and make the habitat less suitable for nesting. Assessing Pesticide Risk to Wildlife To properly assess the need for pesticides and the risk to wildlife, information must be gathered on the condition of the crop, the pest situation, characteristics of candidate pesticides, present and expected weather, and some knowledge about the kinds and behavior of wildlife living in the area. The importance of good judgement, practical experience and common sense cannot be overemphasized. Prior to each and every pesticide application, the overall situation should be evaluated so that the expected benefits of a pesticide application are realized and potential hazards are minimized. Good information is necessary to make good judgements. Monitor Fields Regularly Field scouting must be done. It is important to be aware of the status of the field, the crop stage, general health, and yield potential of the crop, as well as the number and growth stage of the various pests that are present. Careful scouting will reveal any wildlife that may also be present. Most pests and most wildlife do not occur uniformly throughout a field. Drawing a map of the field showing the locations of pest populations and wildlife along with recognizable landmarks can aid you in developing a pest control plan that avoids possible effects on wildlife. Identify Wildlife Signs, Seasons, and Habitats One way to ensure that wildlife will not be impacted by a pesticide is to make the application when wildlife are not present. Most wildlife signs can be easily determined while scouting the field. Virtually all agricultural crops will support some type of wildlife. A wide assortment of wildlife will likely be visible during most scouting trips. Areas where wildlife are most likely to be located are field perimeters and other areas where fields may come into contact with windbreaks, wetlands, livestock watering ponds, fence rows, abandoned farmsteads, grasslands or odd areas. Take note of areas where you actually see animals. Other evidence that wildlife are present and using the area includes signs such as tracks, droppings, or foraging evidence. If numerous wildlife signs are present, pesticide applicators can reduce potential impacts to wildlife by marking such areas on a field map or leaving a flag in that area of a field. When spraying around sensitive areas, leave a buffer zone of at least one-half the width of a sprayer boom. Another way to minimize potential impacts to wildlife is to restrict spraying activities in these fields between the hours of 10 a.m. and 4 p.m. During this period, many wildlife will seek the protective cover of cropland, particularly taller row crops, as they wait out the day prior to beginning evening and early moming foraging activities. Critical Reproductive Periods and Habitats Most wildlife reproduction occurs from May 1 to late June and early July. This is perhaps the most critical for many of our resident and migratory wildlife and fish. To complete this reproduction, animals seek out suitable habitats. These habitats can include wetlands, windbreaks and shelterbelts, fencerows, rangelands, and croplands. Wildlife typically nest, birth, feed, and rear their young in areas that provide not only some type of protective coyer from the elements and potential predators, but also sources of food. The transition zones between habitat types, where one plant community changes to another, are preferred. These edges usually produce the greatest variety of food plants, insects and seeds. This allows wildlife such as grouse, pheasants, and deer to feed without venturing too far from protective cover. For this reason, most upland gamebird nests can be found in or near such edges. Wetlands are important feeding and brood rearing habitats for waterfowl. Insecticides applied near wetlands by ground sprayers or aircraft can enter the habitat through drift or runoff and contaminate these areas. Depending on the insecticide type, food sources may be destroyed, causing sublethal effects or a direct loss of young wildlife. Similarly, shelterbelts and windbreaks are important habitats for many songbirds. Herbicide drift that results in injury to trees and other vegetation can impair the ability of such habitats to provide safe, secure nesting sites. Insecticide drift can kill nestlings and adult birds, as well as contaminate important insect food sources. Reducing Pesticide Exposure Risk Regular field scouting and a pest control plan should be a part of every producer's operation. Pests are best controlled by manipulating cropping conditions to put pests at a disadvantage to the crop or beneficial organisms. Man and his crops are in competition with pests, and ALL available methods for controlling pests should be considered, not just pesticides. Eliminate Unnecessary Pesticide Applications Through IPM Few applicators knowingly apply unnecessary pesticides because pesticides cost money. Every applicator should ask, will this application pay for itself? Growers should not substitute pesticides for good management. Pesticides are necessary but should only be part of a total pest control program, not the entire program. The best method of reducing risks to wildlife is to use integrated pest management (IPM) practices. IPM incorporates cultural methods such as crop rotation, date of planting, variety choices, and seeding rates with other methods of pest control to maintain pest populations at tolerable levels. Under IPM, pesticides are used only when other methods are not successful and pest damage to crops might otherwise exceed the cost of control. Many pest management practices can help reduce the need for pesticides. Some additional control methods include crop competition, crop rotation, tillage and cultivation, sanitation, planting resistant varieties, planting weed and disease free seed, and using the natural controls present when possible. A good example of non -pesticide control is a competitive crop. An early established, well developed crop can do much to help control weeds. Plants emerging first have a competitive advantage over later emerging plants. Anything done to get quick crop emergence that evenly covers the ground early will have a big impact on weeds. Later emerging weeds are at a tremendous disadvantage and may not cause yield and quality losses. The competitiveness of weeds and crops differs between species. Weeds such as wild oats, wild mustard, and kochia are very competitive, while others, such as redroot pigweed and foxtails are generally less competitive. Some crops ranked in order of decreasing competitiveness are rye, barley, conventional height wheat, semidwarf wheat, and flax. Choose the Pesticide Least Toxic to Non -target Organisms Choose the least toxic pesticide that will control the pest. Often more than one pesticide is registered for control of a particular pest in a particular crop. Take time to compare pesticides and make sure you choose the one BEST suited for the job. Many times the best choice will be the least expensive treatment, but that is not always the case. Sometimes the best choice would be a higher priced pesticide with fewer risks for nontarget plants and animals. Pesticide Toxicity to Wildlife Pesticide applicators can plan a pesticide application that is less toxic to wildlife by examining pesticide toxicity and potential for environmental injury to wildlife and wildlife habitats. This information can be found in tables presented in the back of this publication. When an applicator has identified the specific crop pest situation and checked local crop production guides, a pesticide can be selected that minimizes risk to nontarget plants and animals and still achieves the desired level of control. If the selected pesticide still poses a high threat to wildlife, the applicator would at least be aware of the'risk and can take the steps to minimize any potential threats by following recommendations in this publication. Read the Pesticide Label Certain pesticides pose a risk to wildlife or the environment. Some products are classified as RESTRICTED USE PESTICIDES because of environmental hazards. Restricted use pesticides should only be applied by a certified applicator who has been properly trained. Pesticides that pose environmental risks are labeled to warn the applicator what the risks could be and what steps should be taken to protect people, animals and the environment. These warnings can be found in the "Precautionary Statements" section of the label. The precautionary section is divided into subsections dealing with "Hazards to Humans or Domestic Animals," Environmental Hazard" and "Physical or Chemical Hazard." The risks to wildlife and the environment may be found in the "Environmental Hazard" section. It is a violation of federal law to apply pesticides in any way that is not consistent with label instructions. Hazards to Wildlife If a particular pesticide is especially hazardous to wildlife, it will be stated on the label. For example: • This product is highly toxic to bees. • This product is toxic to fish. • This product is toxic to birds and other wildlife. The label may indicate that the product causes undesirable effects in the environment. In this case, the precautionary statement may tell what to avoid doing. Labeling may indicate limitations imposed to protect wildlife, including endangered species. These limitations may include reduced rates, restrictions on types of application, or a ban on the pesticide's use within the species range. The label also may indicate additional sources of information on proper application methods to reduce hazards. These statements explain special hazards that the pesticides may pose. They should help when choosing the safest product for a particular job and serve as a reminder to take extra precautions. General Environmental Statements General environmental statements appear on nearly every pesticide label as reminders of common sense actions needed to avoid contaminating the environment. The absence of any or all of these statements DOES NOT change the requirement to take adequate precautions. Sometimes the statements will follow a "specific toxicity statement" and provide practical steps to avoid harm to wildlife. Examples of general environmental statements include: • Do not apply when runoff is likely to occur. • Do not apply when weather conditions favor drift from treated areas. • Do not contaminate water when cleaning equipment or disposing of wastes. • Keep out of any body of water. • Do not allow drift on desirable plants or trees. • Do not apply when bees are likely to be in the area. • Do not apply where the water table is close to the surface. Note: It is the responsibility of every pesticide applicator to read and follow the label directions. Use the Lowest Effective Rate Many times the label will allow a range of rates to control a particular pest. Differences in pest size or stage, pest populations and environmental conditions can affect the amount of pesticide needed. Often pesticide rates at the lower end of the rate range can be used when pests are in sensitive growth stages, at lower populations and the weather and growing conditions are favorable. Use Buffer Zones An area between the area sprayed and a sensitive area is called a buffer zone. This area can be a grass strip or may even be part of the crop that is not treated. This buffer area will help trap pesticides and prevent them from entering sensitive areas by spray drift or by runoff. Spot Spraying Many times a pest is located only in a portion of the field. Spraying only the area where the pest is found, leaving the rest of the field untreated, reduces potential risks and saves time and money. Begin Spraying In the Middle of the Field Most wildlife will be present near the edges of a field. Spraying the field by starting in the middle of the field will allow wildlife time to escape or move out of the field area. Trap Areas Some farmers are experimenting with the use of trap areas. Farmers will seed these areas with an early maturing crop variety ahead of normal planting dates. These areas may attract pests and if pest populations develop in the trap area, a pesticide application can be made. Controlling pests in this manner can reduce chances that pesticides will be required on the rest of the field. Check Weather Conditions A good applicator always checks the weather conditions before spraying. Weather conditions can greatly affect the pesticide exposure through spray drift or runoff. Don't apply pesticides just before rains because pesticides could run off the treated field with excess rainwater and potentially contaminate sensitive areas. Avoid spraying when weather conditions could cause spray drift into sensitive areas. Avoid Spray Drift Spray drift can cause damage to wildlife or wildlife habitat. The following measures are available to greatly reduce drift. Avoid spraying on windy days Check the wind speed and direction. If conditions could cause spray drift into sensitive areas, don't spray. If an application must be made you must take every precaution you can to prevent drift from entering sensitive areas. Another weather condition to avoid is a temperature inversion. Temperature inversions occur when cooler air is near the ground and is beneath warmer air. Very small spray droplets will remain suspended in the air and can move some distance. Use a nonvolatile formulation Some pesticides are volatile and can form vapors, usually on warmer (greater than 70 F) days, which can drift into susceptible areas. If there is an alternative pesticide or formulation that is not volatile and will control the pest, it should be used instead. Increase Droplet Size Spray nozzles produce spray droplets of many different sizes. Larger droplets are heavier and drift less. Practices that increase droplet size will reduce drift, such as increasing nozzle size or water volume, reducing spray pressure or using a drift retardant. Use Larger Nozzle Larger nozzles allow you to apply the same volume of spray with less spray pressure. Spray droplets will be larger than those produced by a smaller nozzle with higher pressure. Increase Water Volume Increasing the water volume will decrease drift because water droplets will be larger and will tend to drift less. Use the Lowest Practical Pressure Lower spray pressure will result in larger spray droplets that drift less than smaller droplets. If spray pressure is reduced too much the spray pattern that results will not be uniform. Newer nozzles such as the "LP" or "XR" type are designed to produce uniform spray patterns with pressures of 15 to 20 pounds per square inch. Use a Drift Retardant A drift retardant will help reduce spray drift by increasing the size of spray droplets. Larger droplets tend to drift less than small droplets. Reduce Spray Boom Height Set spray booms at the lowest height that will give uniform coverage. The closer the boom is to the spray target the less chance there is for drift. Use a Shielded Sprayer Using a shieldedsprayer will help reduce spray drift by protecting the spray from wind. Shielded sprayers allow a wider selection of spraying times during the day and more total spraying time per day. These time savers can be used to more precisely target crop areas and avoid sensitive areas. More information on spray drift can be found at your state's Cooperative Extension Service county office. Summary The responsibility to prevent or minimize the effects of pesticide applications on nontarget organisms rests with every pesticide applicator. Information conceming the proper use and application of a pesticide can be found on the product label. Reducing the risk' of pesticide exposure to nontarget organisms requires applicators to incorporate crop scouting and IPM techniques with a knowledge of wildlife life cycles and habitats in developing a farm pesticide application plan. Development. of such a plan will insure not only the most cost effective means for controlling crop pest situations, but also result in the greatest reduction of risk of pesticide exposure to wildlife. Resource Material Apply Pesticides Correctly: A Guide for Commercial Applicators, U.S. Department of Agriculture and U.S. Environmental Protection Agency. Commercial and Private Applicator Core Manual: Initial Certification, September 1989, Cooperative Extension Service, Michigan State University. Dexter, A. Herbicide Spray Drift. 1986. NDSU Extension Service. A-657 revised. Extoxnet Cooperative Extension Offices, Comell, U of Calif., Michigan State, Oregon State Univ. Facemire, F. Charles, 1991. Impact of agricultural chemicals on wetland habitats and associated biota with special reference to migratory birds. B 780, SDSU, Brookings, SD. 65 pp. Herbicide Handbook of the Weed Science Society of America. Sixth Ed., 1989, Weed Science Society of America, Champagne, Illinois, 61820. McBride,.D.K., D.E. Peterson, H.A. Lamey, 1988, Persistence and Mobility of Pesticides in Soil and Water, NDSU Extension Service. E-49, NDSU Fargo, ND 58105 Pesticide Applicator Training Manual: Core Manual, 2nd Ed., Chemicals -Pesticides Program, Comell University, 1990. D. Rutz, Director, R. Gardner, W. Smith. Wildlife and Pesticides: A practical guide to reducing the risk (continued) Toxicity Tables These tables provide toxicity comparisons for commonly used pesticides. These comparisons are intended to give applicators the information needed to reduce the risk of an application to wildlife. INSECTICIDES Pesticide (Trade name) Family acephate Organo- (Orthene) phosphate Aldicarb Carbamate (Temik) azinphos Organo- methyl phosphate (Guthion) Bacillus Microbial Thuringiensis (various) carbaryl Carbamate (Sevin) carbofuran Carbamate (Furdan) chlorpyrifos (Lorsban) diazinon (various) Organo- phosphate Organo- phosphate dimethoate Organo- (Cygon) phosphate Toxicity class III -(Birds and mammals) I- (Fish/aquatic insects) I -Birds, fish, mammals and aquatic insects) I -(Mammals) II -IV (Birds) II - (Fish/aqurtic insects) V -(Birds and mammals) Documented effects on wildlife Moderate to slight acute oral toxicity to birds and mammals Reduction in ChE activity. Bird and mammal mortality reported after ingestion of exposed granules. One of the most toxic carbamate pesticides. Extremely toxicto aquatic organisms. Extremely toxic to mammals in formulations containing a high percentage of active ingredient. Highly toxic to fish and aquatic insects. No documented effects on wildlife. Best measures to reduce the risk of exposure Increase water volumes to reduce drift. Avoid use areas of high bird numbers. Use lowest recommended effective rates. Avoid contaminating wetlands, ponds, streams and rivers. Proper incorporation of granules. Consider weather and terrain to avoid runoff potentials into water areas. Scout fields to determine the presence of wildlife. Avoid or delay direct application when wildlife is present. Exercise caution to reduce the risk of direct, drift, or runoff applications to water or wetland areas. Avoid contaminating ponds,lakes, and streams. Apply according to label directions. III -IV -(Birds III- Moderate acute/chronic Avoid direct applications to wetlands and other (Mammals) I -(Aquatic toxicity to birds, fish, and waters. Reduce potentials for drift and runoff by insects) mammals. Low persistence. using buffer zones. Toxic to aquatic insects. 1-(A11) I -II -(Birds) II-III- (Mammis) I -(Fish and aquatic insects) III -(Mammals) I - (Birds, fish and aquatic insects) I -(Birds, fish, and aquatic insects) 111 - Highly toxic to all forms of wildlife even when applied at lowest recommended effective rate. Highly toxic to mammals and birds through oral Extremely toxic to fish and aquatic insects. Extremely toxic to birds and moderately toxic to mammals. Toxic to bees, fish, and other aquatic organisms. Moderate acute oral toxicity to mammals. Avoid applying this chemical when wildlife is present. Use buffer zones when applying near wetlands, other waters, and wooded areas. Use an alternate pestiicide. (Granular carbofuran has been voluntarily cancelled and will be phased out by 1994. Flowable is still registered.) Avoid contaminating wetlands, lakes, ponds, and streams. Do not apply when wildlife are present. Applications should be made only after a careful evaluation. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid application (direct, drift or runoff) on water areas/wetlands. Use buffer zones near water and (Mammals) Extremely toxic to birds, fish, and other aquatic organisms. Pheasants are particularly sensitive to this pesticide. disulfoton Organo- I -(All) Extremely toxic to birds, (Di-Syston) phosphate mammals, fish, bee and aquatic organisms. Secondary poisoning in birds eating treated insects has been reported. endosulfan I -(Fish and aquatic Fish kills associated with (Thiodan) insects) II -IV (Birds) I- contaminated agricultural II (Mammals) • runoff. Concentrates of <1.3 ppm were sufficient to cause mortality. Highly toxic to aquatic organisms/insects. esfenvalerate Pyrethroid I (Fish) IV -(Bird and Highly toxic to fish, (Asana) mammals) aquatic insects. No reported Chlorinated Hydrocarbon parathion Organo- I -(A11) (methy ethyl) phosphate (Penncap-M various) fenvalerate Pyrethroid (Pydrin) fonofos Organo- (Dyfonate) phosphate shelterbelts. Proper field scouting to include a careful evaluation of potential wildlife exposure will reduce the risk. Do not apply when wildlife is present. Caution should be taken to avoid risks associated with agricultural runoff. The use of buffer zone will reduce risk associated with use of this pesticide. Measures to reduce the risks to wildlife. Avoid applications (direct, drift, runoff in water bodies/ toxicity in birds/mammals. wetlands. Use lowest recommended effective rates and buffer zones near water. Ethyl and methyl parathion Prior to applying parathion a thorough scouting of are extremely toxic to birds, mammals through both acute oral and dermal exposure at recommended application rates. These chemicals are highly toxic to bees fish and other aquatic organisms. I -(Fish) IV-V(Bird and See Esfenvalerate mammals) I(A11) Highly toxic to fish, mammals and birds due to chemical action, high field use and relatively long persistence. Used as a granular treatment. malathion Organo- III -(Birds and No documented effects on (Cythion) phosphate mammals) I -(Fish and wildlife (birds/ mammals) aquatic insects) methidathion Organo- II(All) (Supracide phosphate OP) phorate (Thimet) Organo- I(AII) phosphate the field should be conducted. Field applications of parathion should be made prior to 10 a.m. or after 4 p.m. to minimize drift and leave buffer zone near critical wildlife habitats such as windbreaks and wetlands. Do not apply when wildlife are present. See esfenvalerate. Complete incorporation of the product into the soil will minimize wildlife exposure risks. Consider weather and terrain to avoid runoff contamination. Avoid application (direct, drift or runoff) on water areas/wetlands. Use near buffer zones near water. when used at recommended application rates. Toxic to bees, fish and other aquatic organism. High acute oral toxicity to birds/mammals, bees and fish. Extremely high oral and dermal toxicity has been documented in birds and mammals after exposure to pesticide. Wildlife deaths • reported are related to ingestion of improperly incorporated granules, in areas subject to flooding and run off. Uptake of chemical in plants may also Careful scouting of field to identify the presence of wildlife and the subsequent avoidance of such area and critical wildlife habitats during application will minimize wildlife exposure risks. In areas subject to flooding and runoff and where wildlife are present in large concentrations (migrations) the use of this pesticide should be carefully evaluated. The pesticide must be properly incorporated. terbufos Organo- (Counter) phosphate permethin Synthetic (Ambush pyrethroid Pounce) HERBICIDES Pesticide (Trade name) Family 2,4-D Phenoxy 2,4-D Amine 2,4-D Ester (see 2,4,-D) acifluorfen Biphenol (Blazer) ether alachlor Acetanilide (various) atrazine Triazine (various) bentazon Benzothia- (various) diazoles I(AI l) I -(Fish and aquatic insects) V -(Birds and mammals) Toxicity class III -IV -(Birds and mammals) II - (Fish and other aquatic organisms) III -V -(Birds) IV - (Mammals) I- II(Fish and aquatic insects) IV -V -(Birds and mammals) I -(Fish and aquatic insects) IV -V -(Birds and mammals) IV - (Fish) III -IV -(Birds, mammals and fish) bromoxyni Benzonitrile I -(Fish and 1 (Buctril) aquatic insects) II -IV -(Mammals and birds) clopyralid Pyridine IV -V -(Birds and (Stinger) mammals) II - cause wildlife exposure. Extremely toxic to lab mammals. Potential for greatest impact due to ingestion of granules. Extremely toxic to aquatic organisms. No documented field effects on birds or mammals. Documented effects on wildlife Moderately toxic to birds and mammals. Highly toxic to insects, fish. A reduction of birds broad- leaved plants from applications can result in a reduction in the nest numbers of waterfowl and other upland nesting birds. Use of a non toxic oil vehicle during application increases toxicity of the chemical to egg embryos. Spray drift can harm wooded areas. No documented impacts on birds or mammals. Toxic to aquatic organisms. May damage susceptible foliage (cover). No documented impacts on birds and mammals. Highly toxic to aquatic insects and fish. Slightly toxic to birds at high concentrations. Indirect effects on aquatic fauna may result as the chemical impacts aquatic plant species. Toxic to fish and aquatic invertebrates at high concentrations. No documented impacts on birds and mammals. Moderately toxic to Rainbow trout. Extremely toxic to aquatic. invertebrates No documented impacts on birds and mammals. No documented impacts on wildlife. Spillage, failure to cover granules, heavy rains or high winds could expose granules increasing the risk. If such conditions exist do not apply if wildlife is present. In areas subject to flooding and runoff and where wildlife are present in large concentrations (migrations) the use of this pesticide should be carefully evaluated. The pesticide must be properly incorporated. Risk can be reduced if applied as an in -furrow or modified in -furrow application. Prevent direct, applications or drift and runoff into wetlands and other water. Use a buffer zone if applied near water areas. Best measures to reduce the risk of exposure In areas where waterfowl and other upland nest apply with a water based spray mixture. Spot spray where possible to reduce impacts on potential nest cover. Avoid spray drift. Apply amine formulation where drift is a concern. Use a buffer zone when applied in wooded areas, or near watei. Avoid spray drift. Use buffer zones near surface water. Avoid contaminating ponds, lakes, wetlands, and streams. Avoid spray drift and runoff contamination of wetlands and other water areas by using buffer zones. Avoid contaminating ponds, lakes, wetlands, and streams. To minimize the impacts of agricultural runoff carrying this chemical into wetlands and other waters employ buffer zones. Use at lowest effective rate.Use with caution in areas where groundwater contamination is likely. Avoid contaminating ponds, lakes, wetlands, and streams. Use buffer zones to reduce potential impacts to aquatic habitats. Do not apply when conditions favor drift. Avoid contaminating ponds, lakes, wetlands, and streams. Avoid spray drift. Avoid contaminating ponds, lakes, wetlands, and streams. Use buffer zones if applying near water areas. Avoid contaminating ponds, lakes, wetlands, and cyanazine (Bladex) cycloate (Ro-Neet) desmedop ham (Betanex) Triazine Thio- carbamate Carbamate dicamba Benzoic (Banvel) Acid diclofop (Hoelon) difenzoqu at (Avenge) Aryloxy- phenoxy- propionic Acid (Fish) III -IV -(Birds and mammals) V -(Birds) IV - (Mammals) I - Slightly toxic to aquatic invertebrates. No documented impacts in birds or mammals. No documented field effects in wildlife. Low acute oral and dermal streams. Use buffer zones if applying near wetland or other waters. Use caution in areas where groundwater contamination is likely. Apply according to label instructions. Avoid contaminating wetlands, ponds, lakes, and (Fish and aquatic toxicity in laboratory mammals. Toxic streams. organisms) , to fish. IV -(Birds and No documented field effects in Apply according to label instructions. Avoid mammals) I -(Fish wildlife. Low toxicity to laboratory contaminating wetlands, ponds, lakes, and and aquatic animals. Toxic to fish. streams. insects). IV -(Birds mammals, fish, and aquatic insects) V -(Birds) IV - (Mammals) I - (Fish, and aquatic insects) Bipyridilium IV -V -(Birds) IV - (Mammals) II - (Fish) I -(Aquatic insects) EPTC Thio- (Eptam) carbamate ethalflurali Dinitro- n aniline (Sonalan) fenoxapro Aryloxy- p (Whip) phenoxy- (Option) propionic Acid • fluazifop Aryloxy- (Fusilade) phenoxy- propionic Acid glyphosate Amino Acid (Roundup) (Rodeo) Amino Acid imaza- Imidazoline methabenz (Assert) MCPA- Phenoxy- amine carboxylic MCPA- Acid ester metsulfuro Sulfonyl n (Ally) Urea Nicosulfur Sulfonyl- on No documented field effects on wildlife. Slightly toxic to aquatic invertebrates. No documented field effects on wildlife. No documented field effects on wildlife. IV -V (Birds and No documented field effects on mammals) I -(Fish wildlife. Low toxicity in lab birds and and aquatic mammals. insects) IV -V (Birds and No documented field effects on mammals) I- wildlife. Low toxicity in lab birds and (Fish) mammals. IV -V (Birds and No documented field effects on mammals) I -(Fish wildlife. Low toxicity in lab birds and and aquatic mammals. insects) IV -V (Birds and No documented field effects on mammals) I -(Fish wildlife. Low toxicity in lab birds and and aquatic mammals. insects) IV -V (Birds and No documented field effects on mammals) I -(Fish wildlife. Low toxicity in lab birds and and aquatic insects) III -IV Fish and aquatic insects. IV -V (Birds and mammals) II - (Fish and aquatic insects) III -IV (Birds and mammals) I- III(Fish and aquatic insects) IV -V (Birds and mammals) II -III (Fish and aquatic insects) IV -V -(Birds and mammals) IV - mammals. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Rodeo is slightly toxic to aquatic Apply according to label instructions. Avoid organisms unlike its counterpart spray drift. Round -up. No documented field effects on Avoid contaminating wetlands, ponds, lakes, and wildlife. Low toxicity in lab birds and streams. mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Avoid contaminating wetlands, ponds, lakes, and streams. Use drift precautions. Apply the amine formulation in areas where drift is a concern. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Apply according to label directions. Avoid spray drift. pendimeth Dinitro- alin anilien (Prowl) picloram Pyridine (Tordon) primisulfu Sulfonyl- ron urea - (Beacon) quizalofop Aryloxy- (Assure) phenoxy- propionic Acid sethoxydi Cyclohex- m (Poast) anedione thifensulfu Sulfonyl- ron urea (Pinnacle) triallate Thiocarb- (Fargo) amate tribenuron Sulfonyl- (Express) urea trifluralin Dinitro- (various) aniline (Fish and aquatic invertabrates) paraquat Bipyridilium I -(Fish and (Cyclone) aquatic (Gramoxo organisms) II-III- ne- Extra) (waterfowl embroyos, mammals/bird) IV -(Birds and mammals) I -(Fish and aquatic insects) IV -V (Birds and mammals) I - (Fish) IV -V -(Birds, mammals, fish and aquatic insects) IV -V (Birds and mammals) I - (Fish) IV -V (Birds and mammals) IV - (Fish and aquatic insects) IV -V -(Birds mammals and aquatic insects) II -(Fish) IV -V -(Birds and mammals) I -II - (Fish and aquatic insects) IV -V (Birds, mammals and fish) III (Aquatic invertebrates) IV -(Birds and mammals) I -(Fish and aquatic insects) FUNGICIDES Pesticide (Trade name) Family benomyl Benzimida- (Benlate) zole chlorothaloni Aromatic I (Bravo) iprodione (Rovral) Toxic to fish and other aquatic Use a buffer zone when applying near wetlands organisms, duck egg embryos. slightly or other water areas. Avoid direct applications to toxic to mammals and birds. wildlife and nests. No documented field effects on wildlife. No documented field effects on wildlife. Low toxicity in lab birds and mammals.Toxic to early life stage of fish. No documented field effects on wildlife. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Low toxicity in lab birds and mammals. No documented field effects on wildlife. Slightly toxic to aquatic invertebrates. Very low acute and subacute toxicity Avoid contaminating wetlands, lakes, ponds and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Use buffer zones when applying near water areas. Should not be used where groundwater contamination is likely. Apply according to label directions. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid spray drift. Avoid contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and to birds and mammals. Highly toxic to streams. fish and aquatic insects. No documented field effect on wildlife. High toxicity to aquatic invertebrate and fish. Toxicity class V -(Birds and mammals) I -(Fish) .V -(Birds and mammals) I -(Fish and aquatic insects) Dicarboximide V -(Birds and mammals) I -(Fish and Documented effects on wildlife Toxic to fish and aquatic insects. No documented field effects on wildlife. No documented field effects on wildlife Avoid spray drift and contaminating wetlands, ponds, lakes, and streams. Avoid contaminating wetlands, ponds, lakes, and streams. Best measures to reduce the risk of exposure Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and mancozeb Ethylenebis (Dithane, dithio- Manzate, carbamate Penncozeb) propiconazol Triazole e (Tilt) aquatic insects) V -(Birds and mammals) I -(Fish and aquatic insects) IV -V -(Birds and mammals) I -(Fish and aquatic insects) thiabendazol Benzimidazole V -(Birds and e (Mertect) mammals) I -(Fish and aquatic insects) triadimefon Triazole V -(Birds and (Bayleton) mammals) I -(Fish and aquatic insects) thiophanate Benzimidazole IV -V -(Birds and methyl mamals) I -(Fish and (Topsin-M) aquatic insects). No documented field effects on wildlife. No documented field effects on wildlife No documented field effects on wildlife No documented field effects on wildlife No documented field effects on wildlife Toxicity class data is based on acute oral rate median lethal dose (LDSO) chemical. The five toxicity classes used are: Class I - Extremely toxic LDSO < 40 mg/kg II - Highly toxic LDSO 41-200 mg/kg III - Moderately toxic LDSO 201-1,000 mg/kg IV - Slightly toxic LDSO 1001-5,000 mg/kg V - Relatively toxic LDSO > 5,000 mg/kg streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. Apply according to label instruction. Avoid contaminating wetlands, lakes, ponds, and streams. Use a buffer zone when applying near water. values for acute toxicity comparisons among HERBICIDE USE IN ROLLING HILLS by Flavio Bisignano • CONTENTS I. What is a Weed? II. Methods to Control Weeds III. At Issue: Weed Killers, their Pros and Cons IV. Plant Ecology and the Ecological Role of Weeds V. Expanding the Concept of Ecology VI. Closing Thoughts VII. References Z. What is a Weed? "Any plant growing where it is not wanted", defines a weed. For example, when dandelions are cultivated as fresh greens to be eaten - they are not perceived as weeds. When dandelions invade the lawn, they become a nuisance. The term "weed" is a non -technical word for many herbaceous (non -woody) plants growing wild . These are unwanted, self - propagating plants as opposed to cultivated plants whose seeds are deliberately sown. Why are some plants unwanted? 1. Any plant robbing the soil of nutrients and moisture stunts the growth of cultivated plants. 2. Root stems of some weeds multiply underground, choking out the root systems of wanted plants. 3. The resiliency of some weed seeds allow the seeds to be buried in soil remaining dormant for years and then germinate. 4. Weeds serve as hosts to fungi that spread to cultivated plants. Other weeds serve as a source for viruses. Some insects that directly attack cultivated plants, breed on weeds. 5. Weeds that grow in hayfields are of low food value•. Some weeds eaten by cows leave an unpleasant flavor in milk. Buttercups are weeds that thrive in pastures where cows graze. However, they contain an irritating juice that cattle dislike. 6. Weeds with pointed seed pods may get caught in the coats of animals causing discomfort. Plants, wanted or unwanted, could not exist without soil. Without plants, no food chain could evolve. All green plants absorb mineral nutrients from the soil for metabolic activity. Particular species of plants adapt to particular kinds of soil. For example, the optimal environment for cactus plants is soil with low moisture content. The soil could not form without water and the atmosphere. Plants interact with elements in the soil to provide the nutrients needed for growth. Nitrogen, an essential nutrient cannot be used by the plant directly from the atmosphere. Nitrogen forms 16 percent of all living tissue. Atmospheric nitrogen is made available to plants by the process of nitrification. Geologically, the earth's crust is a shell of solid rock about 20 to 30 miles thick. Soil is the link between the rock shell and vegetation on the earth's surface. Soil is a mix of disintegrated rock and decayed organic matter that is populated with microscopic life. Capillaries throughout the particle mix are pore space occupying air and water. Soil formation is a weathering process. Atmospheric conditions and living organisms are in constant interaction with inorganic rock. Temperature is a powerful agent in fragmenting rock. Rocks are composed of various minerals (naturally occurring chemical elements of inorganic compounds). While all minerals expand in heat some expand more than others. The uneven expansion of diverse minerals crack rocks, causing crevices into which water seeps. In cold weather, the water freezes causing ice in the crevices to exert enough pressure to split rocks. Over the centuries, the cycle of freezing, thawing, and refreezing are the physical processes chemical weathering involves micro-organisms to convert elements from air and water into nutrients that plants can use. The metabolic activity of the soil is upon bacteria, fungi, and algae (algae is the traditional term for unrelated groups of photo synthetic organisms). An example: legumes would starve for lack of nitrogen without soil nitrogen -fixing bacteria to form root nodules on the plants. In the process, atmospheric nitrogen is converted into nitrogenous compounds. In simpler terms, the roots supply carbohydrates for the bacteria. In a complex process, these bacteria combine free nitrogen from the air with oxygen to form nitrates. Eventually, nitrogen as a vital element of living tissue, is present in the form of amino acids that make-up chains of protein (clover and alfalfa'are examples of legumes). II. Methods to Control Weeds Cultivation: The mechanical removal of weeds by a garden tool such as a hoe. Crop Rotation: In farming, weeds can be kept in check by planting a different crop in the same field every few years. For example, weeds invading a cornfield would be of a different plant species than the weeds found in a hayfield. Take over by new weeds attracted to a newly planted crop could starve out most weed seeds remaining in the soil attracted to the previous year's crop. Mowing and Burning: Temporary control of weeds such as burning in open range country, along highways\irrigation ditches, mowing. Plant -eating insects: A biological control. A historic example, at the turn of this century the Klamath weed (goat weed) migrated from its native habitat in Europe. Having no ecology in this country - which means there were no natural predators to stop the goat weed spread to the Klamath river area in California. Not until 1944, after devastating some two and a half million acres of land, were two species of beetles imported from France. These beetles feed and reproduce on goatweed, gradually decreasing this toxic plant. In 1959, a ten year survey documented the effectiveness of this biological control. Fertilizer with added insecticides/herbicides: Ocanbinations exist for special lawn problems. .The convenience is in the application of the already mixed product. However, the proper time to fertilize the grass may not be the best time to kill weeds. An example, Ortho's "Weed and Feed" is but one product available in garden centers. Weed -Killing Sprays: Active ingredients vary in their action: Arsenic and Chlordane have been used to kill crabgrass; chlordane is a chlorinated hydrocarbon in which toxic deposits build-up in animal .tissue in cumulative fashion. Arsenic in the weed killer sodium arsenate, is a carcinogen. (Carcinogenics can play either a direct or an indirect role in causing cancer). The "dinitro" herbicides are a metabolic stimulant that "burn" weeds. Aminotriazole (amitrol) is a mutagenic agent capable of altering genes. This is known as the cranberry -weed killer. Mutations assault chromosomes, thus allowing cells to multiply in a wild and unregulated manner. Other herbicides include 2,4 -D/2,4,5 -T and related compounds; IPC and CIPC, chemically related to carbarmates; all these are mutagens. In the application of weed killing products, use them according to the manufacturer's direction. Ideally, these chemicals are toxic only to weeds; but in reality, they threaten the food chain. An example, the herbicide 2,4-D temporarily disrupts nitrification. Example: Second generation: Example: Third generation: Example: III. At Issue: Weed Killers, their Pros and Cons Pesticides divide into insecticides for insect control and herbicides for weed control. Historically, pesticides group into three generations. First Generation: Pre - World War II Inorganic agents such as arsenates of lead, nicotine, and kerosene. In addition, formaldehyde gas was used to treat diseased seed, and sulfur to destroy spores in soil. Arsenic, as an active ingredient, was an effective weed killer. The problem - arsenic dust washed from plants by rain trickled into streams and poisoned fish. Post World War II Synthesized chemical agents. Two groups: chlorinated hydrocarbons (DDT) and organic phosphates (malathion) Herbicides 2,4-D and 2,4,5-T their toxicity is controversial. Research continues to genetically engineer less toxic pesticides. EPA approved gene -altered dead bacteria which gives off endotoxin, poisonous only to targeted insects. The use of man-made chemical weed killers (synthesized in the laboratory) increases the quantity of food and aesthetically improves the landscape. Nature, itself, is chemical. Example: In photosynthesis, sunlight converts water and carbon dioxide into carbohydrates. In this sense, synthesis means combining simple molecules to form a new substance. However, nature is intricately balanced and the misuse of man-made chemicals is disrupting this balance. One reason for the misuse of herbicides is the lack of understanding of the relationship between weeds and soil. Indiscriminant spraying pollutes more than targeted weeds. Chemical residues reduce the number of earthworms and other organisms that decompose soil. Some weed species develop resistance to the herbicides designed to control them. Examples are ragweed and crabgrass. Herbicides have been defended as harmless to wild life because they were thought to be less toxic than insecticides. The cumulative chemical residues of herbicides have endangered wildlife habitat. To destruct homes and food of wildlife can be more devastating than direct killing. Chemical residue tends to concentrate in animal tissue as they pass up the food chain. One way to avoid misusing weed killers is to observe plants in their native habitat. Learn to identify diverse species of plants. Only then can you selectively apply weed -killers to target unwanted plants. IV. Plant Ecology and the Ecological Role of Weeds Plant ecology studies the dynamics of plant, animal, soil, and atmosphere that establishes food webs, the oxygen cycle, and the carbon cycle. Field botany observes and identifies species of plants in their native habitat. When land is barren and atmospheric conditions permit, self -propagating plants (weeds) succeed each other in a given order (lichens, mosses, herbs, shrubs, and trees) Descriptively, soil surfaces the earth to support vegetation. The ecological role of weeds can be found wherever a piece of land is stripped of vegetation and left. idle. First, a dense ground cover is formed to hold the soil in place by annual plants. Completing their life cycle within a year, these weeds enrich the soil as they rot. The next weeds are biennials which have a two-year lease on life before being crowded out by perennials. Given more than a two-year life span, some biennials live many years. If the climate permits forest trees will grow. The longevity of forest trees will persist until ravaged by fire/flood or cut into lumber by man. When vegetation is destructed and the ground is bare, the ecological cycle begins anew. Nature emulated in landscaping begins with a better understanding of the self -propagating plant species and how they inter -relate with one another. V. Expanding the Concept of Ecology Ecology is the study of the relationship between living things and the non -living elements within the environment. Our physical environment is the biosphere; which is made-up of land, water, and air. Planet earth's air supply is finite. Given only solar energy, life on earth is made possible by continually recycling and refreshing the air in the production of elemental oxygen to sustain a balanced biosphere for the pyramid of living organisms. Photosynthesis is the chemical process involving sunlight -capturing greenplants to generate the air we breathe and the carbohydrates we eat. Oxygen production begins with plankton (free-floating, green microscopic plants) in the ocean. This is the earth's air- freshening system. An ecosystem is any environmentwhere the web-of-life._.is self - renewing. Very large ecosystems are called biomes such as the rainforest and Antarctica. Antarctica's barren "land" of ice is the native habitat for penguins. In sharp contrast, brightly colored birds are among the diversity of many species at home in the abundantly vegetated tropical rainforests, global ecosystems are interdependent with one another. This is harmony in nature. Breakdown of intricately balanced ecosystems are leaving gaps in the pyramid of living organisms when oxygen production form the oceans cannot keep pace with oxygen consumption by man, the entire biological structure is_threatened. VI. Closing thoughts: 1. Identify the weeds that you want to keep in check. 2. What are the options to control them? 3. If you decide on a herbicide follow the manufacturer's directions to avoid misuse. The key point: know the pros and cons of the active ingredient. 4. Stay updated on herbicidal products that may be available try to avoid products in which the active ingredient may leave a chemical residue in the soil that could get into the food chain. 5. As Rolling Hills residents, we observe various plants and animals whose native habitat is in our area. Learn how plants interrelate with one another to grow into a vegetate that provides food and shelter for wild life. REFERENCES All About Fertilizers, Soils, and Water. Ortho Books, Chevron Chemical Company. 1979. Brun, Gilbert D. "Plant Ecology and Field Botany", Understanding Botany A Laboratory Guide. Burgess Publishing.Company, 1984. Carson, Rachel. The Silent Spring, Boston: Houghton Mifflin Company, 1962. Christensen, Clyde M. "The Weeds", The Book of Popular Science, Vol. 7, Grolier Inc., 1966. Encyclopedia Science Supplement, Grolier Inc. 1970. Cottam, Clarence, "Pesticide Pollution." 1974. Foster, Ruth S. " Plants and the Urban Ecosystems." 1976. Wolf, Anthony, "Controlling Insects Biologically." 1977/1978 Cusak, Michael, "Weeds." Gales, Donald Moore. Handbook of Wildflowers, Weeds, Wildlife, and Weather of the Palos Verdes Peninsula, Rolling Hills, 1974. Levine, Louis, City College of New York, "Biotechnology" Grolier Encyclopedia, 1992 Yearbook.